Publications associées à Interfacial Photoreduction of Supercritical CO2 by an Aqueous Catalyst

Continuous Supercritical Water Impregnation Method for the Preparation of Metal Oxide on Activated Carbon Composite Materials

Metal oxide (MexOy) nanomaterials are used as catalysts and/or sorbents in processes taking place in supercritical water (scH2O), which is the “green” solvent needed to obtain energy-relevant products. Their properties are significantly influenced by the s ...

2024

Investigation of Biomass Hydrothermal Conversion Products by HRMS

Daniil Salionov

The dependency on fossil fuels and their impact on the environment is a matter of great concern for the future sustainability of modern society. The development of the "green" technologies which utilize renewable energy sources is now under investigation. ...

EPFL2023

Critical values in an anisotropic percolation on $\mathbb{Z}^2$

Hao Xue

In this thesis, we consider an anisotropic finite-range bond percolation model on

\mathbb{Z}^2

. On each horizontal layer

\{(x,i):x\in\mathbb{Z}\}

for

i\in\mathbb{Z}

, we have edges

\langle(x,i),(y,i)\rangle

for

1\leq|x-y|\leq N

with $N\in\mathbb{N ...

EPFL2021

Supported ruthenium nanoparticles for supercritical water gasification - synthesis, activity and stability

Christopher Marc Hunston

Supercritical water gasification (SCWG) is a promising and versatile technology for the conversion of a variety of wet biomass streams into renewable natural gas. In this work, the focus was set on methane production with the help of an active and stable m ...

EPFL2021

New Approach to Synthesis of Tetralin via Naphthalene Hydrogenation in Supercritical Conditions Using Polymer-Stabilized Pt Nanoparticles

Lioubov Kiwi

Supercritical (SC) fluid technologies are well-established methods in modern green chemical synthesis. Using SC fluids as solvents instead of traditional liquids gives benefits of higher diffusivity and lower viscosity, which allows mass transfer intensifi ...

2020

Supercritical water anomalies in the vicinity of the Widom line

Christian Ludwig

Supercritical water is used in a variety of chemical and industrial applications. As a consequence, a detailed knowledge of the structure-properties correlations is of uttermost importance. Although supercritical water was considered as a homogeneous fluid ...

Nature Research2019

Visualization of supercritical water pseudo-boiling at Widom line crossover

Andrea Testino, Christian Ludwig

Supercritical water is a green solvent used in many technological applications including materials synthesis, nuclear engineering, bioenergy, or waste treatment and it occurs in nature. Despite its relevance in natural systems and technical applications, t ...

Nature Research2019

Printing of NiO-YSZ nanocomposites: from continuous synthesis to inkjet deposition

Andreas Stephan Lesch, Victor Costa Bassetto, Massimo Rosa

Water-based inks, containing nanometric NiO and YSZ particles in 66/34 vol. % ratio, are produced by colloidal stabilization of a binary dispersion obtained via continuous hydrothermal synthesis at supercritical conditions, i.e. 280 bar and 400 °C. The met ...

2019

Multiple Inflow Branches at Supercritical-Type Vortex Drop Shaft

Jean-Marc Ribi, Thierry Fuchsmann, Michael Pfister, Corrado Gisonni, Gaetano Crispino

Vortex drop shafts serve to overcome important elevation differences in drainage systems. If well designed, they are performant in terms of energy dissipation and safety. However, the standard design requires well-defined approach flow conditions to ensure ...

ASCE-AMER SOC CIVIL ENGINEERS2018

Multi-objective Optimization of Supercritical Water Gasification of Leftover Brazilian Ginseng Roots After Phytochemical Recovery Steps

François Maréchal, Alberto Mian, Adriano Viana Ensinas, Diego Tresinari dos Santos, Juliana Queiroz Albarelli

The present study aims at studying the supercritical water gasification (SCWG) of the leftover Brazilian ginseng roots after phytochemicals extraction for synthetic natural gas (SNG) production, envisioning the development of a promising Brazilian ginseng ...

