Synthesis of propargyl silanes from terminal alkynes via a migratory Sonogashira reaction

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In contrast to the well-studied 1-vinylcyclobu- tanols, the reactivity of 3-vinylazetidin-3-ols 1 and 3- vinyloxetan-3-ols 2 under transition metal catalysis remains largely unexplored. We report herein their unique reactivity under dual palladium and acid ...

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An asymmetric 3-component reaction between EthynylBenziodoXoles (EBXs), 2,2,2-trifluorodiazoethane and nucleophiles catalyzed by a CuI-BOX (Bisoxazoline) catalyst is described. This protocol gives access to chiral trifluoromethylated propargyl ethers and a ...

We report a copper-catalyzed alkynylation of azadipeptides using ethynylbenziodoxolone (EBX) reagents. Nonsymmetrical ynehydrazides could be obtained in 25–97% yield using azaglycine derivatives as nucleophiles. The transformation is compatible with most f ...

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A Pd-catalyzed method based on the use of a molecular tether is described for olefin difunctionalization. Enabled by an easily introduced trifluoroacetaldehyde-derived tether, a simultaneous introduction of oxygen and nitrogen heteroatoms across unsaturate ...

Synthesis of propargyl silanes from terminal alkynes via a migratory Sonogashira reaction

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Novel Alkynylation Methods through the Combination of Hypervalent Iodine Reagents and Alkynyl-trifluoroborate Salts

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Palladium-based supramolecular assemblies: from complex structures to water-soluble anion-receptors

Solvent- and catalyst-free reduction of CO2 with ammonia borane

Development of Hetero-Vinylbenziodoxolone Reagents for Applications in Synthetic Methodology and Biomolecule Functionalization

Synthesis, isolation and application of a sila-ketenyl anion

Hypervalent Iodine: New Reagents and Functionalization of Peptides

Recent progress in alkynylation with hypervalent iodine reagents

Synthesis and Applications of Ynimines and Enantioselective Total Synthesis of Artatrovirenol A

Diverting the 5-exo-Trig Oxypalladation to Formally 6-endo-Trig Fluorocycloetherification Product through 1,2-O/Pd(IV) Dyotropic Rearrangement

Terminal Alkynes as One-Carbon Donors in [5+1] Heteroannulation: Synthesis of Pyridines via Ynimine Intermediates and Application in the Total Synthesis of Anibamine B

Synthesis and application of bifunctional hypervalent iodine reagents for peptide modification

Copper (I)‐BOX Catalyzed Asymmetric 3‐Component Reaction for the Synthesis of Trifluoromethylated Propargylic Ethers and Anilines**

Copper-Catalyzed Alkynylation of Hydrazides: An Easy Access to Functionalized Azadipeptides

Palladium-Catalyzed trans-Hydroalkoxylation: Counterintuitive Use of an Aryl Iodide Additive to Promote C-H Bond Formation

Radical Alkynylations with EthynylBenziodoXolones: From Photocatalysis to Direct Excitation

Exploring Photoredox-Catalyzed (Re)functionalizations with Core-Modified Benziodoxolones

Chiral control of spin-crossover dynamics in Fe (II) complexes

Development of metal-organic frameworks based on N-heterocyclic ligands

Pd(II)-Catalyzed Aminoacetoxylation of Alkenes Via Tether Formation