Publications associées à High-pressure effects on the Diels-Alder reaction in room temperature ionic liquids

Probing Catalytic Sites and Adsorbate Spillover on Ultrathin FeO2-x Film on Ir(111) during CO Oxidation

The spatially resolved identification of active sites on the heterogeneous catalyst surface is an essential step toward directly visualizing a catalytic reaction with atomic scale. To date, ferrous centers on platinum group metals have shown promising pote ...

Amer Chemical Soc2024

Pressure stabilization effect on the donor-acceptor polyiodide chains in tetraethylammonium bis(diiodine) triiodide - insights from Raman spectroscopy

Nicola Casati, Tomasz Poreba

Polyiodides present high bonding flexibility already at ambient conditions, and undergo significant pressure-induced structural deformations. Resonant Raman spectroscopy has been widely used to study I-I bonds in various polyiodides, but it carries a risk ...

Royal Soc Chemistry2024

A Tunable Self-Offloading Module for Plantar Pressure Regulation in Diabetic Patients

Paolo Germano, Christian Köchli, Yves Perriard, Yoan René Cyrille Civet, Kenny Jeanmonod, Sofia Lydia Ntella, Bhawnath Tiwari

Plantar pressure plays a crucial role in the pathogenesis of foot ulcers among patients with diabetes and peripheral polyneuropathy. Pressure relief is a key requirement for both the prevention and treatment of plantar ulcers. Conventional medical practice ...

2024

Lewis acid catalyzed [4+2] annulation of bicyclobutanes with dienol ethers for the synthesis of bicyclo[4.1.1]octanes

Jérôme Waser, Stefano Nicolai

Bicyclic carbocycles containing a high fraction of Csp3 have become highly attractive synthetic targets because of the multiple applications they have found in medicinal chemistry. The formal cycloaddition of bicyclobutanes (BCBs) with two- or three-atom p ...

Royal Soc Chemistry2024

Fiber pumps for wearable fluidic systems

Herbert Shea, Vito Cacucciolo, Michael James Henry Smith

Incorporating pressurized fluidic circuits into textiles can enable muscular support, thermoregulation, and haptic feedback in a convenient wearable form factor. However, conventional rigid pumps, with their associated noise and vibration, are unsuitable f ...

American Association for the Advancement of Science2023

The influence of the gas on the dynamics of cavitation bubbles

Davide Bernardo Preso

Cavitation bubbles, extensively investigated in fluid mechanics, present enduring challenges in hydraulic machinery, while holding considerable potential for practical applications in biomedicine and sonochemistry. Despite more than a century of research, ...

EPFL2023

Inferring free-energy barriers and kinetic rates from molecular dynamics via underdamped Langevin models

Fabio Pietrucci, Sara Bonella, David Daniel Girardier

Rare events include many of the most interesting transformation processes in condensed matter, from phase transitions to biomolecular conformational changes to chemical reactions. Access to the corresponding mechanisms, free-energy landscapes and kinetic r ...

Aip Publishing2023

Research data supporting 'Fiber pumps for wearable fluidic systems'

Herbert Shea, Vito Cacucciolo, Michael James Henry Smith

The dataset supporting 'Fiber pumps for wearable fluidic systems', published in Science in March 2023. In this work, we present a fluidic pump in the form of a flexible and stretchable tube. These tubes - or 'fiber pumps' - can generate significant fluidic ...

2023

Integrated Electronics for Deep Implants to Remotely Monitor Hemodynamics

Mustafa Besirli

The integration of technology in the medical field has greatly improved accuracy in diagnoses, thus leading to more effective treatments. Wearable and implantable medical devices offer great potential for remote patient monitoring, particularly for heart f ...

EPFL2023

Gas/Surface reactions probed by reflection absorption infrared spectroscopy

Harmina Vejayan

In my thesis, I present an investigation of the dissociation reactions of gas phase molecules on single crystal metal surfaces studied by a molecular beam in combination with Reflection Absorption Infrared Spectroscopy (RAIRS). Two gas/surface systems were ...

