Multicomponent Assembly of Boronic Acid-Based Macrocycles, Cages, and Polymers

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In the modern world, soft robots are gaining importance with technological advances. Compared to rigid robots, their elasticity enables safer and more adaptable integration into various systems, making them suitable for wearable devices, biomedical enginee ...

Mechanochemistry harnesses mechanical force to facilitate chemical reactions. Traditionally, the field of polymer mechanochemistry has used methods to activate chemical bonds, which use forces that are larger than those that are required to break a covalen ...

The combination of palladium salts and bipyridyl ligands can lead to the formation of a large variety of coordination complexes, with different shapes and sizes, displaying a very versatile host-guest chemistry. Increasing their structural complexity remai ...

The invention relates to a method for converting a polymer into hydrocarbon compounds, comprising the steps of a. contacting the polymer with a catalyst to provide a reaction mixture, wherein the polymer contains nitrogen in the polymer backbone, wherein t ...

A dinuclear metal-organic cage with four acrylate side chains was prepared by self-assembly. Precipitation polymerization of the cage with N-isopropylacrylamide yielded a thermoresponsive nanogel. The host properties of the cage were retained within the ge ...

One tetrahedral and two trigonal prismatic cages with π-basic Au3(pyrazolate)3 faces were obtained by connection of pre-formed gold complexes via dynamic covalent imine chemistry. The parallel arrangement of the Au3(pyrazolate)3 complexes in the prismatic ...

Macrocycles offer an attractive format for drug development due to their good binding properties and potential to cross cell membranes. To efficiently identify macrocyclic ligands for new targets, methods for the synthesis and screening of large combinator ...

Metal-porphyrins are studied intensively due their potential applications, deriving from the variety of electronic and chemical properties, tunable by selecting metal centers and functional groups. Metalation, de- and trans-metalation processes are fundame ...

State-specific complete active space self-consistent field (SS-CASSCF) theory has emerged as a promising route to accurately predict electronically excited energy surfaces away from molecular equilibria. However, its accuracy and practicality for chemical ...

Macrocycles provide an attractive modality for drug development but the identification of ligands to targets of interest is hindered by the lack of large macrocyclic compound libraries for high-throughput screening. A strategy to efficiently synthesize lar ...

The emergence of mycelium-bonded biocomposites has been stimulated in the quest for sustainable development. These biocomposites exhibit enhanced mechanical properties through hot pressing, with mycelium playing a crucial role as both the adhesive and rein ...

Low Urinary Tract Dysfunctions (LUTD) and in particular Urinary Incontinence (UI) is a medical condition affecting millions of people worldwide. In this context researchers and engineers performed tests on porcine and human urethras. However, ethical conce ...

Thin polymer coatings present a method to modify the surface properties of underlying substrates. Polymer-coated surfaces have been used as anticorrosive materials, surfaces with special wetting properties, antifriction materials, and as materials for biom ...

Thermoset rubbers give rise to elastomers with tunable stiffness and high resilience but are not recyclable. Thermoplastic elastomers can address this problem but their broad applicability is impeded by either limited operating temperatures or inferior ela ...

Supramolecular interactions play an important role in defining the structure and the resulting mechanical properties of materials. For instance, interchain hydrogen-bonding in PAs gives them superior strength and stiffness in engineering materials, while t ...

The wetting dynamics of molten thermoplastic polymers, which are known to influence the force balance of the triple line, are not understood properly despite their importance in many industrial processes. In particular, the influence of the molecular weigh ...

Polymer brushes, which are polymers anchored to a solid substrate by one chainend, have the ability to modify the properties of an underlying substrate, offering intriguing features such as enhanced lubrication, reduced friction, colloidal stability, and a ...

One of the main goals of organometallic chemistry in the last decades was the activation of small molecule in mild reaction conditions. Even though multiple examples of catalytic cycles able to produce fine chemicals from cheap and abundant sources using t ...

The design of metal-organic frameworks (MOFs) having large pore sizes and volumes often requires the use of complex organic ligands, currently synthesized using costly and time-consuming palladium-catalyzed coupling chemistry. Thus, in the present work, a ...

Melt electrowriting is a microscale manufacturing technique that uses polymer-based melts to create fibrous structures. An electric field is used to stabilize a continuous molten jet, which is then written onto a substrate as a microscale fiber. Herein, it ...

Multicomponent Assembly of Boronic Acid-Based Macrocycles, Cages, and Polymers

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High Permittivity Polysiloxanes and Polyphosphazenes for Actuator Applications

Soft Mechanochemistry of Disulfide-Crosslinked Polymer Networks

Palladium-based supramolecular assemblies: from complex structures to water-soluble anion-receptors

Method for converting nitrogen-containing polymers into hydrocarbon compounds

Nanogels with Metal‐Organic Cages as Functional Crosslinks

Molecular imine cages with π-basic Au3(pyrazolate) faces

Large Libraries of Structurally Diverse Macrocycles Suitable for Membrane Permeation

Stabilization versus competing de-metalation, trans-metalation and (cyclo)-dehydrogenation of Pd porphyrins at a copper surface

Excited State-Specific CASSCF Theory for the Torsion of Ethylene

Methods for high-throughput synthesis and screening of peptide libraries

Investigation of mycelium film as the adhesive for poplar veneer bonding: insight into interfacial bonding mechanisms

Characterisation of Polymer Materials for the Development of an Artificial Urethra

Supramolecular Polymer Brushes

Reinforced Supramolecular Networks of End Functionalized Polymers for Tailored Thermomechanical Property Profiles

Supramolecular Modifications of Semicrystalline Polymers

Influence of the molecular weight and physical properties of a thermoplastic polymer on its dynamic wetting behavior

Architecturally Diverse Polymer Brushes Prepared via Surface-Initiated Atom Transfer Radical Polymerization

Tuning the reactivity of uranium towards small molecules in multimetallic complexes

A Simple, Transition Metal Catalyst-Free Method for the Design of Complex Organic Building Blocks Used to Construct Porous Metal-Organic Frameworks

Effects of Electrode Design on the Melt Electrowriting of Sinusoidal Structures