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Concept

Trigonal planar molecular geometry

Related publications (27)

Mechanistic Insight into Supramolecular Polymerization in Water Tunable by Molecular Geometry

Lukas Pfeifer

Supramolecular self-assembly in water based on non-covalent bonding is attracting major attention due to the potential of hydrogels and aqueous polymers in biomedical applications. Although supramolecular polymerization in organic solvents is well establis ...

CHINESE CHEMICAL SOC2022

3D Weaving with Curved Ribbons

Mark Pauly, Florin Isvoranu, Francis Julian Panetta, Yingying Ren, Tian Chen, Samuel Jean Bernard Poincloux, Christopher Brandt

Basket weaving is a traditional craft for creating curved surfaces as an interwoven array of thin, flexible, and initially straight ribbons. The three-dimensional shape of a woven structure emerges through a complex interplay of the elastic bending behavio ...

2021

Enhanced Intersystem Crossing and Transient Electron Spin Polarization in a Photoexcited Pentacene–Trityl Radical

David Lyndon Emsley, Jacques-Edouard Moser, Dominik Józef Kubicki, Etienne Christophe Socie, Aaron James Rossini, Gabriele Stevanato, Claudia Esther Avalos

Identifying and characterizing systems that generate well-defined states with large electron spin polarization is of high interest for applications in molecular spintronics, high-energy physics, and magnetic resonance spectroscopy. The generation of electr ...

2020

Boosting the power conversion efficiency of perovskite solar cells to 17.7% with an indolo[3,2-b]carbazole dopant-free hole transporting material by improving its spatial configuration

Ulf Anders Hagfeldt, Xiaoqing Jiang

The development of facilely synthesized, dopant-free hole-transporting materials (HTMs) with high efficiency is of great significance for the potential application of perovskite solar cells (PSCs). Herein, we report two novel indolo[3,2-b]carbazole (ICZ) b ...

Royal Society of Chemistry2019

A Learned Shape-Adaptive Subsurface Scattering Model

Wenzel Alban Jakob, Delio Aleardo Vicini

Subsurface scattering, in which light refracts into a translucent material to interact with its interior, is the dominant mode of light transport in many types of organic materials. Accounting for this phenomenon is thus crucial for visual realism, but exp ...

ASSOC COMPUTING MACHINERY2019

Controlling Ferromagnetic Ground States and Solitons in Thin Films and Nanowires Built from Iron Phthalocyanine Chains

Gabriel Aeppli

Iron phthalocyanine (FePc) is a molecular semiconductor whose building blocks are 1D ferromagnetic chains. It is shown that its optical and magnetic properties are controlled by the growth strategy, obtaining extremely high coercivities of over 1 T and mod ...

WILEY-V C H VERLAG GMBH2019

Bond-selective and surface-site-specific dissociation of methane on platinum

Ana Gutiérrez González

I present a molecular beam study of methane dissociation on differ-ent surface sites of several platinum single crystal surfaces (Pt(111), Pt(211), Pt(210), Pt(110)-(2x1)). The experiments were performed in a molecular beam/surface-science apparatus that c ...

EPFL2019

The influence of external electric fields on charge reorganization energy in organic semiconductors

Anne-Clémence Corminboeuf, Hongguang Liu

Charge reorganization energies (k) of inter-ring carbon-carbon (IRCC) bond connected conjugated polycyclics are shown to exhibit an electric-field-driven anisotropic character. An external electric field parallel to the IRCC linker(s) reduces k while the f ...

Royal Society of Chemistry2019

Methoxydiphenylamine-substituted fluorene derivatives as hole transporting materials: role of molecular interaction on device photovoltaic performance

Mohammad Khaja Nazeeruddin, Michael Saliba, Sanghyun Paek

The molecular structure of the hole transporting material (HTM) play an important role in hole extraction in a perovskite solar cells. It has a significant influence on the molecular planarity, energy level, and charge transport properties. Understanding t ...

Nature Research2017

Probing Defects and Correlations in the Hydrogen-Bond Network of ab Initio Water

Michele Ceriotti, Piero Gasparotto

The hydrogen-bond network of water is characterized by the presence of coordination defects relative to the ideal tetrahedral network of ice, whose fluctuations determine the static and time-dependent properties of the liquid. Because of topological constr ...

