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Concept

Prelog strain

Related publications (31)

Oxidative rearrangement of 1,1-disubstituted alkenes to ketones

Qian Wang, Jieping Zhu, Qiang Feng

The Wacker process, which is widely used to convert monosubstituted alkenes into the corresponding methyl ketones, is thought to proceed through a PdII/Pd0 catalytic cycle involving a b-hydride elimination step. This mechanistic scenario is inapplicable to ...

American Association for the Advancement of Science2023

Energy dissipation in fiber-polymer composites adhesive joints under cyclic loading

Ghazaleh Eslami

Sustainable development has emerged as a paramount consideration in various fields of industry, including construction, to preserve the environment and its finite resources. Lightweight structures, such as fiber-polymer composite structures, address both s ...

EPFL2023

Cycloalkane Oxidation Catalyzed by Copper-based Catalysts with H2O2 under Mild Conditions

Nukorn Plainpan

Copper-catalyzed cycloalkane oxidation using H2O2 as an oxidant was investigated under mild conditions. The copper catalysts studied in this work ranged from commercially-available copper(II) salts to copper(II) complexes containing polypyridyl ligands. Va ...

WILEY-V C H VERLAG GMBH2023

Activation of aminocyclopropanes via radical intermediates

Jérôme Waser, Mingming Wang

Aminocyclopropanes are versatile building blocks for accessing high value-added nitrogen-containing products. To control ring-opening promoted by ring strain, the Lewis acid activation of donor-acceptor substituted systems is now well established. Over the ...

Royal Society of Chemistry2022

Deformation twinning mechanism in magnesium at the microscale: strain rate, temperature and orientation effects

Nicolò Maria Della Ventura

The project aims to validate some recent theoretical developments on the deformation twinning nucleation mechanism in HCP metals through small-scale mechanic experiments. To this end, a systematic investigation of the mechanical response of pure magnesium ...

EPFL2022

Scaling Description of Creep Flow in Amorphous Solids

Matthieu Wyart, Thomas Willem Jan de Geus, Marko Popovic, Wencheng Ji

Amorphous solids such as coffee foam, toothpaste, or mayonnaise display a transient creep flow when a stress E is suddenly imposed. The associated strain rate is commonly found to decay in time as gamma_ -t-nu, followed either by arrest or by a sudden flui ...

AMER PHYSICAL SOC2022

Umbrella Meshes: Elastic Mechanisms for Freeform Shape Deployment

Mark Pauly, Florin Isvoranu, Tian Chen, Yingying Ren, Uday Kusupati, Davide Pellis

We present a computational inverse design framework for a new class of volumetric deployable structures that have compact rest states and deploy into bending-active 3D target surfaces. Umbrella meshes consist of elastic beams, rigid plates, and hinge joint ...

Association for Computing Machinery (ACM)2022

Mechanical performance and upscaling of bio-improved soils

Ray Harran

Ecological awareness, pressing climate considerations and rising need for soil stabilization push forward the quest for alternative solutions in geotechnical engineering such as Microbially Induced Carbonate Precipitation (MICP). Precipitated crystals serv ...

EPFL2022

Order parameters for antiferromagnetic structures: A first-principles study of iridium manganese

Anirudh Raju Natarajan

We use density-functional theory to study the ordered states of iridium manganese, demonstrating a simple but powerful method for describing magnetic structures and the transitions among them. As an illustrative example, the coupling of magnetism and cryst ...

AMER PHYSICAL SOC2022

A probabilistic deformation-based seismic hazard model for Iran

Alireza Khodaverdian

Probabilistic seismic hazard analysis, as the most prevalent approach to evaluate earthquake hazard, is commonly based on earthquake catalogs. Although previous studies show that the recurrence time of large-magnitude (M-w > 7.0) events in Iran is more tha ...

2022

A numerical approach to characterize the viscoelastic behaviour of fibre beds and to evaluate the influence of strain deviations on viscoelastic parameter extraction

Véronique Michaud, Vincent Werlen

The development of a robust material model able to accurately describe fibre bed compaction at different strain and strain rates is highly desirable because it is essential for the simulation of many composite manufacturing processes. In this study, we inv ...

