Publication

Biphasic catalysis in aqueous and ionic liquid media

Publications associées (30)

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A rapidly growing population and industrialization have caused the exploitation of natural resources in keeping with fossil fuels shortage. Due to the combustion of fossil fuels, the concentration of CO2 in the earth's atmosphere, which is a potent greenho ...

EPFL2015

Heterogeneous Silica-Supported Ruthenium Phosphine Catalysts for Selective Formic Acid Decomposition

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The water-soluble ruthenium(II)–mTPPTS complex (mTPPTS= meta-trisulfonated triphenylphosphine) efficiently catalyzes the generation of hydrogen from formic acid in aqueous solution. This catalyst has been immobilized in a hydrophilic silica sup- port to fa ...

Wiley-VCH Verlag2013

Formic acid as a hydrogen source – recent developments and future trends

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Formic acid has recently been suggested as a promising hydrogen storage material. The basic concept is briefly discussed and the recent advances in the development of formic acid dehydrogenation catalysts are shown. Both the state of research for heterogen ...

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Imidazolium salts with aromatic groups 1,3-bis(9-anthracenylmethyl)imidazolium chloride ([Bamim]Cl), 1,3-bis(1-naphthalenylmethyl)imidazolium chloride ([Bnmim]Cl) and 1,3-bis( benzylmethyl)imidazolium chloride ([Bbmim]Cl) were reacted with PdCl2 forming th ...

Elsevier2012

Extents of Reaction and Mass Transfer in the Analysis of Chemical Reaction Systems

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Monitoring, control and optimization of chemical reaction systems often requires in-depth analysis of the underlying reaction mechanisms. This dissertation investigates appropriate tools that facilitate the analysis of homogeneous and gas-liquid reaction s ...

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Recent Advances in the Liquid-Phase Synthesis of Metal Nanostructures with Controlled Shape and Size for Catalysis

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Recent advances in the liquid-phase synthesis of metal nanostructures of different sizes and shapes are reviewed regarding their catalytic properties. The controlled synthesis of nanostructures is based on the colloid chemistry techniques in the solution, ...

2009

Suzuki Coupling Reactions in Ether-Functionalized Ionic Liquids: The Importance of Weakly Interacting Cations

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Imidazolium- and pyridinium-based ionic liqs. with ether/polyether substituents have been evaluated as solvents for palladium-catalyzed Suzuki C-C coupling reactions. In general, reactions proceed more efficiently in these solvents compared to other ionic ...

2008

Design, synthesis and applications of functionalized ionic liquids

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Room temperature ionic liquids (RTILs), considered as "designers' solvents", are attracting a great attention because of their possibility to be tailored based on property requirements. The ionic liquids designed and synthesized for carrying out specified ...

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Structured fiber supports for ionic liquid-phase catalysis used in gas-phase continuous hydrogenation

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Structured supported ionic liquid-phase (SSILP) catalysis is a new concept with the advantages of ionic liquids (ILs) used as solvents for homogeneous catalyst and the further benefits of structured heterogeneous catalysts. This is achieved by confining th ...

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Applications of functionalized ionic liquids

Dongbin Zhao, Zhaofu Fei, Xuan Li

Recent developments of the synthesis and applications of functionalized ionic liqs. (including dual-functionalized ionic liqs.) have been highlighted in this review. Ionic liqs. are attracting attention as alternative solvents in green chem., but as more f ...

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