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RETRACTED: On the enzymatic activity of catalase: an iron L-edge X-ray absorption study of the active centre

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Publications associées (37)

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Unconventional Spin Relaxation Involving Localized Vibrational Modes in Ho Single-Atom Magnets

Harald Brune, Stefano Rusponi, Marina Pivetta, Jan Gui-Hyon Dreiser, Pietro Gambardella, Fabio Donati, Christian Wäckerlin, Aparajita Singha, Romana Baltic, Katharina Johanna Diller

We investigate the spin relaxation of Ho single atom magnets on MgO/Ag(100) as a function of temperature and magnetic field. We find that the spin relaxation is thermally activated at low field, while it remains larger than 1000 s up to 30 K and 8 T. This ...

AMER PHYSICAL SOC2020

Plant responses to rising vapor pressure deficit

Charlotte Grossiord

Recent decades have been characterized by increasing temperatures worldwide, resulting in an exponential climb in vapor pressure deficit (VPD). VPD has been identified as an increasingly important driver of plant functioning in terrestrial biomes including ...

2020

An overview of the ORACLES (ObseRvations of Aerosols above CLouds and their intEractionS) project: aerosol-cloud-radiation interactions in the southeast Atlantic basin

Athanasios Nenes

Southern Africa produces almost a third of the Earth's biomass burning (BB) aerosol particles, yet the fate of these particles and their influence on regional and global climate is poorly understood. ORACLES (ObseRvations of Aerosols above CLouds and their ...

Copernicus GmbH2021

Optical absorption properties of metal-organic frameworks: solid stateversusmolecular perspective

Berend Smit, Anne-Clémence Corminboeuf, Ivano Tavernelli, Maria Fumanal Quintana

The vast chemical space of metal and ligand combinations in Transition Metal Complexes (TMCs) gives rise to a rich variety of electronic excited states with local and non-local character such as intra-ligand (IL), metal-centered (MC), metal-to-ligand (MLCT ...

2020

Exploring the coupled ocean and atmosphere system with a data science approach applied to observations from the Antarctic Circumnavigation Expedition

Julia Schmale, Katherine Colby Leonard, Andrea Baccarini, Robin Lewis Modini, Sebastian Johannes Heinz-Josef Landwehr, Alireza Moallemi, Fernando Perez Cruz, Christel Sybille Hassler

The Southern Ocean is a critical component of Earth's climate system, but its remoteness makes it challenging to develop a holistic understanding of its processes from the small scale to the large scale. As a result, our knowledge of this vast region remai ...

2021

Dynamics of wind-induced coastal upwelling and interbasin exchange in Lake Geneva during winter: Implications for deepwater renewal

Rafael Sebastian Reiss

Water quality in lakes is closely linked to hydrodynamics and often dominated by stratification, limiting the exchange between the epi- and hypolimnion. Thus, the vertical redistribution of biogeochemical tracers such as dissolved oxygen and nutrients by c ...

EPFL2021

Science, Diplomacy, and the Red Sea's Unique Coral Reef: It's Time for Action

Anders Meibom, Maoz Fine

Rapid ocean warming due to climate change poses a serious risk to the survival of coral reefs. It is estimated that 70-90 percent of all reefs will be severely degraded by mid-century even if the 1.5 degrees C goal of the Paris Climate Agreement is achieve ...

FRONTIERS MEDIA SA2020

The Quest for Genes Involved in Adaptation to Climate Change in Ruminant Livestock

Stéphane Joost, Elia Vajana

Simple Summary: After domestication in specific regions, livestock followed human migrations and colonized the whole world. During this population expansion, human and natural selection, together with demographic events, molded the livestock genome leading ...

2021

Electrochemical evaluation of iron-binding ligands along the Australian GEOTRACES southwestern Pacific section (GP13)

Christel Sybille Hassler

In this work, we performed electrochemical investigations of Fe-binding ligands in water samples collected in autumn 2011 along the Australian GEOTRACES southwestern Pacific section (GP13, between 153 degrees E and 170 degrees W longitude along the 30 degr ...

2020

The role of air-sea fluxes for the water vapour isotope signals in the cold and warm sectors of extratropical cyclones over the Southern Ocean

Josué Etienne Gehring

Meridional atmospheric transport is an important process in the climate system and has implications for the availability of heat and moisture at high latitudes. Near-surface cold and warm temperature advection over the ocean in the context of extratropical ...

Copernicus Gesellschaft Mbh2021

Thermal spin crossover in Fe(ii) and Fe(iii). Accurate spin state energetics at the solid state

Sergio Vela Llausi, Maria Fumanal Quintana

The thermal spin crossover (SCO) phenomenon refers to an entropy-driven spin transition in some materials based on d(6)-d(9) transition metal complexes. While its molecular origin is well known, intricate SCO behaviours are increasingly common, in which th ...

ROYAL SOC CHEMISTRY2020

Ensemble modelling of ice cover for a reservoir affected by pumped-storage operation and climate change

Ulrike Kobler

Ensemble modelling was used to assess the robustness of projected impacts of pumped-storage (PS) operation and climate change on reservoir ice cover. To this end, three one-dimensional and a two-dimensional laterally averaged hydrodynamic model were set up ...

WILEY2019

Development of a novel carboxamide-based off-on switch fluorescence sensor: Hg2+, Zn(2+)and Cd2+

Kurt Schenk

Here, the carboxamide ligandN-(thiazole-2-yl) picolinamide (L) was synthesized in an ionic liquid tetrabutylammonium bromide (TBAB) as the benign reaction medium. The sensitivity ofLtowards different metal-ions was investigated, and a comprehensive, logica ...

2020

Crystal field, ligand field, and interorbital effects in two-dimensional transition metal dichalcogenides across the periodic table

Oleg Yazyev, Diego José Pasquier

Two-dimensional (2D) transition metal dichalcogenides (TMDs) exist in two polymorphs, referred to as 1T and 1H, depending on the coordination sphere of the transition metal atom. The broken octahedral and trigonal prismatic symmetries lead to different cry ...

IOP PUBLISHING LTD2019

Fast remote correlation experiments for 1H homonuclear decoupling in solids

David Lyndon Emsley, Pinelopi Moutzouri, Bruno Simões de Almeida

In 1H MAS spectra, the residual homogeneous broadening under MAS is due to a combination of higher-order shifts and splittings. We have recently shown how the two-dimensional anti-z-COSY experiment can be used for the removal of the splittings. However, th ...

Academic Press Inc - Elsevier Science2020

Nanophotonic supercontinuum-based mid-infrared dual-comb spectroscopy

Luc Thévenaz, Tobias Kippenberg, Camille Sophie Brès, Junqiu Liu, Hairun Guo, Wenle Weng, Wolfgang Hänsel

High resolution and fast detection of molecular vibrational absorption is important for organic synthesis, pharmaceutical processes, and environmental monitoring, and is enabled by mid-infrared (mid-IR) laser frequency combs via dual-comb spectroscopy. Her ...

2020

Life-history trade-offs and limitations associated with phenotypic adaptation under future ocean warming and elevated salinity

Emma Mary Gibbin

Little is known about the life-history trade-offs and limitations, and the physiological mechanisms that are associated with phenotypic adaptation to future ocean conditions. To address this knowledge gap, we investigated the within-and trans-generation li ...

ROYAL SOC2019