Publication

Precise Control of Intramolecular Charge-Transport: The Interplay of Distance and Conformational Effects

Publications associées (30)

Efficient ab initio semiclassical dynamics for linear and nonlinear electronic spectroscopy

Molecular spectroscopy is an essential experimental technique in both fundamental physical sciences and applied research. For example, electronic spectroscopy, in which light induces a change in the electronic state of a molecule, is a powerful tool for st ...

EPFL2021

Optical properties and carrier dynamics in Co-doped ZnO nanorods

Anna Fontcuberta i Morral, Nicolas Tappy, Simon Robert Escobar Steinvall, Aswathi Kanjampurath Sivan

The controlled modification of the electronic properties of ZnO nanorods via transition metal doping is reported. A series of ZnO nanorods were synthesized by chemical bath growth with varying Co content from 0 to 20 atomic% in the growth solution. Optoele ...

ROYAL SOC CHEMISTRY2021

Structural and analytical identifications of biomolecules by cold ion spectroscopy of non-covalent complexes

Erik Saparbayev

Non-covalent interactions are ubiquitous in nature. The diversity and functionality of these interactions are employed by nature as a universal tool for building the molecular mechanism of life. Although weak, these interactions play a key role in both for ...

EPFL2021

Mono-, Di- and Tetra-iron Complexes with Selenium or Sulphur Functionalized Vinyliminium Ligands: Synthesis, Structural Characterization and Antiproliferative Activity

Paul Joseph Dyson, Lucinda Kate Batchelor, Silvia Schoch

A series of diiron/tetrairon compounds containing a S- or a Se-function (2a-d, 4a-d, 5a-b, 6), and the monoiron [FeCp(CO){SeC1(NMe2)(CHC3)-H-2(Me)}] (3) were prepared from the diiron mu-vinyliminium precursors [Fe2Cp2(CO)( mu-CO){mu-eta(1): eta(3)-C-3(R')( ...

2020

New Measurement Method in Drug Sensing by Direct Total-Charge Detection in Voltammetry

Sandro Carrara, Danilo Demarchi, José David González Martínez, Simone Aiassa

Electrochemical biosensors are promoting point-of-care and wearable instrumentation due to their high versatility in measuring human metabolites. There is a considerable number of biological compounds that can be detected and measured through voltammetry b ...

IEEE2020

Montmorillonite clay-modified disposable ink-jet-printed graphene electrode as a sensitive voltammetric sensor for the determination of cadmium(II) and lead(II)

Hubert Girault, Andreas Stephan Lesch, Victor Costa Bassetto, Milica Jovic, Léopoldine Guenang Sonfack

This work describes a new sensitive sensor for the simultaneous electrochemical determination by square wave anodic stripping voltammetry of Cd2+ and Pb2+ ions in aqueous solution, based on a disposable ink-jet-printed graphene electrode (IPGE) modifed by ...

2020

Oxygen Plasma/Bismuth Modified Inkjet Printed Graphene Electrode for the Sensitive Simultaneous Detection of Lead and Cadmium

Hubert Girault, Andreas Stephan Lesch, Victor Costa Bassetto, Milica Jovic, Prachi Gupta, Léopoldine Guenang Sonfack

In this work, a simple procedure for the preparation of an inkjet printed disposable graphene electrode is reported. Commercial graphene ink was printed on a kapton substrate and the resulting electrode was 30 min treated by oxygen plasma, then modified by ...

2020

Stabilization of p-GaAs electrode surfaces in organic solvent by bi-phenyl rings for spin dependent electron transfer studies

Jean-Philippe Ansermet, Christophe Roussel, Mika Antero Tamski

Biphenyl-4-thiol (B4t) functionalised p-GaAs photocathodes were compared to non-functionalised p-GaAs ones in the presence of methyl viologen cation radical (MV+•) as a redox mediator. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS ...

2020

Highly Loaded Mildly Edge‐Oxidized Graphene Nanosheet Dispersions for Large‐Scale Inkjet Printing of Electrochemical Sensors

Hubert Girault, Horst Pick, Andreas Stephan Lesch, Victor Costa Bassetto, Yingdi Zhu, Milica Jovic, Bhawna Nagar

Inkjet printing of electrochemical sensors using a highly loaded mildly edge‐oxidized graphene nanosheet (EOGN) ink is presented. An ink with 30 mg/mL EOGNs is formulated in a mixture of N‐methyl pyrrolidone and propylene glycol with only 30 min of sonicat ...

2020

Mapping Electrochemical Heterogeneity at Gold Surfaces: A Second Harmonic Imaging Study

Arianna Marchioro, Sylvie Roke, Igor Nahálka

Designing efficient catalysts requires correlating surface structure and local chemical composition with reactivity on length scales from nanometers to tens of microns. While much work has been done on this structure/function correlation on single crystals ...

2020