Publications associées à A bright tetranuclear iridium(III) complex

Publications associées (41)

Multi-scale and Multi-physics Modeling of Electrochemical CO2 Reduction

The electrochemical CO2 reduction is a promising approach to convert this greenhouse gas to valuable products. The membrane electrode assembly (MEA) configuration integrates porous gas diffusion electrodes (GDEs) where the CO2 reduction reaction rapidly oc ...

EPFL2025

Emergence of Light‐Transforming Layered Hybrid Halide Perovskites

Ghewa Alsabeh

Layered hybrid halide perovskites (LHPs) have attracted considerable attention in optoelectronics. They are based on tailored organic spacer cations templating halide perovskite slabs, featuring improved stabilities compared to their 3D halide perovskite a ...

Wiley2025

Palladium-based supramolecular assemblies: from complex structures to water-soluble anion-receptors

Sylvain Alexandre Marie Sudan

The combination of palladium salts and bipyridyl ligands can lead to the formation of a large variety of coordination complexes, with different shapes and sizes, displaying a very versatile host-guest chemistry. Increasing their structural complexity remai ...

EPFL2024

Managing Excess Lead Iodide with Functionalized Oxo-Graphene Nanosheets for Stable Perovskite Solar Cells

Guixiang Li

Stability issues could prevent lead halide perovskite solar cells (PSCs) from commercialization despite it having a comparable power conversion efficiency (PCE) to silicon solar cells. Overcoming drawbacks affecting their long-term stability is gaining inc ...

Wiley-VCH Verlag GmbH2023

Influence of an Organic Salt-Based Stabilizing Additive on Charge Carrier Dynamics in Triple Cation Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Paul Joseph Dyson, Bin Ding, Yong Ding, Roland Christopher Turnell-Ritson

Besides further improvement in the power conversion efficiency (PCE) of perovskite solar cells (PSC), their long-term stability must also be ensured. Additives such as organic cations with halide counter anions are considered promising candidates to addres ...

Wiley2023

Tuning the reactivity of uranium towards small molecules in multimetallic complexes

Nadir Jori

One of the main goals of organometallic chemistry in the last decades was the activation of small molecule in mild reaction conditions. Even though multiple examples of catalytic cycles able to produce fine chemicals from cheap and abundant sources using t ...

EPFL2023

Tailoring passivators for highly efficient and stable perovskite solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Lukas Pfeifer, Hong Zhang

There is an ongoing global effort to advance emerging perovskite solar cells (PSCs), and many of these endeavours are focused on developing new compositions, processing methods and passivation strategies. In particular, the use of passivators to reduce the ...

NATURE PORTFOLIO2023

The acid-mediated isomerization of iridium(iii) complexes with cyclometalated NHC ligands: kinetic vs. thermodynamic control

Kay Severin, Farzaneh Fadaei Tirani, Anastasia Gitlina

The isomerization of iridium(III) complexes with metalated N-heterocyclic carbene (NHC) ligands was studied. The fac isomers of complexes with 1-phenyl-3-methylbenzimidazolin-2-ylidene or 1-phenyl-3-benzylbenzimidazolin-2-ylidene ligands are transformed cl ...

2023

Over 24% efficient MA-free Cs(x)FA(1-x)PbX(3) perovskite solar cells

Michael Graetzel

Methylammonium (MA)-free perovskites such as Cs(x)FA(1-x)PbX(3) (CsFA) show excellent thermal stability, favoring their use in perovskite solar cells (PSCs). However, the power conversion efficiency (PCE) of CsFA lags behind that of MA-containing formulati ...

CELL PRESS2022

Synthesis, structural determination, theoretical studies and catalytic activity of Mn(II) complex of N-isonicotinyl phosphoric triamide ligand

Farzaneh Fadaei Tirani, Kurt Schenk

synthesized and characterized by H-1, C-13, P-31 NMR and IR spectroscopies. The reaction of MnCl2 center dot 4H(2)O with L led to the formation of a new 3D system {MnL2Cl2}(n)center dot 34CH(3)OH (C-1). X-ray crystallographic data revealed that the ligand ...

