Publications associées à Optimizing the solar photo-fenton process in the treatment of contaminated water. Determination of intrinsic kinetic constants for scale-up

Publications associées (32)

Gamma noise to non-invasively monitor nuclear research reactors

Andreas Pautz, Vincent Pierre Lamirand, Oskari Ville Pakari, Pavel Frajtag, Tom Mager

Autonomous nuclear reactor monitoring is a key aspect of the International Atomic Energy Agency’s strategy to ensure nonproliferation treaty compliance. From the rise of small modular reactor technology, decentralized nuclear reactor fleets may strain the ...

Nature Research2024

OECD-NEA EXPERT GROUP ON REACTOR SYSTEMS MULTI-PHYSICS: DEVELOPMENT OF VERIFICATION AND VALIDATION GUIDELINES FOR MULTI-PHYSICS SIMULATIONS

Mathieu Hursin

Over the past decades, national and multi-national efforts have been established to develop high-fidelity, multi-physics, and multi-scale modeling and simulation (M&S) tools for design and safety challenges for existing and advanced reactors. These tools a ...

American Society of Mechanical Engineers (ASME)2024

Oxidation processes and me

Urs von Gunten

This publication summarizes my journey in the field of chemical oxidation processes for water treatment over the last 30+ years. Initially, the efficiency of the application of chemical oxidants for micropollutant abatement was assessed by the abatement of ...

Pergamon-Elsevier Science Ltd2024

Reactivity of Cyanobacteria Metabolites with Ozone: Multicompound Competition Kinetics

Urs von Gunten

Cyanobacterial blooms occur at increasing frequency and intensity, notably in freshwater. This leads to the introduction of complex mixtures of their products, i.e., cyano-metabolites, to drinking water treatment plants. To assess the fate of cyano-metabol ...

Amer Chemical Soc2024

A holistic investigation of photocatalytic hydrogen generation

Sangram Ashok Savant

Photocatalytic (PC) solar hydrogen production is a promising way to provide green hydrogen using only sunlight and abundant reactants such as water. PC approaches use catalytically active semiconductor particles suspended in liquid electrolytes. The partic ...

EPFL2023

Hydrogen Peroxide Formation during Ozonation of Olefins and Phenol: Mechanistic Insights from Oxygen Isotope Signatures

Urs von Gunten, Joanna Maria Houska

Mitigation of undesired byproducts from ozonation of dissolved organic matter (DOM) such as aldehydes and ketones is currently hampered by limited knowledge of their precursors and formation pathways. Here, the stable oxygen isotope composition of H2O2 for ...

AMER CHEMICAL SOC2023

Integrated modelling of neon impact on JET H-mode core plasmas

Yann Camenen, Michele Marin

Nuclear fusion reactor plasmas will need to exhaust a significant proportion of energy flux through radiative processes, to enable acceptable divertor loads. This can be obtained by line radiation from impurities, injected from the plasma edge. There are h ...

IOP Publishing Ltd2023

Metabolic Performance and Fate of Electrons during Nitrate-Reducing Fe(II) Oxidation by the Autotrophic Enrichment Culture KS Grown at Different Initial Fe/N Ratios

Natalia Jakus

Autotrophic nitrate-reducing Fe(II)-oxidizing (NRFeOx) microorganisms fix CO2 and oxidize Fe(II) coupled to denitrification, influencing carbon, iron, and nitrogen cycles in pH-neutral, anoxic environments. However, the distribution of electrons from Fe(II ...

AMER SOC MICROBIOLOGY2023

Design and operational guidelines of solar-driven catalytic conversion of CO2 and H2 to fuels

Sophia Haussener, Sha Li

Sunlight-powered catalytic conversion of CO2 and (green) H2 into fuels and chemicals via Sabatier and reverse water gas shift (RWGS) processes offers a promising solution to reduce greenhouse gas emissions and increase renewable energy utilization. The suc ...

ELSEVIER SCI LTD2023

Oxidative Water Treatment: The Track Ahead

Urs von Gunten

Chemical oxidation has been applied in municipal water treatment for more than a century, initially for disinfection. In the early decades, chlorine disinfection was adopted in the fight against waterborne disease. However, the oxidative properties of chlo ...

