Publications associées à Mechanistic Insights into the Role of the Bis(trifluoromethanesulfonyl) imide Ion in Coevaporated p-i-n Perovskite Solar Cells

Publications associées (17)

Dissolvable molecular bridges promoting buried interface modification for high-performance inverted perovskite solar cells

Non-radiative recombination and suboptimal interfacial contact at the hole transportation layer (HTL)/perovskite interface critically suppress the device performance and stability of inverted perovskite solar cells (PSCs). Herein, we proposed a dissolvable ...

Royal Society of Chemistry2025

Emergence of Light‐Transforming Layered Hybrid Halide Perovskites

Ghewa Alsabeh

Layered hybrid halide perovskites (LHPs) have attracted considerable attention in optoelectronics. They are based on tailored organic spacer cations templating halide perovskite slabs, featuring improved stabilities compared to their 3D halide perovskite a ...

Wiley2025

Managing Excess Lead Iodide with Functionalized Oxo-Graphene Nanosheets for Stable Perovskite Solar Cells

Guixiang Li

Stability issues could prevent lead halide perovskite solar cells (PSCs) from commercialization despite it having a comparable power conversion efficiency (PCE) to silicon solar cells. Overcoming drawbacks affecting their long-term stability is gaining inc ...

Wiley-VCH Verlag GmbH2023

Influence of an Organic Salt-Based Stabilizing Additive on Charge Carrier Dynamics in Triple Cation Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Paul Joseph Dyson, Bin Ding, Yong Ding, Roland Christopher Turnell-Ritson

Besides further improvement in the power conversion efficiency (PCE) of perovskite solar cells (PSC), their long-term stability must also be ensured. Additives such as organic cations with halide counter anions are considered promising candidates to addres ...

Wiley2023

Tailoring passivators for highly efficient and stable perovskite solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Lukas Pfeifer, Hong Zhang

There is an ongoing global effort to advance emerging perovskite solar cells (PSCs), and many of these endeavours are focused on developing new compositions, processing methods and passivation strategies. In particular, the use of passivators to reduce the ...

NATURE PORTFOLIO2023

Understanding and mitigating resistive losses in fired passivating contacts: role of the interfaces and optimization of the thermal budget

Christophe Ballif, Franz-Josef Haug, Aïcha Hessler-Wyser, Luca Massimiliano Antognini, Sofia Libraro, Audrey Marie Isabelle Morisset, Julien Hurni, Ezgi Genç

This work presents a study of p-type passivating contacts based on SiCx formed via a rapid thermal processing (RTP) step, using conditions compatible with the firing used to sinter screen-printed metallization pastes in industry. The contributions of the t ...

Elsevier2023

Over 24% efficient MA-free Cs(x)FA(1-x)PbX(3) perovskite solar cells

Michael Graetzel

Methylammonium (MA)-free perovskites such as Cs(x)FA(1-x)PbX(3) (CsFA) show excellent thermal stability, favoring their use in perovskite solar cells (PSCs). However, the power conversion efficiency (PCE) of CsFA lags behind that of MA-containing formulati ...

CELL PRESS2022

The role of Encapsulants in the long-term performance of advanced Crystalline Silicon Glass-Glass PV modules

Luca Gnocchi

The adoption of crystalline silicon (c-Si) PV modules based on glass-glass (G-G) structures is gaining momentum because of the possibility to manufacture bifacial panels, collecting light from the rear side. Despite not being an optimal material, Ethylene ...

EPFL2022

Formate as Anti-Oxidation Additives for Pb-Free FASnI(3) Perovskite Solar Cells

Jiyoun Seo, Jaeki Jeong, Jinhyun Kim

Pb-free Sn-based perovskite solar cells (PSCs) have significant potential for application in photovoltaic devices because oftheir suitable bandgap, low exciton binding energy, high carrier mobility, and long diffusion length. However, their performance is ...

WILEY-V C H VERLAG GMBH2022

A combined molecular dynamics and experimental study of two-step process enabling low-temperature formation of phase-pure α-FAPbI3

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, Ulf Anders Hagfeldt, Paramvir Ahlawat, Essa Awadh R Alharbi, Haizhou Lu

It is well established that the lack of understanding the crystallization process in a two-step sequential deposition has a direct impact on efficiency, stability, and reproducibility of perovskite solar cells. Here, we try to understand the solid-solid ph ...

2021

Understanding the design principles of organic sensitizers for highly efficient dye sensitized solar cells

Marko Stojanovic

The conversion of solar to electrical power has presented itself as a solution to meet the growing energy demand and replace our current fossil fuel dependence, which causes dramatic damages to the environment. At the heart of this challenge lies the perfo ...

EPFL2021

Ni80Fe20 nanotubes with optimized spintronic functionalities prepared by atomic layer deposition

Anna Fontcuberta i Morral, Dirk Grundler, Simon Robert Escobar Steinvall, Sho Watanabe, Maria Carmen Giordano

Permalloy Ni80Fe20 is one of the key magnetic materials in the field of magnonics. Its potential would be further unveiled if it could be deposited in three dimensional (3D) architectures of sizes down to the nanometer. Atomic Layer Deposition, ALD, is the ...

2021

Quasi-Heteroface Perovskite Solar Cells

Ulf Anders Hagfeldt, Peng Wang

Perovskite solar cells (PSCs) have attracted unprecedented attention due to their rapidly rising photoelectric conversion efficiency (PCE). In order to further improve the PCE of PSCs, new possible optimization path needs to be found. Here, quasi-heterofac ...

WILEY-V C H VERLAG GMBH2020

Atomic scale structure and its impact on the band gap energy for Cu2Zn(Sn,Ge)Se(4)kesterite alloys

Thomas Bischoff

Kesterite based materials gain more and more relevance in the pursuit of affordable, efficient and flexible absorber materials for thin film photovoltaics. Alloying Cu(2)ZnSnSe(4)with Ge could allow controlled band gap engineering as already established fo ...

2020

Photoelectrochemical Cells Based on Dye Sensitization for Electricity and Fuel Production

Ulf Anders Hagfeldt, Nikolaos Vlachopoulos

Dye-sensitized semiconductor oxide photoelectrodes in which light is absorbed by a monomolecular layer of dye chemisorbed on a porous oxide substrate have attracted considerable interest in the last 35 years, mainly for the conversion of sunlight to electr ...

SWISS CHEMICAL SOC2019

Selective C-C Coupling in Carbon Dioxide Electroreduction via Efficient Spillover of Intermediates As Supported by Operando Raman Spectroscopy

Michael Graetzel, Shaik Mohammed Zakeeruddin, Jingshan Luo, Dan Ren, Hong Zhang, Jing Gao

Developing efficient systems for the conversion of carbon dioxide to valuable chemicals using solar power is critical for mitigating climate change and ascertaining the worlds future supply of clean fuels. Here, we introduce a mesoscopic cathode consisting ...

AMER CHEMICAL SOC2019

Elucidating the role of the InGaN UL in the efficiency of InGaN based light-emitting diodes

Camille Haller

Blue III-nitride light-emitting diodes (LEDs) are widely used nowadays in solid-state lighting, as white light can be produced by combining yellow phosphors and blue LEDs. This technology has the advantage to have a higher luminous efficiency than incandes ...

EPFL2019