Elsevier Science Sa2015

The role of Encapsulants in the long-term performance of advanced Crystalline Silicon Glass-Glass PV modules

Luca Gnocchi

The adoption of crystalline silicon (c-Si) PV modules based on glass-glass (G-G) structures is gaining momentum because of the possibility to manufacture bifacial panels, collecting light from the rear side. Despite not being an optimal material, Ethylene ...

EPFL2022

Supramolecular assemblies of organotin(IV)-diphosphoryl adducts: insights from X-rays and DFT

Kurt Schenk

Mono-, di- and tri-phenyltin(IV) adducts containing a neutral diphosphoryl ligand, Ph2P(O)OC6H4OP(O) Ph-2, were synthesized and characterized. These 2 : 1 adducts of two trans-organotin(IV) moieties and the bridging ligand all crystallize around a centre o ...

Royal Soc Chemistry2015

Formate as Anti-Oxidation Additives for Pb-Free FASnI(3) Perovskite Solar Cells

Jiyoun Seo, Jaeki Jeong, Jinhyun Kim

Pb-free Sn-based perovskite solar cells (PSCs) have significant potential for application in photovoltaic devices because oftheir suitable bandgap, low exciton binding energy, high carrier mobility, and long diffusion length. However, their performance is ...

WILEY-V C H VERLAG GMBH2022

Quantifying the Solution Structure of Metal Nanoclusters Using Small-Angle Neutron Scattering

Huayan Yang, Francesco Stellacci, Stefan Guldin, Zhi Luo

Metal nanoclusters are a unique class of synthetic material, as their crystal structures can be resolved using X-ray diffraction, and their chemical formula can be precisely determinated from mass spectroscopy. However, a complete structure characterizatio ...

Wiley-VCH Verlag GmbH2022

Exploring Ligand Affinities for Proteins by NMR of Long-Lived States

Roberto Buratto

The detection of molecules that can bind to active sites of protein targets and the measurement of their affinities is a promising application of NMR. Nowadays, the screening of drug candidates is routinely done by NMR in pharmaceutical industry. We have p ...

EPFL2015

Development of metal-organic frameworks based on N-heterocyclic ligands

Ilia Kochetygov

Metal-organic frameworks (MOFs) have firmly established in the field of porous materials since their early discovery in the 1990s. With a plethora of applications, these materials offer endless possibilities owing to their tunable, modular nature. The vast ...

EPFL2022

Ultrafast Photophysics of Transition Metal Complexes

Majed Chergui

CONSPECTUS: The properties of transition metal complexes are interesting not only for their potential applications in solar energy conversion, OLEDs, molecular electronics, biology, photochemistry, etc. but also for their fascinating photophysical properti ...

American Chemical Society2015

Understanding the design principles of organic sensitizers for highly efficient dye sensitized solar cells

Marko Stojanovic

The conversion of solar to electrical power has presented itself as a solution to meet the growing energy demand and replace our current fossil fuel dependence, which causes dramatic damages to the environment. At the heart of this challenge lies the perfo ...

EPFL2021

Mechanistic Insights into the Role of the Bis(trifluoromethanesulfonyl) imide Ion in Coevaporated p-i-n Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Paul Joseph Dyson, Mounir Driss Mensi, Hiroyuki Kanda, Klaus Leifer, Cristina Roldán Carmona, Albertus Adrian Sutanto, Keith Gregory Brooks, Maria Cristina Momblona Rincón, Cansu Igci, Nadja Isabelle Desiree Klipfel

Hybrid lead halide perovskites have reached comparable efficiencies to state-of-the-art silicon solar cell technologies. However, a remaining key challenge toward commercialization is the resolution of the perovskite device instability. In this work, we id ...

2021

New Zn(II) complexes with N2S2 Schiff base ligands. Experimental and theoretical studies of the role of Zn(II) in disulfide thiolate-exchange

Kurt Schenk

Described are the synthesis and characterization of two, potentially tetradentate, N2S2 Schiff-base ligands, containing a disulfide bond, N,N'-bis(3-phenylprop-2-en-l-ylidene)-2,2'-disulfanediyldianiline (L-1) and N,N'-bis(3,3-diphenylprop-2-en-1-ylidene)- ...

Elsevier2014