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Publication

Ionic partition diagram of tetraphenylporphyrin at the water|1,2-dichloroethane interface

Hubert Girault, Bin Su, Manuel Alejandro Méndez Agudelo
2011
Journal Articles

Résumé

diagram of 5,10,15,20-tetraphenyl-21H,23H-porphine (H2TPP) at the water|1,2-dichloroethane interface using a simple Born solvation model. This zone diagram shows under which form this porphyrin is present, i.e. neutral, monoprotonated or diprotonated, and in which phase i.e. either in the aqueous or the organic phase as a function of the aqueous pH and the interface polarisation that can be controlled externally or by the distribution of supporting electrolytes. This diagram explains why the monoprotonated form has been difficult to observe when doing biphasic pH titrations

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https://infoscience.epfl.ch/entities/publication/7acceeca-4d67-4ea1-a96c-aed92f0a4054

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Hubert Girault, Bin Su, Manuel Alejandro Méndez Agudelo
2011
Journal Articles

Résumé

Source officielle

https://infoscience.epfl.ch/entities/publication/7acceeca-4d67-4ea1-a96c-aed92f0a4054

À propos de ce résultat

Concepts associés (17)

Diagramme d'Euler

droite|vignette|upright=1.5|lang=fr|Un diagramme d'Euler illustrant que l'ensemble des « animaux à quatre pattes » est un sous-ensemble des « animaux », mais l'ensemble des « minéraux » est disjoint (il n'a pas de membres en commun) avec « animaux ».|lien=Fichier:EulerDiagram.svg%3Flang=fr Un diagramme d'Euler est un moyen de représentation diagrammatique des ensembles et des relations en leur sein. La première utilisation des « cercles Eulériens » est communément attribuée au mathématicien suisse Leonhard Euler (1707-1783).

Electrolytic capacitor

An electrolytic capacitor is a polarized capacitor whose anode or positive plate is made of a metal that forms an insulating oxide layer through anodization. This oxide layer acts as the dielectric of the capacitor. A solid, liquid, or gel electrolyte covers the surface of this oxide layer, serving as the cathode or negative plate of the capacitor. Because of their very thin dielectric oxide layer and enlarged anode surface, electrolytic capacitors have a much higher capacitance-voltage (CV) product per unit volume than ceramic capacitors or film capacitors, and so can have large capacitance values.

Aluminum electrolytic capacitor

Aluminum electrolytic capacitors are polarized electrolytic capacitors whose anode electrode (+) is made of a pure aluminum foil with an etched surface. The aluminum forms a very thin insulating layer of aluminum oxide by anodization that acts as the dielectric of the capacitor. A non-solid electrolyte covers the rough surface of the oxide layer, serving in principle as the second electrode (cathode) (-) of the capacitor. A second aluminum foil called “cathode foil” contacts the electrolyte and serves as the electrical connection to the negative terminal of the capacitor.

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Ionic partition diagram of tetraphenylporphyrin at the water|1,2-dichloroethane interface

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