2023

Kinetic Network Modeling of the Catalytic Upgrading of Biomass's Acetate Fraction to Aromatics

Jeremy Luterbacher, Jher Hau Yeap, Bartosz Rozmyslowicz

The acetate fraction is the fourth most abundant fraction by weight in many plant species and can be easily extracted as acetic acid in high yields. We have previously shown that acetic acid obtained from steam pretreated beech wood could be upgraded in a ...

Amer Chemical Soc2023

Advanced methodologies for modeling and assessment of SFR safety functions

Janos Bodi

The present doctoral work was performed to contribute to the conceptual design development and safety assessment of a Generation IV Sodium Fast Reactor (SFR) in the frame of the European Sodium Fast Reactor Safety Measures Assessment and Research Tools (ES ...

EPFL2022

Thermodynamic modelling of hydrogen production in sorbent-enhanced biochar-direct chemical looping process

Zezhong Li

Hydrogen (H-2) has been widely considered the clean energy carrier of choice for emerging renewable energy generation technologies. However, H-2 is a secondary fuel mainly derived from natural gas. Over the past decades, research on developing H-2 producti ...

2022

Enhanced Solar-to-Fuel Efficiency of Ceria-Based Thermochemical Cycles via Integrated Electrochemical Oxygen Pumping

Sophia Haussener, Meng Lin, Clemens Gregor Suter

The solar thermochemical cycle based on ceria is a promising route for renewable fuel production. The solar-to-fuel efficiency of a thermochemical reactor is highly dependent on the oxygen removal during the reduction step. Conventional nitrogen sweeping ( ...

AMER CHEMICAL SOC2022

Alpha-Nickel Hydroxide Coating of Metallic Nickel for Enhanced Alkaline Hydrogen Evolution

Yunchang Liang

In this work, alkaline hydrogen evolution reaction (HER) processes of three typical nickel-based electrocatalysts [i.e., Ni, alpha-Ni(OH)(2), and beta-Ni(OH)(2)] were investigated to probe critical factors that determine the activity and durability. The HE ...

WILEY-V C H VERLAG GMBH2022

Investigation and Validation of Unstructured Mesh Methodologies for Modeling Experimental Reactors

Andreas Pautz, Mathieu Hursin, Carlo Fiorina, Tom Mager

This paper summarizes a methodology developed at Ecole Polytechnique Federale de Lausanne for the neutronic modeling of the CROCUS experimental reactor and proposes solutions to the challenges one may face while modeling a research reactor with a complex g ...

MDPI2022

Multi-physics modeling of VVERs with high fidelity high-resolution codes

Marianna Papadionysiou

The calculations performed for the design and operation of a Nuclear Power Plant (NPP) are a key factor for their safety analyses. The standard for the computational analysis of NPPs is the so called conventional approach, which relies on coarse mesh diffu ...

EPFL2022

Microfluidic study in a meter-long reactive path reveals how the medium’s structural heterogeneity shapes MICP-induced biocementation

Lyesse Laloui, Dimitrios Terzis, Ariadni Elmaloglou

Microbially induced calcium carbonate (CaCO3) precipitation (MICP) is one of the major sustainable alternatives to the artificial cementation of granular media. MICP consists of injecting the soil with bacterial- and calcium-rich solutions sequentially to ...

Nature Research2022

Toward biocontrol of waterborne pathogens: contributions of protists to virus removal and associated mechanisms

Margot Ninon Lauren Olive

Human viruses are widespread in the water environment and pose a risk to human health. Wastewater effluents represent the main source of viruses discharge in the environment, leading to contamination of aquatic ecosystems. Viral pathogens can persist on th ...

EPFL2022

Prospects and challenges in designing photocatalytic particle suspension reactors for solar fuel processing

Sophia Haussener, Swarnava Nandy, Sangram Ashok Savant

Photocatalytic approaches for the production of solar hydrogen or hydrocarbons are interesting as they provide a sustainable alternative to fossil fuels. Research has been focused on water splitting and on the synthesis of photocatalyst materials and compo ...

2021