Rotational barriers of biphenyls having heavy heteroatoms as ortho-substituents: experimental and theoretical determination of steric effects

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Curcuminoids and their complexes continue to attract attention in medicinal chemistry, but little attention has been given to their metabolic derivatives. Here, the first examples of (arene)Ru(II) complexes with curcuminoid metabolites, tetrahydrocurcumin ...

The construction industry plays a major role in the high levels of greenhouse gas emissions, resource consumption, and waste generation observed nowadays. Key to the circular economy, structural component reuse arises as a promising solution to divert cons ...

Gas bearings use pressurized gas as a lubricant to support and guide rotating machinery. These bearings have a number of advantages over traditional lubricated bearings, including higher efficiency in a variety of applications and reduced maintenance requi ...

To characterize in detail the charge density wave (CDW) transition of 1T-VSe2, its electronic structure and lattice dynamics are comprehensively studied by means of x-ray diffraction, muon spectroscopy, angle resolved photoemission (ARPES), diffuse and ine ...

Load-bearing systems in buildings, significant in material use and embodied greenhouse gas emissions (EGHGE), have lacked detailed analysis on their environmental and functional relationships over time and space. This study evaluates the environmental impa ...

Structure determination of materials is key to understanding their physical properties. While single-crystal X-ray diffraction is the gold standard for structures displaying long-range order, many materials of interest are polycrystalline and/or disordered ...

Barocaloric (BC) materials provide cheaper and more energy efficient alternatives to traditional refrigerants. Some liquid alkanes were recently shown to exhibit a colossal BC effect, matching the entropy changes in commercial vapour-liquid refrigerants. D ...

Herringbone grooved journal bearings (HGJBs) are widely used in micro-turbocompressor applications due to their high load-carrying capacity, low friction, and oil-free solution. However, the performance of these bearings is sensitive to manufacturing devia ...

Machine learning has paved the way for the real-time monitoring of complex infrastructure and industrial systems. However, purely data-driven methods have not been able to learn the underlying dynamics and generalize them to operating conditions that have ...

Structural systems are a significant contributor to buildings’ embodied carbon and reusing structural elements in new load-bearing applications is one strategy to reduce this impact. However, integrating this approach into existing design workflows without ...

Designing turbocompressors is a complex and challenging task, as it involves balancing conflicting objectives such as efficiency, stability, and robustness against manufacturing deviations. This paper proposes an integrated design methodology for turbocomp ...

Structure determination of amorphous materials remains challenging, owing to the disorder inherent to these materials. Nuclear magnetic resonance (NMR) powder crystallography is a powerful method to determine the structure of molecular solids, but disorder ...

DNA mechanics plays a crucial role in many biological processes, including nucleosome positioning and protein-DNA interactions. It is believed that nature employs epigenetic modifications in DNA to further regulate gene expression. Moreover, double-strande ...

In the evolution of structural glass beam elements, the requirements for post-fracture load bearing capacity and safe failure behaviour have led to the development of reinforced and post-tensioned beams. Maximum bending capacity in the post-fracture state ...

Efficient valorization of lignin, a sustainable source of functionalized aromatic products, would reduce dependence on fossil-derived feedstocks. Oxidative depolymerization is frequently applied to lignin to generate phenolic mono- mers. However, due to th ...

Ternary-based titanium nitride (TiN) thin films have drawn attention toward rational applications due to their wear resistance, high hardness, and corrosion resistance. The influence of Mo content on the structural, tribo-logical, and mechanical properties ...

Structure determination techniques are an essential tool to investigate and understand molecules, especially in biology, where functionality crucially depends on structure. The dominant high-resolution methods, such as transmission electron microscopy and ...

Metal nanoclusters are a unique class of synthetic material, as their crystal structures can be resolved using X-ray diffraction, and their chemical formula can be precisely determinated from mass spectroscopy. However, a complete structure characterizatio ...

Rotational barriers of biphenyls having heavy heteroatoms as ortho-substituents: experimental and theoretical determination of steric effects

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Ru(II)-Arene Complexes of Curcumin and Bisdesmethoxycurcumin Metabolites

RE:SLAB — a load bearing system for open-ended component reuse in building structures

Parametric Reduced Order Model of a Gas Bearings Supported Rotor

Electronic structure and lattice dynamics of 1T-VSe2:Origin of the three-dimensional charge density wave

Multiscale Spatiotemporal Characterization of Embodied Environmental Performance of Building Structures in Geneva from 1850 to 2018

NMR Crystallography in the Big Data Era: New Methods and Applications Powered by Machine Learning

Pressure-freezing of dodecane: exploring the crystal structures, formation kinetics and phase diagrams for colossal barocaloric effects in n-alkanes

Robust Design of Herringbone Grooved Journal Bearings using Multi-Objective Optimization with Artificial Neural Networks

Robust Design of Herringbone Grooved Journal Bearings using Multi-Objective Optimization with Artificial Neural Networks

Graph neural networks for dynamic modeling of roller bearings

Parametric Reduced Order Model of a Gas Bearings Supported Rotor

Interactive design with optimum matchmaking of reused structural elements – a software implementation

An Integrated Approach to Designing Robust Turbocompressors on Gas Bearings Through Surrogate Modeling and Constrained Multi-Objective Optimization

Atomic-level structure determination of amorphous molecular solids by NMR

cgNA+: A sequence-dependent coarse-grain model of double-stranded nucleic acids

Exploring the potential of the critical shear crack theory for reinforced and post-tensioned glass beams: Initial analysis and experiments

Direct conversion of lignin to functionalized diaryl ethers via oxidative cross-coupling

Effect of Mo addition on the mechanical and tribological properties of magnetron sputtered TiN films

Low-energy Electron Holography Microscope for Imaging of Single Molecules

Quantifying the Solution Structure of Metal Nanoclusters Using Small-Angle Neutron Scattering