Designing Simple Tridentate Ligands for Highly Luminescent Europium Complexes

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Cupredoxins are widely occurring copper-binding proteins with a typical Greek-key beta barrel fold. They are generally described as electron carriers that rely on a T1 copper centre coordinated by four ligands provided by the folded polypeptide. The discov ...

The combination of palladium salts and bipyridyl ligands can lead to the formation of a large variety of coordination complexes, with different shapes and sizes, displaying a very versatile host-guest chemistry. Increasing their structural complexity remai ...

We use James Webb Space Telescope Near-Infrared Camera Wide Field Slitless Spectroscopy (NIRCam WFSS) and the Near-Infrared spectrograph (NIRSpec) in the Cosmic Evolution Early Release survey to measure rest-frame optical emission-line ratios of 155 galaxi ...

A dinuclear metal-organic cage with four acrylate side chains was prepared by self-assembly. Precipitation polymerization of the cage with N-isopropylacrylamide yielded a thermoresponsive nanogel. The host properties of the cage were retained within the ge ...

We report the identification of 64 new candidates of compact galaxies, potentially hosting faint quasars with bolometric luminosities of L-bol = 10(43)-10(46) erg s(-1), residing in the reionization epoch within the redshift range of 6 less than or similar ...

Dual photoredox−transition-metal catalysis has emerged as a powerful tool for the development of chemical transformations. However, its application in the selective difunctionalization of 1,3-dienes remains essentially unexploited. By the synergistic actio ...

Structural and electronic factors are crucial to rationalizethedifferent N,O or N,N chelating coordination of pyrazolones containinga pyridine ring. The reactivity of proligand 3-phenyl-1-(pyridin-2-yl)-5-pyrazolone(HLpy,ph) with the (arene)Ru(II) fragment ...

Pd-catalyzed cyclizative functionalization of γ-hydroxyalkenes affords tetrahydrofuran derivatives via a key 5-exo-trig oxypalladation step. Herein, we report a palladium(II)-catalyzed, Selectfluor-mediated formal 6-endo-trig fluorocycloetherification of γ ...

Ynolates or ketenyl anions, [RCCO]-, are negatively charged reactive intermediates, which can be generated in situ and used for divergent chemical transformations. Ynolates can react either at the oxygen or carbon centres or across the C-C triple bond, mak ...

Bent (hetero)allenes such as carbodicarbenes and carbodiphosphoranes can act as neutral C-donor ligands, and diverse applications in coordination chemistry have been reported. N-Heterocyclic diazoolefins are heterocumulenes, which can function in a similar ...

The isomerization of iridium(III) complexes with metalated N-heterocyclic carbene (NHC) ligands was studied. The fac isomers of complexes with 1-phenyl-3-methylbenzimidazolin-2-ylidene or 1-phenyl-3-benzylbenzimidazolin-2-ylidene ligands are transformed cl ...

One of the main goals of organometallic chemistry in the last decades was the activation of small molecule in mild reaction conditions. Even though multiple examples of catalytic cycles able to produce fine chemicals from cheap and abundant sources using t ...

We have investigated the cosmological constraints that can be expected from measurement of the cross-correlation of galaxies with cosmic voids identified in the Euclid spectroscopic survey, which will include spectroscopic information for tens of millions ...

Near-infrared luminescent materials have recently received considerable attention for a large number of applications, including in solid-state lighting, as bioimaging agents, as photovoltaic cells, and in the telecommunication industry. By adding diverse e ...

Most large galaxies contain Super Massive Black Holes at their centers, drawing matter nearby to form swirling accretion disks emitting electromagnetic radiation. These are Active Galactic Nuclei. The brightest quasars are the most luminous Universe object ...

Mid-infrared (mid-IR) observations are powerful in identifying heavily obscured active galactic nuclei (AGN) that have weak emission in other wavelengths. Data from the Mid-Infrared Instrument (MIRI) on board the James Webb Space Telescope provides an exce ...

Cobalt(II) complexes featuring hexadentate amino-pyridyl ligands have been recently discovered as highly active catalysts for the Hydrogen Evolution Reaction (HER), whose high performance arises from the possibility of assisting proton transfer processes v ...

The Dark Energy Spectroscopic Instrument (DESI) Survey has obtained a set of spectroscopic measurements of galaxies to validate the final survey design and target selections. To assist in these tasks, we visually inspect DESI spectra of approximately 2500 ...

Recent observations have shown that the environmental quenching of galaxies at z & SIM; 1 is qualitatively different to that in the local Universe. However, the physical origin of these differences has not yet been elucidated. In addition, while low-redshi ...

We report on the discovery of two low-luminosity, broad-line active galactic nuclei (AGNs) at z > 5 identified using JWST NIRSpec spectroscopy from the Cosmic Evolution Early Release Science (CEERS) survey. We detect broad Ha emission in the spectra of bot ...

Designing Simple Tridentate Ligands for Highly Luminescent Europium Complexes

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Beyond the coupled distortion model: structural analysis of the single domain cupredoxin AcoP, a green mononuclear copper centre with original features

Palladium-based supramolecular assemblies: from complex structures to water-soluble anion-receptors

CEERS Key Paper. VIII. Emission-line Ratios from NIRSpec and NIRCam Wide-Field Slitless Spectroscopy at z > 2

Nanogels with Metal‐Organic Cages as Functional Crosslinks

Tracing the rise of supermassive black holes A panchromatic search for faint, unobscured quasars at z ≥ 6 with COSMOS-Web and other surveys

Dual Photoredox and Copper Catalysis: Enantioselective 1,2-Amidocyanation of 1,3-Dienes

Steric and Electronic Effects Responsible for N,O- or N,N-Chelating Coordination of Pyrazolones Containing a Pyridine Ring in Ruthenium Arene Systems

Diverting the 5-exo-Trig Oxypalladation to Formally 6-endo-Trig Fluorocycloetherification Product through 1,2-O/Pd(IV) Dyotropic Rearrangement

Synthesis, isolation and application of a sila-ketenyl anion

Synthesis and Reactivity of an Anionic Diazoolefin

The acid-mediated isomerization of iridium(iii) complexes with cyclometalated NHC ligands: kinetic vs. thermodynamic control

Tuning the reactivity of uranium towards small molecules in multimetallic complexes

Euclid: Cosmology forecasts from the void-galaxy cross-correlation function with reconstruction

Full Solution Process of a Near-Infrared Light-Emitting Electrochemical Cell Based on Novel Emissive Ruthenium Complexes of 1,10-Phenanthroline-Derived Ligands and a Eutectic Alloy as the Top Electrode

Strong and micro lensing in distant quasars

CEERS Key Paper. VI. JWST/MIRI Uncovers a Large Population of Obscured AGN at High Redshifts

Electro- and photochemical H-2 generation by Co(ii) polypyridyl-based catalysts bearing ortho-substituted pyridines

The DESI Survey Validation: Results from Visual Inspection of Bright Galaxies, Luminous Red Galaxies, and Emission-line Galaxies

GOGREEN: A critical assessment of environmental trends in cosmological hydrodynamical simulations at z approximate to 1

Hidden Little Monsters: Spectroscopic Identification of Low-mass, Broad-line AGNs at z> 5 with CEERS