Spectroscopy and Conformational Preferences of Gas-Phase Helices

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Chip -scale optical frequency combs enable the generation of highly -coherent pulsed light at gigahertz-level repetition rates, with potential technological impact ranging from telecommunications to sensing and spectroscopy. In combination with techniques ...

Infrared and Raman spectroscopies are ubiquitous techniques employed in many experimental laboratories, thanks to their fast and non-destructive nature able to capture materials' features as spectroscopic fingerprints. Nevertheless, these measurements freq ...

Applications demanding imaging at low-light conditions at near-infrared (NIR) and short-wave infrared (SWIR) wavelengths, such as quantum information science, biophotonics, space imaging, and light detection and ranging (LiDAR), have accelerated the develo ...

Low-level light detection with high spatial and timing accuracy is a growing area of interest by virtue of applications such as light detection and ranging (LiDAR), biomedical imaging, time-resolved Raman spectroscopy, and quantum applications. Single-phot ...

Glycans play a pivotal role in both physiological processes; however, the field of glycobiology remains relatively understudied within biochemistry. The intricate complexity of glycans, coupled with their abundance of isomeric forms, presents formidable ch ...

Nanocavities formed by ultrathin metallic gaps permitthe reproducibleengineering and enhancement of light-matter interaction, withmode volumes reaching the smallest values allowed by quantum mechanics.While the enhanced vacuum field in metallic nanogaps ha ...

We describe a novel UHV state-to-state molecule/surface scattering apparatus with quan- tum state preparation of the incident molecular beam and angle-resolved quantum state detection of the scattered molecules. State resolved detection is accomplished usi ...

We present a new spectroscopic study of 175 stars in the vicinity of the dwarf galaxy Hercules (d similar to 132 kpc) with data from the Anglo-Australian Telescope and its AAOmega spectrograph together with the Two Degree Field multi-object system to solve ...

Data and code associated with the following paper V. Vento, S. Tarrago-Velez et al., Nat. Commun. (2023) A thorough explanation of the experiment performed is available there. The name of each sub-folder and file in CS2_data_code.zip indic ...

In my thesis, I present an investigation of the dissociation reactions of gas phase molecules on single crystal metal surfaces studied by a molecular beam in combination with Reflection Absorption Infrared Spectroscopy (RAIRS). Two gas/surface systems were ...

We investigate the gas-phase structure of the neutral pentaalanine peptide. The IR spectrum in the 340-1820 cm-1 frequency range is obtained by employing supersonic jet cooling, infrared multiphoton dissociation, and vacuum-ultraviolet action spectroscopy. ...

The presence of chemisorbed oxygen on the Cu(111) surface is known to strongly reduce the activation barrier for water dissociation as compared to bare Cu(111). Here, we present direct experimental evidence for the hydrogen abstraction mechanism responsibl ...

Glycans play an essential role in numerous physiological and pathological processes of living organisms. Despite their significant biological relevance, glycobiology remains one of the least explored fields of biochemistry. The intrinsic isomeric complexit ...

The atomic motion controls important properties of materials, such as thermal transport, phase transitions, and vibrational spectra. However, simulating the ionic dynamics is exceptionally challenging when quantum fluctuations are relevant (e.g., at low te ...

Solving native structures of such large molecules, like biomolecules, is often challenging, particularly due to the potentially infinite number of non-covalent interactions with water. In this thesis, we report the use of cold ion gas-phase action spectros ...

All coronaviruses are characterized by spike glycoproteins whose S1 subunits contain the receptor binding domain (RBD). The RBD anchors the virus to the host cellular membrane to regulate the virus transmissibility and infectious process. Although the prot ...

The structural complexity of glycans makes their characterization challenging, not only because of the presence of various isomeric forms of the precursor molecule but also because the fragments can themselves be isomeric. We have recently developed an IMS ...

The geometry of biomolecules isolated in the gas phaseusuallydiffers substantially from their native structures in aqueous solution,which are the only ones truly relevant to life science. To connectthe high resolution of cold ion spectroscopy that can be a ...

Polydimethylsiloxane (PDMS) based soft polymer optical fibers (POFs) have recently demonstrated their intriguing potential for different sensing applications like strain or temperature sensing. Recent studies have elaborated on the sensing capability of PD ...

Line ratio diagnostics provide valuable clues as to the source of ionizing radiation in galaxies with intense black hole accretion and starbursting events, such as local Seyfert galaxies or galaxies at the peak of their star formation history. We aim to pr ...

Spectroscopy and Conformational Preferences of Gas-Phase Helices

Chattez avec Graph Search

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The Pristine dwarf galaxy survey-V. The edges of the dwarf galaxy Hercules

Data and code associated with the paper 'Measurement-induced collective vibrational quantum coherence under spontaneous Raman scattering in a liquid'

Gas/Surface reactions probed by reflection absorption infrared spectroscopy

Indication of 310-Helix Structure in Gas-Phase Neutral Pentaalanine

Probing Water Dissociation and Oxygen Replacement on Partially Oxygen-Covered Cu(111) by Reflection Absorption Infrared Spectroscopy

Combining ion mobility spectrometry and cryogenic ion spectroscopy with enzymatic digestion/synthesis for the study of N-linked glycans

Wigner Gaussian dynamics: Simulating the anharmonic and quantum ionic motion

Bridging Native and Intrinsic Structures of Microhydrated Biomolecules by Cold Ion Spectroscopy

Secondary Structures of MERS-CoV, SARS-CoV, and SARS-CoV-2 Spike Proteins Revealed by Infrared Vibrational Spectroscopy

Multistage Ion Mobility Spectrometry Combined with Infrared Spectroscopy for Glycan Analysis

Revealing the Structure of Tryptophan in Microhydrated Complexes by Cold Ion Spectroscopy

Polydimethylsiloxane based soft polymer optical fibers: From the processing-property relationship to pressure sensing applications

Optical and mid-infrared line emission in nearby Seyfert galaxies