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Wetting in infiltration of alumina particle preforms with molten copper

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Liquid metal infiltration of silicon based alloys into porous carbonaceous materials. Part II: Experimental verification of modelling approaches by infiltration of Si-Zr alloy into idealized microchannels

Ludger Weber, Caroline Hain, Manoj Kondibhau Naikade

In this work, the mechanisms leading to the pore closure in reactive melt infiltration (RMI) of carbon by pure silicon and a near eutectic Si-8 at-pct Zr alloy at 1500 and 1700 degrees C under vacuum were studied. Various geometrical configurations of micr ...

ELSEVIER SCI LTD2022

The long cross-over dynamics of capillary imbibition

Ignacio Pagonabarraga Mora

Spontaneous capillary imbibition is a classical problem in interfacial fluid dynamics with a broad range of applications, from microfluidics to agriculture. Here we study the duration of the cross-over between an initial linear growth of the imbibition fro ...

Cambridge University Press2022

Surface energy contributions to the work of infiltration in metal matrix composite processing

Andreas Mortensen, Gionata Schneider

The work needed to mechanically drive molten metal into a porous solid preform when producing a composite material by infiltration can significantly exceed the energy change required for thermodynamically reversible infiltration. We measure, by quantitativ ...

2021

Understanding of the factors slowing down metakaolin reaction in limestone calcined clay cement (LC3) at late ages

Karen Scrivener, Paul Bowen, Mohsen Ben Haha, François Henri Avet, Yosra Briki

Factors which could explain the slowing down of the metakaolin reaction in LC3 blends are investigated. Portlandite availability and the presence of aluminium ions in the pore solution are shown not to be limiting factors. ...

Pergamon-Elsevier Science Ltd2021

Electron Beam Induced Copper Deposition from Carboxylate Precursors and the Study of Underlying Growth Mechanisms

Luisa Berger

The fabrication of defined and high-quality metal nanostructures is an ongoing topic of research. Direct-write deposition of copper nanostructures is of great value for many fields of research and industrial applications. Focused electron beam induced depo ...

EPFL2020

Simulating Infiltration as a Sequence of Pinning and De-pinning Processes

Andreas Mortensen, William Craig Carter

The infiltration of a non-wetting liquid, such as molten metal, into a porous solid, such as a ceramic preform, is influenced by the wetting angle of the liquid on the solid. The link between local wetting and the minimum pressure required for initiation o ...

2021

Stability and Degradation Mechanisms of Copper-Based Catalysts for Electrochemical CO2 Reduction

Raffaella Buonsanti, Jan Vávra

To date, copper is the only monometallic catalyst that can electrochemically reduce CO2 into high value and energy-dense products, such as hydrocarbons and alcohols. In recent years, great efforts have been directed towards understanding how its nanoscale ...

Wiley-VCH Verlag GmbH2020

Defect formation and mitigation during laser powder bed fusion of copper

Carl Tore Viktor Lindström

Additive manufacturing (AM) is a group of processing technologies which has the potential to revolutionize manufacturing by allowing easy manufacturing of complex shapes and small series. One AM-method which is of high interest for processing of metals is ...

EPFL2021

Diffraction artefacts from twins and stacking faults, and the mirage of hexagonal, polytypes or other superstructures

Cyril Cayron

Recently, a hexagonal phase has been reported in high carbon steels in several studies. Here, we show that the electron microscopy results used in these studies were erroneously interpreted. The extra-spots in the diffraction patterns and the odd contrasts ...

2020

Decoupling the role of inertia, friction and cohesion in dense granular avalanche pressure build‐up on obstacles

Christophe Ancey, Johan Alexandre Philippe Gaume, Michael Lukas Kyburz

Understanding the physical processes involved in snow avalanche‐obstacle interaction is essential to be able to estimate the pressure exerted on structures. Although avalanche impact pressure has been measured in field experiments for decades, the underlyi ...

2020

Copper, my precious!

Raffaella Buonsanti

To produce chemicals and fuels from CO2 and water while storing excess energy from renewable resources will play a big role in sustainability. Three decades ago, we learned that copper possesses the unique ability to break the stable CO2 bonds and to form ...

NATURE PORTFOLIO2021

Microstructural controls of anticrack nucleation in highly porous brittle solids

Johan Alexandre Philippe Gaume, Henning Löwe

Porous brittle solids have the ability to collapse and fail even under compressive stresses. In fracture mechanics, this singular behavior, often referred to as anticrack, demands for appropriate continuum models to predict the catastrophic failure. To ide ...

Nature Research2020

Factors affecting the reactivity of slag at early and late ages

Karen Scrivener, Mohsen Ben Haha, Yosra Briki

This study investigates the difference between the reactivity of slag in NaOH solution (w/s = 100) and in cement paste (w/b = 0.4). The reactivity of slag is much higher in NaOH solution than in cement paste. When the NaOH solution is saturated with portla ...

Pergamon-Elsevier Science Ltd2021

The mechanical behaviour and failure modes of volcanic rocks: a review

Marie Estelle Solange Violay

The microstructure and mineralogy of volcanic rocks is varied and complex, and their mechanical behaviour is similarly varied and complex. This review summarises recent developments in our understanding of the mechanical behaviour and failure modes of volc ...

2021

Shape Engineering of Metal-Organic Frameworks via MOF@Polymer Composite Fabrication

Bardiya Valizadeh

Metal-organic frameworks (MOFs) are a fascinating class of porous materials that have become the subject of research owing to their unique characteristics such as high surface areas, low densities, and structural tunability. Recently, the research has been ...

EPFL2020