New BMGs exhibiting strong glass forming ability combined with high hardness have been developed based on the Pt-Si-B ternary system. The effects of partial substitution of platinum by transition metals of the group iron, cobalt, nickel, and copper, as wel ...
We show how dynamic nuclear polarization (DNP) enhanced solid-state NMR spectroscopy can be used to characterize polymorphs and solvates of organic solids. We applied DNP to three polymorphs and one hydrated form of the asthma drug molecule theophylline. F ...
The electrochemical oxidation and reduction of decamethylferrocene is demonstrated in supercritical carbon dioxide at a macro gold disc electrode at 100 bar and 313 K. Fast mass transport effects were exhibited and the corresponding steady-state voltammetr ...
The combination of reaction calorimetry and supercritical fluids as reactants and/or solvent holds great potential for the optimization of chemical processes using high pressure near-critical and/or supercritical mixtures. The very specific properties of s ...