2021

Discussion on "Experimental Deformation of Opalinus Clay at Elevated Temperature and Pressure Conditions: Mechanical Properties and the Influence of Rock Fabric" of Schuster, V., Rybacki, E., Bonnelye, A., Herrmann, J., Schleicher, AM, Dresen, G

Lyesse Laloui, Alessio Ferrari, Eleonora Crisci

The testing procedure and results on saturated samples of Opalinus Clay in the work of Schuster et al. (Rock Mech Rock Eng https://doi.org/10.1007/ s00603-021-02474-3, 2021) were conducted and presented using strain rates two to four orders of magnitudes h ...

2022

Constitutive Modeling of Structural Steels: Nonlinear Isotropic/Kinematic Hardening Material Model and Its Calibration

Dimitrios Lignos, Albano António De Abreu E Presa De Castro E Sousa

Numerical models of structural components that deteriorate primarily due to geometric instabilities under multiaxis cyclic loading are sensitive to both the assumed geometric imperfections and the nonlinear material model assumptions. Therefore, the accura ...

2021

New Strategies for the Functionalization of Alkenes Exploiting Tethering Chemistry and Ring Strain

Bastian Antoine Rodolphe Claude Muriel

Amino alcohols, cyclopropanes and nitriles are privileged structural motifs found in the scaffold of natural products and bioactive compounds. In addition, they are versatile building blocks in organic chemistry. The development of new and increasingly eff ...

EPFL2021

Influence of Joule Effect Heating on Recrystallization Phenomena in Inconel 718

Roland Logé, Mathijs Pieter van der Meer

In this article, the Joule effect heating influence on recrystallization phenomena in the Inconel 718 nickel-based superalloy is investigated in details. On the one hand, static recrystallization kinetic studies at 1020 degrees C after cold deformation up ...

SPRINGER2021

A scenario modeling pipeline for COVID-19 emergency planning

Francisco Javier Perez Saez, Joseph Chadi Benoit Lemaitre

Coronavirus disease 2019 (COVID-19) has caused strain on health systems worldwide due to its high mortality rate and the large portion of cases requiring critical care and mechanical ventilation. During these uncertain times, public health decision makers, ...

Nature Portfolio2021

The effect of stress triaxiality on the phase transformation in transformation induced plasticity steels: Experimental investigation and modelling the transformation kinetics

Helena Van Swygenhoven, Nicola Casati

In situ multiaxial loading during neutron diffraction tests were undertaken on a low-alloyed Quenched and Partitioning (Q&P) Transformation Induced Plasticity (TRIP) Bainitic Ferrite (TBF) steel with dispersed austenite particles. The effect of stress tria ...

2021

Tensile response of UHPFRC under very low strain rates and low temperatures

Emmanuel Denarié, Mohamed Abdul Hafiz

This paper addresses the uniaxial tensile response of Strain Hardening Ultra High-Performance Fiber Reinforced Concretes (SH-UHPFRC) subjected to very low strain rates and low temperatures. The influence of four different strain rates; 1 × 10−5, 1 × 10−7, ...

Pergamon-Elsevier Science Ltd2020

Heat source and voiding signatures of Mullins damage in filled EPDM

Nicolas Candau, Oguzhan Oguz

The thermomechanical coupling of Mullins damage in filled EPDM has been investigated by analysing the self-heating via Infrared thermography (IR) and the voiding fraction by Digital Image Correlation (DIC). The volumetric strain measured during the rubber ...

ELSEVIER SCI LTD2020

Cold Atmospheric Plasma Inactivation of Microbial Spores Compared on Reference Surfaces and Powder Particles

Alan Howling, David Martinet

Heat-resistant spores on a dry, heat- and water-sensitive food matrix are difficult to inactivate. Radioactive or X-ray exposure is allowed and accepted only for some selected commodities. Non-thermal atmospheric pressure plasma treatments could offer an e ...

SPRINGER2020