A bimetallic ruthenium ethylene complex as a catalyst precursor for the Kharasch reaction

Chattez avec Graph Search

Posez n’importe quelle question sur les cours, conférences, exercices, recherches, actualités, etc. de l’EPFL ou essayez les exemples de questions ci-dessous.

AVERTISSEMENT : Le chatbot Graph n'est pas programmé pour fournir des réponses explicites ou catégoriques à vos questions. Il transforme plutôt vos questions en demandes API qui sont distribuées aux différents services informatiques officiellement administrés par l'EPFL. Son but est uniquement de collecter et de recommander des références pertinentes à des contenus que vous pouvez explorer pour vous aider à répondre à vos questions.

Using acetal-stabilized lignin we performed a truly steady state continuous high-yielding lignin depolymerization (45% monophenolics using Ni/C), which offered a window into challenges and opportunities that will be faced when processing this feedstock. Wi ...

Supercritical water gasification (SCWG) is a promising and versatile technology for the conversion of a variety of wet biomass streams into renewable natural gas. In this work, the focus was set on methane production with the help of an active and stable m ...

We found that cyclometalated cyclopentadienyl iridium(III) complexes are uniquely efficient catalysts in homogeneous hydrogenation of oximes to hydroxylamine products. A stable iridium C,N-chelation is crucial, with alkoxy-substituted aryl ketimine ligands ...

The development of new catalytic methods for organic synthesis is a critical endeavour in order to obviate the economic and ecological drawbacks of stoichiometric organic synthesis. While catalysis can offer significant advantages in terms of atom-economy, ...

Achieving fundamental understanding of enantioselective heterogeneous synthesis is marred by the permanent presence of multitudinous arrangements of catalytically active sites in real catalysts. In this study, we address this issue by using structurally co ...

Supported Pd-based catalysts used in heterogeneously catalyzed liquid phase processes often undergo an activation step through reduction of the oxide phase or of the oxidic passivation layer prior to reaction. An oxidized Pd/Al2O3 catalyst was reduced by u ...

Among all CO2 electroreduction products, methane (CH4) and ethylene (C2H4) are two typical and valuable hydrocarbon products which are formed in two different pathways: hydrogenation and dimerization reactions of the same CO intermediate. Theoretical studi ...

The electrochemical CO2 reduction reaction (CO2RR) is envisioned to play a significant role in achieving carbon neutrality while contributing to storing renewable energies. Cu-based materials are among the most promising electrocatalysts. However, 16 diffe ...

Methane abatement pathways in Pd/Rh three-way catalysts have been investigated in three scales ranging from a vehicle application size catalyst, a model gas reactor and the catalyst in powder form. A special test rig was designed for the investigation of v ...

The increasing urgency to make chemical processes more environmentally friendly while continuing to derive the chemicals required for modern society from renewable resources requires the development of a forthcoming generation of synthetic processes and th ...

C-C and C-N bonds are some of the most common structures in molecules ranging from drugs to catalysts and to food additives. Many coupling reactions were developed to form these types of bonds with excellent selectivity and good performance. Still, the syn ...

The activation of small molecule is a topic of high current interest. A variety of homogeneous end heterogeneous catalysts have been studied to be able to promote chemical transformation of industrial relevance under mild condition and therefore decrease t ...

Metal oxide deposition is an emerging synthetic technique for designing heterogeneous catalysts. Depositing a nanoscale overcoat of metal oxide on heterogeneous catalysts can modify their structural and chemical characteristics. Many deposition approaches, ...

A bimetallic ruthenium ethylene complex as a catalyst precursor for the Kharasch reaction

Chattez avec Graph Search

Continuous hydrogenolysis of acetal-stabilized lignin in flow

Supported ruthenium nanoparticles for supercritical water gasification - synthesis, activity and stability

Iridium-Catalyzed Acid-Assisted Hydrogenation of Oximes to Hydroxylamines

Developing the Catalytic Applications of 1,3,2-Diazaphospholenes

Asymmetric azide-alkyne Huisgen cycloaddition on chiral metal surfaces

Reduction of PdO/Al2O3 in Liquid Cyclohexane Followed In Situ by ATR-IR, High-Energy XRD, and XAS

Controllable CO adsorption determines ethylene and methane productions from CO2 electroreduction

Cu/Metal Oxide Hybrid Nanocrystals as Electrocatalysts for the CO2 Reduction Reaction

Reaction pathways of methane abatement in Pd-Rh three-way catalyst in heavy duty applications: A combined approach based on exhaust analysis, model gas reactor and DRIFTS measurements

Data-Driven Advancement of Homogeneous Nickel Catalyst Activity for Aryl Ether Cleavage

Synthetic methodologies for C-C and C-N bond formation involving alkyl radicals

Activation of small molecules promoted by multimetallic complexes supported by redox active ligands

Synthesis of heterogeneous catalysts with metal oxide overcoat for renewable catalysis applications