In-situ cross-linkable hole transporting triazatruxene monomers for optoelectronic devicestr

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Molecular Engineering of Copper Phthalocyanines: A Strategy in Developing Dopant-Free Hole-Transporting Materials for Efficient and Ambient-Stable Perovskite Solar Cells

Ulf Anders Hagfeldt, Xiaoqing Jiang

Copper (II) phthalocyanines (CuPcs) have attracted growing interest as promising hole-transporting materials (HTMs) in perovskite solar cells (PSCs) due to their low-cost and excellent stability. However, the most efficient PSCs using CuPc-based HTMs repor ...

WILEY-V C H VERLAG GMBH2019

Perovskite Solar Cells Based on Oligotriarylamine Hexaarylbenzene as Hole-Transporting Materials

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt

A cobalt-catalyzed cyclotrimerization of bis(aryl)alkyne is used as an innovative tool to obtain hole-transport materials (HTMs). The novel HTM containing six units of oligotriarylamine (HAB1), characterized by UV-vis, cyclic voltammetry, DFT, and thermogr ...

AMER CHEMICAL SOC2019

Charge carrier and exciton dynamics within hybrid lead halide perovskites of mixed composition and dimensionality

Marine Eva Fedora Bouduban

Research is nowadays usually directed by its potentiality to birth technological applications of relevance in the present environmento-socio-economical context, which can be seen as fair. This can however appear frustrating to us scientists, as it sometime ...

EPFL2019

Zr-doped indium oxide electrodes: Annealing and thickness effects on microstructure and carrier transport

Christophe Ballif, Aïcha Hessler-Wyser, Mathieu Gérard Boccard, Quentin Thomas Jeangros, Monica Morales Masis, Oscar Esteban Rucavado Leandro, Federica Landucci

Zr-doped indium oxide (In2O3:Zr) has been shown to satisfy the requirements of low resistance, wide band gap, and high infrared transmittance for application as a front contact in broadband solar cells. However, the reduction of indium usage in front of tr ...

AMER PHYSICAL SOC2019

Dispiro-oxepine/thiapine derivatives for optoelectronic semiconductors

Mohammad Khaja Nazeeruddin, Sanghyun Paek, Kasparas Rakstys

The dispiro-oxepine/dispiro-thiapine derivatives for optoelectronic semiconductors is a compound based on a structure having a functionalized dispiro compound of formula (Ia) or (Ib) with the core unit being a seven-membered heterocycle oxepine or thiapine ...

2018

Hole transporting organic molecules containing enamine groups for optoelectronic and photoelectrochemical devices

Sanghyun Paek, Kasparas Rakstys

The present invention relates to a compound of formula (I) based on enamine derivatives and used as organic hole conductors or hole transporting material in an optoelectronic or photoelectrochemical device. The present invention relates to the hole transpo ...

2018

Defect chemistry of methylammonium lead iodide

Alessandro Senocrate

The present work deals with the defect chemistry and charge transport properties in halide perovskites, and in particular in the archetypal methylammonium lead iodide. These materials are extensively researched due to their very promising application as li ...

EPFL2018

Stretchable and Highly Bendable Thin Film Transistors Based on Atomically Thin Chemical Vapor Deposited Molybdenum Disulfide

Yen-Cheng Kung

Two-dimensional (2D) materials have received tremendous research attention recently, as they possess peculiar physical properties in their monolayer and few-layer forms, which further lead to novel applications. A wide range of 2D materials covers insulato ...

EPFL2018

Inorganic hole conductor based perovskite photoelectric conversion device with high operational stability at long term

Michael Graetzel, Shaik Mohammed Zakeeruddin, Mohammad Ibrahim Dar, Neha Arora

The invention relates to an optoelectronic and/or photoelectrochemical device comprising a conductive support layer, n-type semiconductor, a sensitizer or light-absorber layer, a hole transporting layer, a spacer layer and a back contact, wherein the n-typ ...

2018

What Limits Mobility in Hydrogenated Indium Oxide?

Monica Morales Masis, Laura Ding, Michael Elias Stückelberger, Fabien Paul Jacques Dauzou

Understanding the electron scattering mechanisms dominating transport in high and low mobility transparent conducting oxides can provide insight into improving the properties of this crucial photovoltaic device layer. Contributions from ionized impurity sc ...

IEEE2018

Molecularly Engineered Hole Transporting Materials for High Performance Perovskite Solar Cells

Kasparas Rakstys

Perovskite solar cells have rapidly revolutionized the photovoltaic research showing an im-pressively dynamic progress on power conversion efficiency from 3.8 to 22% in only several years, a record for a nascent technology. Furthermore, inexpensive precurs ...

EPFL2018