The Role of Percent Volume Buried in the Characterization of Copper(I) Complexes for Lighting Purposes

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Cupredoxins are widely occurring copper-binding proteins with a typical Greek-key beta barrel fold. They are generally described as electron carriers that rely on a T1 copper centre coordinated by four ligands provided by the folded polypeptide. The discov ...

One tetrahedral and two trigonal prismatic cages with π-basic Au3(pyrazolate)3 faces were obtained by connection of pre-formed gold complexes via dynamic covalent imine chemistry. The parallel arrangement of the Au3(pyrazolate)3 complexes in the prismatic ...

The synthesis of heterotrimetallic molecular cages is reported. The assemblies contain three types of coordination compounds: FeII clathrochelate complexes, AuI3(pyrazolate)3 complexes, and [PdII(pyridine)4]2+ complexes. The cages were obtained in a stepwi ...

Over the past decade, quantum photonics platforms aiming at harnessing the fundamental properties of single particles, such as quantum superposition and quantum entanglement, have flourished. In this context, single-photon emitters capable of operating at ...

The combination of palladium salts and bipyridyl ligands can lead to the formation of a large variety of coordination complexes, with different shapes and sizes, displaying a very versatile host-guest chemistry. Increasing their structural complexity remai ...

Structural and electronic factors are crucial to rationalizethedifferent N,O or N,N chelating coordination of pyrazolones containinga pyridine ring. The reactivity of proligand 3-phenyl-1-(pyridin-2-yl)-5-pyrazolone(HLpy,ph) with the (arene)Ru(II) fragment ...

Bent (hetero)allenes such as carbodicarbenes and carbodiphosphoranes can act as neutral C-donor ligands, and diverse applications in coordination chemistry have been reported. N-Heterocyclic diazoolefins are heterocumulenes, which can function in a similar ...

Near-infrared luminescent materials have recently received considerable attention for a large number of applications, including in solid-state lighting, as bioimaging agents, as photovoltaic cells, and in the telecommunication industry. By adding diverse e ...

This study investigates chloride binding in blended cement pastes exposed to 0.5 M NaCl solutions (with and without pH adjustment) using X-ray diffraction and energy-dispersive X-ray spectroscopy image analysis (edxia). The aim is to better understand the ...

Improving indoor lighting conditions at the workplace has the potential to support proper circadian entrainment of hormonal rhythms, sleep, and well-being. We tested the effects of optimized dynamic daylight and electric lighting on circadian phase of mela ...

In comparison with Ru-II-arene compounds, the medicinal potential of homologous Ru-II-tpm compounds [tpm = tris(pyrazolyl)methane] is underexplored. Pyridine, 4-pyridinemethanol and four functionalized pyridines, synthesized from the esterification of 4-py ...

The small Stokes shift and weak emission in the solid state are two main shortcomings associated with the boron-dipyrromethene (BODIPY) family of dyes. This study presents the design, synthesis and luminescent properties of boron difluoro complexes of 2-ar ...

Despite recent advances in the field of cyclic alkyl amino carbenes (CAACs) including a few complementary synthetic strategies affording CAACs with various substitution patterns, the application potential of chiral CAACs to efficiently catalyze asymmetric ...

To investigate the effect of different halogen substituents and leaving groups and the flexibility of ligands on the anticancer activity of copper complexes, sixteen copper(ii) complexes with eight different tridentate Schiff-base ligands containing pyridi ...

The present simulation case study compares the impact of electric lighting distributions in relation to work-desk location and orientation on work-plane and eye-level illumination within a small private office. The aim of this study is to better understand ...

The use of daylight in buildings is important because it contributes to energy savings by reducing the use of electric lighting and space heating. It also impacts on biological functions and on well-being. Indeed, light not only allows vision, but has non- ...

As the interest in design applications related to responses to light beyond vision is growing, two simulation tools, ALFA and Lark, have been developed to incorporate spectral characteristics of light in the evaluation of indoor lighting conditions. The sp ...

Turn-on time is a key factor for lighting devices to be of practical application. To decrease the turn-on time value of a deep-red light-emitting electrochemical cells (DR-LECs), two novel approaches based on molecularly engineered ruthenium phenanthroimid ...

Two pyrazole-based ligands bearing a pyridine moiety, 3-methyl-1-(pyridin-2-yl)-5-pyrazolone (HLpy), and 3methyl-1-(pyridin-2-yl)-4-trifluoroacetyl-5-pyrazolone (HQpy,CF3), were prepared and fully characterized in the solid-state and the tautomerism of bot ...

In this thesis, we exploited optical and X-ray pump-probe methods in a synergistic approach to study the interplay of the electronic, spin and structural degrees of freedom in two class of complex systems relevant for solar energy conversion applications: ...

The Role of Percent Volume Buried in the Characterization of Copper(I) Complexes for Lighting Purposes

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Beyond the coupled distortion model: structural analysis of the single domain cupredoxin AcoP, a green mononuclear copper centre with original features

Molecular imine cages with π-basic Au3(pyrazolate) faces

Stepwise synthesis of heterotrimetallic FeII/PdII/AuI coordination cages

Investigation of room-temperature single-photon emitters in GaN-based materials and GaN/AlN quantum dots

Palladium-based supramolecular assemblies: from complex structures to water-soluble anion-receptors

Steric and Electronic Effects Responsible for N,O- or N,N-Chelating Coordination of Pyrazolones Containing a Pyridine Ring in Ruthenium Arene Systems

Synthesis and Reactivity of an Anionic Diazoolefin

Full Solution Process of a Near-Infrared Light-Emitting Electrochemical Cell Based on Novel Emissive Ruthenium Complexes of 1,10-Phenanthroline-Derived Ligands and a Eutectic Alloy as the Top Electrode

Insights on chemical and physical chloride binding in blended cement pastes

Optimized office lighting advances melatonin phase and peripheral heat loss prior bedtime

Anticancer ruthenium(II) tris(pyrazolyl)methane complexes with bioactive co-ligands

Thiazole Boron Difluoride Dyes with Large Stokes Shift, Solid State Emission and Room-Temperature Phosphorescence

Chiral Cyclic Alkyl Amino Carbene (CAAC) Transition-Metal Complexes: Synthesis, Structural Analysis, and Evaluation in Asymmetric Catalysis

Copper(ii) complexes with tridentate halogen-substituted Schiff base ligands: synthesis, crystal structures and investigating the effect of halogenation, leaving groups and ligand flexibility on antiproliferative activities

The Impact of Light Distribution and Furniture Layout on Meeting Light Exposure Objectives in an Office – A Simulation Case Study

Integrating non-visual effects of light in the automated daylight-responsive control of blinds and electric lighting

Validation of Spectral Simulation Tools for the Prediction of Indoor Electric Light Exposure

High-Efficiency Deep-Red Light-Emitting Electrochemical Cell Based on a Trinuclear Ruthenium(II)-Silver(I) Complex

Arene-ruthenium(II) complexes with pyrazole-based ligands bearing a pyridine moiety: Synthesis, structure, DFT calculations, and cytotoxicity

Photo- and thermally-induced electronic and structural dynamics in perovskites and transition metal oxides