2017

The impact of sorbent geometry on the sulphur adsorption under supercritical water conditions: a numerical study

Andrea Testino, Christian Ludwig

A numerical model to show the impact of the adsorption bed geometry on the desulfurization process of wet biomass under supercritical water (SCW) gasification process has been developed. Three different geometries, straight channels (pipe), sharp-edged cha ...

Springer Heidelberg2017

Thermo-economic and environmental comparison of supercritical water and enzymatic hydrolysis of sugarcane bagasse in a biorefinery concept

François Maréchal, Adriano Viana Ensinas

In this study, we discuss the difference regarding thermo-economic and environmental (water intake) aspects between two methods of biomass hydrolysis. A thermo-economic model was developed using Aspen Plus® and MATLAB software in order to analyze the energ ...

2017

Photocatalytic and Electrocatalytic Reduction of Carbon Dioxide in Pressurized Systems

Patrick Voyame

The depletion of carbon-based fossil fuels and the rise in atmospheric carbon dioxide concentration will force an inevitable change in the future global energy landscape. CO2 reduction presents the advantages of decreasing its atmospheric concentration and ...

EPFL2016

Apparatus for salt separation under supercritical water conditions

Daniel Favrat, François Maréchal, Alberto Mian, Adriano Viana Ensinas

Apparatus for salt separation (2) under supercritical water conditions, comprising a heat exchanger (4) and a fluidized bed reactor (6). The fluidized bed reactor comprising a supercritical water pressure containing wall (8) defining therein a fluidized be ...

2016

Heat expandable biopolymers for one-step production of foam core sandwich composites

Yonghoon Yoon

The overall aim of this work has been to develop sustainable solid thermally activated foam precursors suitable for the in-line production of lightweight bio-based foam core sandwich structures with consolidated wood particle facings, using a non-inflammab ...

EPFL2016

Working fluid charge reduction. Part II: Supercritical CO2 gas cooler designed for light commercial appliances

John Richard Thome, Jackson Braz Marcinichen

The present study focused on the thermal hydraulic performance improvement of a CO2 gas cooler with the principal goal of reducing its volume, and consequently the necessary charge of the working fluid. To achieve this compactness, the leading methods for ...

Elsevier Sci Ltd2016

Valorization of sugarcane biorefinery residues using supercritical water gasification: A case study and perspectives

François Maréchal, Alberto Mian, Adriano Viana Ensinas

The present study evaluates the use of supercritical fluid technology, particularly supercritical water gasification (SCWG), to add value to residues from a sugarcane biorefinery that produces first and second generation ethanol. This case study aims at el ...

2015

Electrochemistry in Supercritical Fluids: A Mini Review

Patrick Voyame, Manuel Alejandro Méndez Agudelo, Kathryn Ellen Toghill

A brief overview of the literature relating to electrochemical studies and processes undertaken in supercritical fluids is presented. This review mostly concerns carbon dioxide and hydrofluorocarbons, given the accessibility of their supercritical states, ...

Elsevier2014

Steady-state macroscale voltammetry in a supercritical carbon dioxide medium

Hubert Girault, Patrick Voyame, Astrid Johana Olaya Avendano, Dmitry Momotenko, Kathryn Ellen Toghill

The electrochemical oxidation and reduction of decamethylferrocene is demonstrated in supercritical carbon dioxide at a macro gold disc electrode at 100 bar and 313 K. Fast mass transport effects were exhibited and the corresponding steady-state voltammetr ...

Royal Soc Chemistry2013

Biodegradable polylactide/hydroxyapatite nanocomposite foam scaffolds for bone tissue engineering applications

Pierre-Etienne Bourban, John Christopher Plummer, Claire Diane Delabarde

Supercritical carbon dioxide processing of poly--lactide (PLLA)/hydroxyapatite (nHA) nanocomposites was investigated as a means to prepare foams suitable as scaffolds in bone tissue engineering applications. For given foaming parameters, addition of nHA to ...

Springer US2012