Ligand-Controlled Regiodivergent Hydroalkylation of Pyrrolines

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Molybdenum sulfide materials had been shown as promising non-precious catalysts for hydrogen evolution. This paper describes the study of the promotional effect of certain transition metal ions on the activity of amorphous MoS3 films. Ternary metal sulfide ...

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The water soluble ruthenium(II) complex [RuCl2(PTA)([9]aneS3)] (PTA = 1,3,5-triaza-7-phosphadamantane, [9]aneS3 = 1,4,7-trithiacyclononane) catalyzes the hydrogenation of CO2 and bicarbonate in aqueous solution. ...

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Palladium-catalyzed intramolecular carbopalladation of N-aryl acrylamides followed by migratory insertion of an isocyanide-coordinated C(sp3)-Pd intermediate afforded an alkylimidoyl-Pd(II) complex, which can be intercepted by a nucleophile, including hete ...

Reaction pathways during CO2 hydrogenation catalyzed by the Ru dihydride complex [Ru(dmpe)2H2] (dmpe=Me2PCH2CH2PMe2) have been studied by DFT calculations and by IR ...

Metal-catalyzed cross-coupling reactions are powerful and widespread methods for the carbon-carbon bond formation. Among the electrophile partners, non-activated alkyl halides remain challenging substrates because of their reluctance towards oxidative addi ...

This thesis describes novel methods for and investigations into C–C and C–N bond formation reactions. Chapter 1 gives a very brief overview of established strategies for the formation of new C–C bonds in organic synthesis. In chapter 2, a multi‐step one‐po ...

Iron-catalyzed hydrogenation has drawn much attention, yet the scope and chemoselectivity of iron catalysis warrant further improvement. Here we report new iron pincer complexes as chemoselective hydrogenation and transfer hydrogenation catalysts. Several ...

The tetradentate chelate ligand tris[(1-vinylimidazol-2-yl)methyl]amine (10) was synthesized in five steps from commercially available starting materials. Upon reaction with MCl2 (M = Zn, Cu, Ni, Co) in the presence of NH4PF6, the complexes [M(10)Cl]PF6 (M ...

Ligand-Controlled Regiodivergent Hydroalkylation of Pyrrolines

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Mechanistic Study on the Palladium(II)-Catalyzed Synthesis of 2,3-Disubstituted Indoles Under Aerobic Conditions: Anion Effects and the Development of a Low-Catalyst-Loading Process

CO2 hydrogenation reaction over pristine Fe, Co, Ni, Cu and Al2O3 supported Ru: Comparison and determination of the activation energies

Diaminophosphine Oxide Ligand Enabled Asymmetric Nickel-Catalyzed Hydrocarbamoylations of Alkenes

Development of heterogeneous catalytic systems for the transformation of carbon dioxide to methanol under mild conditions

Structured Non-Noble Metal Catalysts for the Liquid-Phase Reduction of Nitroaromatics

Fe, Co, and Ni Ions Promote the Catalytic Activity of Amorphous Molybdenum Sulfide Films for Hydrogen Evolution

Propene oligomerization over Ni-exchanged Na-X zeolites

Ni-based structured catalyst for selective 3-phase hydrogenation of nitroaromatics

In situ NMR characterisation of an intermediate in the catalytic hydrogenation of CO2 and HCO3– in aqueous solution

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Suzuki-Miyaura cross-coupling of non-activated alkyl halides catalyzed by well-defined nickel pincer complexes

Novel Applications of Nitrous Oxide and Transition Metals for C-C and C-N Bond Formation

Chemoselective Hydrogenation and Transfer Hydrogenation of Aldehydes Catalyzed by Iron(II) PONOP Pincer Complexes

Biomimetic catalysis with immobilized transition metal complexes