Nanophotonic Platforms for Enhanced Chiral Sensing

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Kinetically fast racemization of chiral substrates through an achiral intermediate and enantioselective functionalization of one of the enantiomeric substrates forms the basis of the dynamic kinetic resolution (DKR) of centrally chiral molecules. We report ...

Catalysts play a major role in chemical synthesis, and catalysis is considered to be a green and economic process. Catalysis is dominated by covalent interactions between the catalyst and substrate. The design of non-covalent catalysts came into limelight ...

Chirality (C) is a fundamental property of objects, in terms of symmetry. It is extremely important to sense and distinguish chiral molecules in the fields of biochemistry, science, and medicine. Vibrational circular dichroism (VCD) spectroscopy, obtained ...

We study the evolution of magnetic fields coupled with chiral fermion asymmetry in the framework of chiral magnetohydrodynamics with zero initial total chirality. The initial magnetic field has a turbulent spectrum peaking at a certain characteristic scale ...

In materials, certain approximated symmetry operations can exist in a lower-order approximation of the effective model but are good enough to influence the physical responses of the system, and these approximated symmetries were recently dubbed "quasisymme ...

Beyond the common supramolecular helical polymers in solutions, controlling single-crystal helical self-assembly with precisely defined chirality and architectures has been challenging. Here, we report that simply merging static homochiral amino acids with ...

We introduce a classification of the radial spin textures in momentum space that emerge at the high-symmetry points in crystals characterized by nonpolar chiral point groups (D2, D3, D4, D6, T, O). Based on the symmetry constraints imposed by these point g ...

Chirality is a structural property of molecules lacking mirror symmetry that has strong implications in diverse fields, ranging from life sciences to materials science. Chirality-sensitive spectroscopic methods, such as circular dichroism, exhibit weak sig ...

In this thesis, we mainly utilize silver to construct the meta-atoms. Although suffering from easily oxidized, its excellent lossless property throughout the visible range makes it suitable for study. When preserved properly, silver-made metasurfaces can s ...

Chiral optical switches, which use light to control chirality in a reversible manner, offer unique properties and fascinating prospects in the areas of molecular switching and responsive systems, new photochromic materials and molecular data processing and ...

Iron-based spin-crossover complexes hold tremendous promise as multifunctional switches in molecular devices. However, real-world technological applications require the excited high-spin state to be kinetically stable-a feature that has been achieved only ...

alpha-RuCl3 is a promising candidate material to realize the so far elusive quantum spin liquid ground state. However, at low temperatures, the coexistence of different exchange interactions couple the effective pseudospins into an antiferromagnetically zi ...

Reconfigurable metalenses are compact optical components composed by arrays of meta-atoms that offer unique opportunities for advanced optical systems, from microscopy to augmented reality platforms. Although poorly explored in the context of reconfigurabl ...

Providing an additional degree of freedom for binary information encoding and nonreciprocal information transmission, chiral single photons have become a new research frontier in quantum optics. Without using complex external conditions (e.g., magnetic fie ...

We investigate phase separation in a chiral fluid, made of spinning ferromagnetic colloids that interact both via hydrodynamic and dipolar forces and collectively organize into separated circulating clusters. We show that, at high spinning frequency, hydro ...

Constrained by the Nielsen-Ninomiya no-go theorem, in all so-far experimentally determined Weyl semimetals (WSMs) the Weyl points (WPs) always appear in pairs in the momentum space with no exception. As a consequence, Fermi arcs occur on surfaces which con ...

From a geometrical perspective, a chiral object does not have mirror planes or inversion symmetry. It exhibits the same physical properties as its mirror image (enantiomer), except for the chiroptical activity, which is often the opposite. Recent advanceme ...

Dielectric metasurfaces have emerged as a powerful platform for novel optical biosensors. Due to their low optical loss and strong light-matter interaction, they demonstrate several exotic optical properties, including sharp resonances, strong nearfield en ...

Novel two-dimensional metamaterials, known as metasurfaces, have emerged as a breakthrough platform for controlling electromagnetic wave properties at the nanoscale. These metasurfaces consist of subwavelength nanoantennas or so-called meta-atoms, which ca ...

We address the intrinsic polarization and screening of an external electric field in a broad range of ordered and twisted configurations of multilayer graphene, using an ab initio approach combining density functional theory and the Wannier function formal ...

Nanophotonic Platforms for Enhanced Chiral Sensing

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Catalytic Enantioselective Synthesis of Inherently Chiral Macrocycles by Dynamic Kinetic Resolution

Chalcogen bonding catalysis

Dielectric Tetramer Nanoresonators Supporting Strong Superchiral Fields for Vibrational Circular Dichroism Spectroscopy

Chiral magnetohydrodynamics with zero total chirality

Hierarchy of quasisymmetries and degeneracies in the CoSi family of chiral crystal materials

Architecture-Controllable Single-Crystal Helical Self-assembly of Small-Molecule Disulfides with Dynamic Chirality

Diversity of radial spin textures in chiral materials

Hard X-ray helical dichroism of disordered molecular media

Optical metasurfaces: synthesis, nanofabrication, and colorful applications

Visible light activated BINOL-derived chiroptical switches based on boron integrated hydrazone complexes

Chiral control of spin-crossover dynamics in Fe (II) complexes

Magneto-optical study of metamagnetic transitions in the antiferromagnetic phase of alpha-RuCl3

Thermally reconfigurable metalens

Plasmonic nanobar-on-mirror antenna with giant local chirality: a new platform for ultrafast chiral single-photon emission

Arrested phase separation in chiral fluids of colloidal spinners

Observation of a singular Weyl point surrounded by charged nodal walls in PtGa

Discrete metal nanoparticles with plasmonic chirality

Dielectric Metasurfaces Enabling Advanced Optical Biosensors

Metasurfaces for label-free biosensing mid-infrared optics and active photonic devices

Crystal Field Effect and Electric Field Screening in Multilayer Graphene with and without Twist