EPFL2023

Improving the Accuracy of Fracture Toughness Measurement in Burst Experiments

Guanyi Lu, Yixuan Zhang

Experimental studies suggest that the fracture toughness of rocks increases with the confining pressure. Among many methods to quantify this dependency, a so-called burst experiment (Abou-Sayed, 1978) may be the most widely applied in practice. Its thick w ...

SPRINGER WIEN2022

Overflow pressure characterization in lined plunge pools for slab sizing

Giovanni De Cesare, Pedro Filipe De Almeida Manso, Francisca Marco Cutillas

This study presents an experimental work on dynamic pressures at the bottom of a lined plunge pool that receives overflow rectangular impinging jets and aims at improving the design criteria for pool slabs. The experiments were conducted in a fairly large ...

International Association for Hydro-Environment Engineering and Research (IAHR)2022

Bottom-Pressure Development Due to an Abrupt Slope Reduction at Stepped Spillways

Anton Schleiss, José Pedro Gamito de Saldanha Calado Matos, Michael Pfister, Mohammad Javad Ostad Mirza

Fluctuating bottom-pressures on stepped chutes are relevant for the spillway design. An abrupt slope reduction causes a local alteration of the bottom-pressure development. Little information is available regarding the air–water flow properties near an abr ...

2022

Temperature- and pressure-dependence of the hydrogen bond network in plastic ice VII

Livia Eleonora Bove Kado, Umbertoluca Ranieri, Maria Rescigno

We model, via classical molecular dynamics simulations, the plastic phase of ice VII across a wide range of the phase diagram of interest for planetary investigations. Although structural and dynamical properties of plastic ice VII are mostly independent o ...

AIP Publishing2022

In flow acoustic characterisation of a 2D active liner with local and non local strategies

Hervé Lissek, Maxime Volery, Gaël Matten

The design and the grazing flow aeroacoustical characterization of a 2D active liner based on an array of electroacoustic absorbers are presented in this paper. The strategy stands on a pressure-based, current-driven digital architecture for impedance cont ...

2022

Preliminary design of the pressure relief system of the EDIPO 2 helium vessel

Pierluigi Bruzzone, Kamil Sedlák, Roberto Guarino, Evgeny Solodko

The European Dipole (EDIPO) test facility is undergoing a major upgrade of its magnet assembly, which will provide ground for testing both fusion and high-energy physics superconducting samples at variable temperature and with a background field of 15 T. I ...

2022

Imaging of Chemical Kinetics at the Water–Water Interface in a Free-Flowing Liquid Flat-Jet

Andreas Osterwalder, Bruno Credidio

We present chemical kinetics measurements of the luminol oxidation chemiluminescence (CL) reaction at the interface between two aqueous solutions, using liquid jet technology. Free-flowing liquid microjets are a relatively recent development that have foun ...

2022

Transport barrier in 5D gyrokinetic flux-driven simulations

Two ways for producing a transport barrier through strong shear of the E x B poloidal flow have been investigated using GYSELA gyrokinetic simulations in a flux-driven regime. The first one uses an external poloidal momentum (i.e. vorticity) source that lo ...

IOP Publishing Ltd2022

Femtosecond laser-shockwave induced densification in fused silica

Yves Bellouard, Pieter Vlugter, Arunkrishnan Radhakrishnan, Julien Gilles Edgar Gateau

A tightly focused femtosecond laser-beam in the non-ablative regime can induce a shockwave sufficiently intense to reach local pressures in the giga-Pascal range or more. In a single beam configuration, the location of the highest-pressure zone is nested w ...

2022

Arterial Wave Reflection and Aortic Valve Stenosis: Diagnostic Challenges and Prognostic Significance

Nikolaos Stergiopoulos, Stamatia Zoi Pagoulatou, Vasiliki Bikia, Georgios Rovas

IntroductionArterial wave reflection is an important component of the left ventricular afterload, affecting both pressure and flow to the aorta. The aim of the present study was to evaluate the impact of wave reflection on transvalvular pressure gradients ...

FRONTIERS MEDIA SA2022