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Ionic partition diagram of tetraphenylporphyrin at the water|1,2-dichloroethane interface

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Publications associées (33)

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Modeling Current Transients in a Reciprocal Motion Tribocorrosion Experiment

Stefano Mischler, Anna Neus Igual Muñoz, Shoufan Cao

Tribocorrosion of passivating metals is a dynamic phenomenon causing degradation of materials by a combination of mechanical wear and electrochemical dissolution. The mechanical action typically produces a local removal of particles, metal as well as oxide ...

ELECTROCHEMICAL SOC INC2021

Energy Level Alignment at the Cobalt Phosphate/Electrolyte Interface: Intrinsic Stability vs Interfacial Chemical Reactions in 5 V Lithium Ion Batteries

Nicola Marzari, Matteo Cococcioni

The intrinsic stability of the 5 V LiCoPO4-LiCo2P3O10 thin-film (carbon-free) cathode material coated with MoO3 thin layer is studied using a comprehensive synchrotron electron spectroscopy in situ approach combined with firstprinciple calculations. The at ...

AMER CHEMICAL SOC2022

Perspective-Electrochemical Stability of Water-in-Salt Electrolytes

Corsin Battaglia, David Reber

The water-in-salt approach has expanded the electrochemical stability window of aqueous electrolytes, enabling novel aqueous batteries with relatively high cell voltages and energy densities. However, the stability of these electrolytes tends to be overest ...

2020

Blumino: The First Fully Integrated Analog SiPM With On-Chip Time Conversion

Edoardo Charbon, Andrei Ardelean, Emanuele Ripiccini, Andrada Alexandra Muntean, Esteban Venialgo Araujo

Blumino is the first analog silicon photomultiplier with integrated amplifier, comparator and time-to-digital converter (TDC). The combination of a photodetector together with on-chip readout circuitry enables system-level advantages, such as internal para ...

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC2021

White-line evolution in shocked solid Ta evidenced by synchrotron x-ray absorption spectroscopy

Richard Gaal

Time-resolved x-ray absorption experiments have been performed on shocked tantalum. Using a single 100 ps synchrotron x-ray pulse, nanosecond-lived equilibrium states of shocked solid Ta have been measured by L-3-edge absorption spectroscopy. The energy sh ...

2020

Experimental Evaluation of Steel Columns under Seismic Hazard-Consistent Collapse Loading Protocols

Dimitrios Lignos

This paper presents results from 21 large-scale experiments on steel columns that examined their collapse behavior as related to steel moment resisting frames (MRFs). The test specimens included wide-flange and square hollow structural shapes (HSS) and wer ...

2021

Mixed Simulation-Experimental Optimization of a Modular Multilevel Switched Capacitors Converter Cell

Elison de Nazareth Matioli, Remco Franciscus Peter van Erp, Palliyage Srilak Nirmana Perera, Georgios Kampitsis

This work presents a mixed simulation experimental method for efficiency optimization of a modular multilevel switched capacitor DC-DC converter. The results show that the optimal frequency deviates from the circuit's self-resonant frequency, commonly prop ...

IEEE2020

Low-Power and Wide-Tuning Range Frequency Generation for FMCW Radars in Advanced CMOS Technologies

Francesco Chicco

Nowadays, the internet of things (IoT) nodes have started to spread in various domains of our society, from the industrial to the domestic environment. The remote sensing is one among their fundamental functions. The implementation of a radio detection and ...

EPFL2021

Manipulating topological spin textures in multiferroic and polar materials

Jan Hugo Dil

The possibility to manipulate spin textures is of central importance for their utilisation in functional materials. Here it will be shown how the resulting changes in the spin texture of the electronic structure can directly be imaged by spin- and angle-re ...

SPIE2020

Monocarborane cluster as a stable fluorine-free calcium battery electrolyte

Andreas Züttel, Kun Zhao

High-energy-density and low-cost calcium (Ca) batteries have been proposed as 'beyond-Li-ion' electrochemical energy storage devices. However, they have seen limited progress due to challenges associated with developing electrolytes showing reductive/oxida ...

Nature Portfolio2021

Enabling Optimal Power Generation of Flow Cell Arrays in 3D MPSoCs with On-Chip Switched Capacitor Converters

David Atienza Alonso, Marina Zapater Sancho, Alexandre Sébastien Julien Levisse, Halima Najibi

Flow cell arrays (FCAs) provide efficient on-chip liquid cooling and electrochemical power generation capabilities in three-dimensional multi-processor systems-on-chip (3DMPSoCs). When connected to power delivery networks (PDNs) of chips, the current flowi ...

IEEE2020

Strong coloration of nanoporous tungsten oxides by in-vacuo lithiation for all-solid-state electrochromic devices

Andreas Schueler, Anna Krammer, Luc Burnier, Olivia Valérie Charlotte Bouvard, Maxime Lagier

Electrochromic windows allow for an improved management of solar heat gains in buildings and enhanced visual comfort of building users. All-solid-state electrochromic devices can be especially durable. During their fabrication lithium has to be inserted, p ...

ELSEVIER SCIENCE SA2021

A Low-Power 9-Bit 222 MS/s Asynchronous SAR ADC in 65 nm CMOS

Yusuf Leblebici, Firat Çelik, Ayça Akkaya

This paper presents a 9-bit 222 MS/s low-power asynchronous single-bit/cycle successive approximation register (SAR) ADC. The SAR ADC combines techniques such as asynchronous clocking, binary-weighted custom-designed capacitive DAC with small unit capacito ...

IEEE2020