Amer Chemical Soc2016

Analytic first derivatives of floating occupation molecular orbital-complete active space configuration interaction on graphical processing units

Marine Eva Fedora Bouduban

The floating occupation molecular orbital-complete active space configuration interaction (FOMO-CASCI) method is a promising alternative to the state-averaged complete active space self-consistent field (SA-CASSCF) method. We have formulated the analytic f ...

Amer Inst Physics2015

Complex image method for RF antenna-plasma inductive coupling calculation in planar geometry. Part II: measurements on a resonant network

Ivo Furno, Alan Howling, Philippe Frédérique Bruno Guittienne, Rémy Jacquier

Measurements and analysis of a radio-frequency planar antenna are presented for applications in inductively-coupled plasma processing. The network of inductive and capacitive elements exhibits high currents under resonance which are efficient for plasma ge ...

Iop Publishing Ltd2015

Synthesis and structural elucidation of bioactive triorganotin (IV) derivatives of sodium deoxycholate

Rosario Scopelliti

Trimethyl (1), tributyl (2), and triphenyl tin (3) derivatives of sodium (R)-4-((3R, 5R, 8R, 9S, 10S, 12S, 13R, 14S, 17R)-3,12-dihydroxy-10,13-dimethyl-hexadecahydro-1H-cyclopenta[a] phenanthren-17-yl)pentanoate (sodium deoxycholate) were synthesized by re ...

Taylor & Francis Ltd2014

Harvesting UV Photons for Solar Energy Conversion Applications

Jacques-Edouard Moser, Magdalena Anna Marszalek, Mateusz Barnaba Wielopolski

We report the synthesis and characterization of five new donor–π–spacer–acceptor dye molecules with a diphenylamine donor, fluorene–1,2,5-oxadiazole spacers and a range of acceptor/anchor groups (carboxylic acid 1, cyanoacrylic acid 2 and 3, alcohol 4 and ...

Royal Soc Chemistry2014

Curved artificial compound-eyes for autonomous navigation

Ramon Pericet Camara

Natural compound-eyes consist of a large number of ommatidia that are arranged on curved surfaces and thus are able to detect signals from a wide field of view. We present an integrated artificial compound-eye sensor system with enhanced field of view of 1 ...

SPIE-INT SOC OPTICAL ENGINEERING2014

Generation of Whistler-Wave Heated Discharges with Planar Resonant rf Networks

Christoph Hollenstein, Alan Howling, Philippe Frédérique Bruno Guittienne

Magnetized plasma discharges generated by a planar resonant rf network are investigated. A regime transition is observed above a magnetic field threshold, associated with rf waves propagating in the plasma and which present the characteristics of whistler ...

Amer Physical Soc2013

Speciation of aqueous tellurium(IV) in hydrothermal solutions and vapors, and the role of oxidized tellurium species in Te transport and gold deposition

Lothar Helm, Pascal Grundler

Despite the close association between tellurium (Te) and gold (Au) in many epithermal, orogenic, and intrusion-related hydrothermal ore deposits, the hydrothermal chemistry of Te remains poorly understood. We studied the protonation/ deprotonation and stru ...

Elsevier2013

Significant Improvement of Dye-Sensitized Solar Cell Performance by Small Structural Modification in π-Conjugated Donor-Acceptor Dyes

Michael Graetzel, Shaik Mohammed Zakeeruddin, Robin Humphry-Baker, Jacques-Edouard Moser, Joël Teuscher, Magdalena Anna Marszalek, Mateusz Barnaba Wielopolski

Two donor-π-acceptor (D-π-A) dyes are synthesized for application in dye- sensitized solar cells (DSSC). These D-π-A sensitizers use triphenylamine as donor, oligothiophene as both donor and π-bridge, and benzothiadiazole (BTDA)/cyanoacrylic acid as accept ...

Wiley-Blackwell2012

Facile fabrication of nanofluidic diode membranes using anodic aluminium oxide

Jürgen Brugger, Philippe Renaud, Arnaud Bertsch, Oscar Vazquez Mena, Songmei Wu, Fabien Patrick Wildhaber

Active control of ion transport plays important roles in chemical and biological analytical processes. Nanofluidic systems hold the promise for such control through electrostatic interaction between ions and channel surfaces. Most existing experiments rely ...

Royal Soc Chemistry2012

DNA Reactivity Profile of trans-Platinum Planar Amine Derivatives

Alexey Nazarov

New trans-platinum planar amines (TPAs) represent a family of platinum-based drugs with cytotoxicity equivalent to that of cisplatin, but with negligible cross-resistance. According to the substitution pattern around the metal center, distinct DNA adducts ...

2011