Principal Descriptors of Ionic Liquid Co-catalysts for the Electrochemical Reduction of CO2

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The electrochemical reduction of carbon dioxide (CO2RR) currently attracts considerable attention as a way to make fuels and value-added products from CO2 using renewable energy. Much effort has been devoted to developing efficient electrode materials for ...

In a recent article entitled "Solubility Parameter of Carbon Dioxide-an Enigma"[1], Marcus reported the literature values for the solubility parameter of liquid carbon dioxide (CO2) at 298 K with discrepancies as large as 200%. An analogous article on ioni ...

The intrinsic stability of the 5 V LiCoPO4-LiCo2P3O10 thin-film (carbon-free) cathode material coated with MoO3 thin layer is studied using a comprehensive synchrotron electron spectroscopy in situ approach combined with firstprinciple calculations. The at ...

The world needs to move from a fossil fuel to a renewable energy based society. With the increasing electricity production from wind and PV, short and long term energy storage are becoming one of challenge of the 21st century. While batteries are the prefe ...

Electrochemical reduction of carbon dioxide is a promising approach to decrease the amount of anthropogenic CO2 being released into the atmosphere, provided that a surplus of renewable electrical energy is available. Copper based materials are at the cente ...

The electrochemical reduction of CO2 (CO2RR) into valuable products represents a step towards alleviating global warming and the energy crisis. However, the sluggish kinetics of the CO2RR and the competitive hydrogen evolution reaction (HER) still limit th ...

Gas separation is one of the most important industrial processes and is poised to take a larger role in the transition to renewable energy, e.g., carbon capture and hydrogen purification. Conventional gas separation processes involving cryogenic distillati ...

Organic radicals are highly active species that can undergo various transformations. Electrochemistry and photochemistry are efficient methods for the generation of these species of high energy, through single electron transfer processes under mild conditi ...

The reduction of carbon dioxide to desirable products is an urgent goal in favour of the environment, the energy-cycle and mankind. We report the electrochemical reduction of CO2 to carbon monoxide by means of the ho-mogeneous electrocatalyst (1), [Ru(bpy) ...

The implementation of an electrochemical flow cell has enabled improved efficiency for CO2 reduction. However, in situ spectroscopic insights into the interface are still lacking. Here, we investigate a series of copper layers with different thicknesses on ...

In this work, we identify the importance of C-60 and compact-TiO2 (cTiO(2)) as electron transport layers on the device performance of coevaporated n-i-p perovskite solar cells. We found (1) a synergetic effect between both layers when extracting the charge ...

Utilizing earth-abundant metals to design economical and efficient electrocatalysts for cathodic hydrogen evolution reaction (HER) and anodic oxygen evolution reaction (OER) is critical for acquiring clean hydrogen energy by the electrochemical overall wat ...

Non-invasive and semi-invasive bioimaging is of great interest for the rapid diagnosis and efficient as well as specific treatments of biological systems affecting human health, such as cancer tissue and biofilms. Electrochemical bioimaging is one of the d ...

Water management by gas diffusion electrodes is a fundamental aspect of the performance of electrochemical cells. Herein, we introduce the characteristic constrictions size as a descriptor for microporous layers (MPL). This parameter is calculated by volum ...

The electrochemical reduction of carbon dioxide (CO2RR) has attracted enormous interest because of the energy crisis and climate change; however, more efficient catalysts are required for practical applications. Herein, we present electrospinning as a faci ...

The coulombic repulsion between two adjacent cation centres of 1,2-carbodications is known to decrease with pi- and/or n-donor substituents by a positive charge delocalization. Here we report the delocalization of the positive charge of transient 1,2-carbo ...

Electroreduction of carbon dioxide (CO2) in a flow electrolyzer represents a promising carbon-neutral technology with efficient production of valuable chemicals. In this work, the catalytic performance of polycrystalline copper (Cu), Cu2O-derived copper (O ...

The adsorption behavior of beta-nicotinamide adenine dinucleotide (NADH) at the carbon/electrolyte interface has been studied using a combination of neutron reflectometry (NR) and solution depletion isotherms. Coupling the NR technique with an electrochemi ...

The water-in-salt approach has expanded the electrochemical stability window of aqueous electrolytes, enabling novel aqueous batteries with relatively high cell voltages and energy densities. However, the stability of these electrolytes tends to be overest ...

Principal Descriptors of Ionic Liquid Co-catalysts for the Electrochemical Reduction of CO2

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The Role of Organic Promoters in the Electroreduction of Carbon Dioxide

The solubility parameters of carbon dioxide and ionic liquids: Are they an enigma?

Energy Level Alignment at the Cobalt Phosphate/Electrolyte Interface: Intrinsic Stability vs Interfacial Chemical Reactions in 5 V Lithium Ion Batteries

Decreasing the Stability of Borohydride with Ionic Liquids for Hydrogen Storage and Carbon Dioxide Conversion

Monitoring and understanding Cu catalyst dissolution during CO2 electroreduction

Electrospun nanofibers for electrochemical reduction of CO2: A mini review

Gas Separation Membranes with Atom-Thick Nanopores: The Potential of Nanoporous Single-Layer Graphene

Copper-catalyzed transformations of carboradicals generated by electrochemical and photochemical methods: oxidative amination and polyfluoroarylation

Electrochemically CO2 conversion using homogeneous and nanostructured heterogeneous Ru (II) electrocatalysts

New Insights into the Interface of Electrochemical Flow Cells for Carbon Dioxide Reduction to Ethylene

C-60 Thin Films in Perovskite Solar Cells: Efficient or Limiting Charge Transport Layer?

Universal Strategy of Bimetal Heterostructures as Superior Bifunctional Catalysts for Electrochemical Water Splitting

Electrochemical imaging of metabolic activity in tissue and biofilms

On the role of pore constrictions in gas diffusion electrodes

Synergistic Cu/CeO2 carbon nanofiber catalysts for efficient CO2 electroreduction

Trisubstituted geminal diazaalkene derived transient 1,2-carbodications

Revisiting the Impact of Morphology and Oxidation State of Cu on CO2 Reduction Using Electrochemical Flow Cell

Adsorption Behavior of the Coenzyme NADH at the Carbon/ Electrolyte Interface Determined by Neutron Reflectometry

Perspective-Electrochemical Stability of Water-in-Salt Electrolytes