The deposition of a stack of amorphous (a-Si:H) and microcrystalline (µc- Si:H) tandem thin film silicon solar cells (micromorph) requires at least twice the time used for a single junction a-Si:H cell. However, micromorph devices have a higher potential efficiency, thanks to the broader absorption spectrum of µc-Si:H material. High efficiencies can only be achieved by mitigating the nanocracks in the µc-Si:H cell and the light-induced degradation of the a- Si:H cell. As a result, µc-Si:H cell has to grow on a smooth substrate with large periodicity (>1 µm) and the a-Si:H cell on sharp pyramids with smaller feature size (~350 nm) to strongly scatter the light in the weak absorption spectra of a-Si:H material. The asymmetric intermediate reflector introduced in this work uncouples the growth and light scattering issues of the tandem micromorph solar cells. The stabilized efficiency of the tandem n-i-p/n-i-p micromorph is increased by a relative 15% compared to a cell without AIR and 32% in relative compared to an a-Si:H single junction solar cells. The overall process (T
Mohammad Khaja Nazeeruddin, Peng Gao
Michael Graetzel, Mohammad Khaja Nazeeruddin, Shaik Mohammed Zakeeruddin, Paul Joseph Dyson, Ursula Röthlisberger, David Lyndon Emsley, Fatemeh Ansari, Felix Thomas Eickemeyer, Lukas Pfeifer, Nikolaos Lempesis, Virginia Carnevali, Ümmügülsüm Günes, Likai Zheng, Vladislav Slama, Tristan Axel Georges, Andrea Vezzosi