Precipitation fate and transport in a Mediterranean catchment through models calibrated on plant and stream water isotope data

To predict hydrologic responses to inputs and perturbations, it is important to understand how precipitation is stored in catchments, released back to the atmosphere via evapotranspiration (ET), or transported to aquifers and streams. We investigated this partitioning of precipitation using stable isotopes of water (O-18) at the Can Vila catchment in the Spanish Pyrenees mountains. The isotope data covered four years of measurements, comprising > 550 rainfall and > 980 stream water samples, capturing intra-event variations. They were complemented by fortnightly plant water isotope data sampled over eight months. The isotope data were used to quantify how long it takes for water to become evapotranspiration or to be discharged as streamflow using StorAge Selection (SAS) functions. We calibrated the SAS functions using a conventional approach fitting the model solely to stream water isotope data and a multi-objective calibration approach in which the model was simultaneously fitted to tree xylem water isotope data.