Artificial Metalloenzymes with Multiple Catalytic Sites for Tandem or Synergistic Transformations

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Protein therapeutics have enormous potential for transforming the treatment of intracellular cell disorders, such as genetic disorders and cancers. Due to proteins’ cell-membrane impermeability, protein-based drugs against intracellular targets require eff ...

N-Heterocyclic carbenes (NHCs) are preferred ligands in numerous transformations involving various transition metals. Despite their broad utility, the availability of chiral NHCs for asymmetric catalysis is limited. However, a chiral version of the widely ...

Realizing a hydrogen economy strongly requires alkaline water electrolysis to achieve large-scale generation of H2, but lacks stable and efficient catalysts. The insufficient active sites in Ni(OH)2 impair the catalytic performance of alkaline HER. Herein, ...

The rapid progress in the field of deep learning has had a significant impact on protein design. Deep learning methods have recently produced a breakthrough in protein structure prediction, leading to the availability of high-quality models for millions of ...

Cu-based bimetallic catalysts have attracted great attention for the reverse water gas shift (RWGS) reaction due to their high activity and selectivity. This work reports the application of Cu-In bimetallic catalysts for the RWGS reaction and demonstrates ...

The valorisation of the plant biopolymer lignin is now recognised as essential to enabling the economic viability of the lignocellulosic biorefining industry. In this context, the "lignin-first" biorefining approach, in which lignin valorisation is conside ...

The enantiopure Schiff bases (R or S)-N-1-( phenyl)ethyl-2,4-X-1,X2(-)salicylaldimine (X-1, X-2 = Cl, Br, I) coordinate to copper(II) and provide pseudotetrahedral bis[(S or R)-N-1-(phenyl)ethyl-(2,4-X-1,X-2-salicylaldiminato.2N,O)]-./.-Cu(II) (kappa N-2,O ...

Artificial Metalloenzymes with Multiple Catalytic Sites for Tandem or Synergistic Transformations

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Efficient Direct Cytosolic Protein Delivery via Protein-Linker Co-engineering

Chiral N-Heterocyclic Carbene Ligands: Enhancing Nickel-Catalyzed Asymmetric Syntheses

Anisotropic In-Plane strain engineering Ni(OH)2 to activate alkaline hydrogen evolution reaction

A new age in protein design empowered by deep learning

Support-Dependent Cu-In Bimetallic Catalysts for Tailoring the Activity of Reverse Water Gas Shift Reaction

Guidelines for performing lignin-first biorefining

Solid-state to solution helicity inversion of pseudotetrahedral chiral copper(II) complexes with 2,4-dihalo-salicylaldiminate ligands