Publication

Effects of High Angular Momentum on the Unimolecular Dissociation of CD2CD2OH: Theory and Comparisons with Experiment

Publications associées (32)

Robust Collaborative Learning with Linear Gradient Overhead

Rachid Guerraoui, Le Nguyen Hoang, John Stephan, Sadegh Farhadkhani, Nirupam Gupta, Rafaël Benjamin Pinot

Collaborative learning algorithms, such as distributed SGD (or D-SGD), are prone to faulty machines that may deviate from their prescribed algorithm because of software or hardware bugs, poisoned data or malicious behaviors. While many solutions have been ...

PLMR2023

Quantum state-resolved methane scattering from Ni(111) and NiO(111) by bolometer infrared laser tagging: The effect of surface oxidation

Rainer Beck, Bo-Jung Chen, Patrick Floss, Christopher Scott Reilly

We describe a novel UHV state-to-state molecule/surface scattering apparatus with quan- tum state preparation of the incident molecular beam and angle-resolved quantum state detection of the scattered molecules. State resolved detection is accomplished usi ...

2023

Hypervalent Iodine: New Reagents and Functionalization of Peptides

Eliott Hugo Joran Le Du

Alkynes are found in a multitude of natural or synthetic bioactive compounds. In addition to the capacity of these chemical motifs to impact the physicochemical properties of a molecule of interest, the well-established reactivity of alkynes makes them ide ...

EPFL2023

Charging and Electric Field Effects on Hydrogen Molecules Physisorbed on Graphene

Klaus Kern, Shai Mangel, Alessio Scavuzzo, Tobias Wollandt

Molecular hydrogen adsorbed on graphene was investigated by analyzing rotational excitation spectra obtained with a gate-tunable scanning tunneling microscope (STM). Through the shift of the rotational excitation energy, the tunability of physisorbed H2 on ...

AMER CHEMICAL SOC2023

Strength and timing of primary and secondary vortices generated by a rotating plate

Karen Ann J Mulleners, Diego Francescangeli

Accurate predictions of how vortices grow, evolve, and separate from aerodynamic objects are desirable for various applications ranging from autonomous aerial vehicles to wind turbines. Here, we present an experimental characterisation of the formation pro ...

2023

Emergent non-Hermitian localization phenomena in the synthetic space of zero-dimensional bosonic systems

Fabrizio Minganti

Phase transitions in non-Hermitian systems are at the focus of cutting edge theoretical and experimental research. On the one hand, parity-time- (PT-) and anti-PT-symmetric physics have gained ever-growing interest, due to the existence of non-Hermitian sp ...

AMER PHYSICAL SOC2023

Valence Orbitals Driving the Spin Dynamics in a Rare-Earth Single-Atom Magnet

Harald Brune, François Patthey, Stefano Rusponi, Marina Pivetta, Dante Philippe Sblendorio, Alberto Curcella

We combine spin-polarized scanning tunneling microscopy with quantum master equation analysis to investigate the spin dynamics of the single atom magnet Dy on graphene/Ir(111). By performing reading and writing experiments, we show that the strongly spin p ...

AMER PHYSICAL SOC2023

Evaluation of the role of superoxide radical as chain carrier for the formation of hydroxyl radical during ozonation

Gang Yu, Urs von Gunten, Yan Wang

Superoxide radicals (O-2(center dot-)) have been suggested as an important chain carrier in the radical chain reaction that promotes ozone (O-3) decomposition to hydroxyl radicals ((OH)-O-center dot) during ozonation. However, due to the difficulty in meas ...

PERGAMON-ELSEVIER SCIENCE LTD2023

Interactive-time Exploration, Querying, and Analysis of Large High-dimensional Datasets

Sachin Basil John

In the current era of big data, aggregation queries on high-dimensional datasets are frequently utilized to uncover hidden patterns, trends, and correlations critical for effective business decision-making. Data cubes facilitate such queries by employing p ...

EPFL2023

Scalable and Privacy-Preserving Federated Principal Component Analysis

Jean-Pierre Hubaux, Jean-Philippe Léonard Bossuat, David Jules Froelicher, Joao André Gomes de Sá e Sousa, Juan Ramón Troncoso-Pastoriza, Apostolos Pyrgelis

Principal component analysis (PCA) is an essential algorithm for dimensionality reduction in many data science domains. We address the problem of performing a federated PCA on private data distributed among multiple data providers while ensuring data confi ...

IEEE COMPUTER SOC2023

Widespread detection of chlorine oxyacids in the Arctic atmosphere

Julia Schmale, Ivo Fabio Beck, Hélène Paule Angot

Observations are reported of HClO3 and HClO4 in the atmosphere and their widespread occurrence over the pan-Arctic during spring, providing further insights into atmospheric chlorine cycling in the polar environment. ...

Nature Portfolio2023

Twisting instabilities in elastic ribbons with inhomogeneous pre-stress: A macroscopic analog of thermodynamic phase transition

Pedro Miguel Nunes Pereira de Almeida Reis, Michael Christopher Gomez

We study elastic ribbons subject to large, tensile pre-stress confined to a central region within the cross-section. These ribbons can buckle spontaneously to form helical shapes, featuring regions of alternating chirality (phases) that are separated by so ...

PERGAMON-ELSEVIER SCIENCE LTD2023