Molecular Complex of Tb in the +4 Oxidation State

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Lanthanides are versatile modulators of optoelectronic properties owing to their narrow optical emission spectra across the visible and near-infrared range. Their use in metal halide perovskites (MHPs) has recently gained prominence, although their fate in ...

One tetrahedral and two trigonal prismatic cages with π-basic Au3(pyrazolate)3 faces were obtained by connection of pre-formed gold complexes via dynamic covalent imine chemistry. The parallel arrangement of the Au3(pyrazolate)3 complexes in the prismatic ...

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Electron-rich organocerium complexes (C5Me4H)(3)Ce and [(C5Me5)(2)Ce(ortho-oxa)], with redox potentials E-1/2 = -0.82 V and E-1/2 = -0.86 V versus Fc/Fc(+), respectively, were reacted with fullerene (C-60) in different stoichiometries to obtain molecular m ...

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Thesynthesis of molecular uranium complexes in oxidation stateslower than +3 remains a challenge despite the interest for their multielectrontransfer reactivity and electronic structures. Herein, we report theone- and two-electron reduction of a U(III) com ...

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The biological N-2-fixation process is catalyzed exclusively by metallocofactor-containing nitrogenases. Structural and spectroscopic studies highlighted the presence of an additional mononuclear metal-binding (MMB) site, which can coordinate Fe in additio ...

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In this thesis, we exploited optical and X-ray pump-probe methods in a synergistic approach to study the interplay of the electronic, spin and structural degrees of freedom in two class of complex systems relevant for solar energy conversion applications: ...

Molecular Complex of Tb in the +4 Oxidation State

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Speciation of Lanthanide Metal Ion Dopants in Microcrystalline All-Inorganic Halide Perovskite CsPbCl3

Molecular imine cages with π-basic Au3(pyrazolate) faces

Beyond the coupled distortion model: structural analysis of the single domain cupredoxin AcoP, a green mononuclear copper centre with original features

Realization of Organocerium-Based Fullerene Molecular Materials Showing Mott Insulator-Type Behavior

Hybrid organic/metal-oxide shells on semiconductor nanocrystals via colloidal atomic layer deposition

Solution-based Cu+ transient species mediate the reconstruction of copper electrocatalysts for CO2 reduction

Multielectron Redox Chemistry of Uranium by Accessing the plus II Oxidation State and Enabling Reduction to a U(I) Synthon

Tungsten oxide-based photoanodes: biomass valorization and the effects of oxygen vacancies

Tuning the reactivity of uranium towards small molecules in multimetallic complexes

Atomic-level structure determination of amorphous molecular solids by NMR

Mechanism of Reduction of Aqueous U(V)-dpaea and Solid-Phase U(VI)-dpaea Complexes: The Role of Multiheme c-Type Cytochromes

NMR Crystallography in the Big Data Era: New Methods and Applications Powered by Machine Learning

koopmans: An Open-Source Package for Accurately and Efficiently Predicting Spectral Properties with Koopmans Functionals

The Mononuclear Metal-Binding Site of Mo-Nitrogenase Is Not Required for Activity

Stabilizing Unusual Oxidation States of Lanthanides in Molecular Complexes: Synthesis, Properties, and Reactivity

Quantifying the Solution Structure of Metal Nanoclusters Using Small-Angle Neutron Scattering

Anticancer ruthenium(II) tris(pyrazolyl)methane complexes with bioactive co-ligands

Pd(II)-Catalyzed Aminoacetoxylation of Alkenes Via Tether Formation

Assessing the persistence of chalcogen bonds in solution with neural network potentials

Photo- and thermally-induced electronic and structural dynamics in perovskites and transition metal oxides