Publications associées à The Use of Passive Samplers to Reveal Industrial and Agricultural Pollution Trends in Swiss Rivers

Process-Induced Structures of Injection-Molded High-Density Polyethylene-Combining X-ray Scattering and Finite Element Modeling

The success of plastics heavily relies on fast melt processing methods used for large-scale industrial manufacturing, including injection molding. The hierarchical structure of the solid polymer depends on material selection combined with processing condit ...

Amer Chemical Soc2024

Spatiotemporal Dynamics of Flow and Hydrochemistry in Drainage Networks

Izabela Bujak-Ozga

Despite their high ecological value, non-perennial streams have received less attention than their perennial counterparts. This doctoral thesis addresses this disparity by advancing knowledge on the dynamics of the drainage density and hydrologic processes ...

EPFL2024

Scanning Small-Angle X-ray Scattering of Injection-Molded Polymers: Anisotropic Structure and Mechanical Properties of Low-Density Polyethylene

Marianne Liebi, Manuel Guizar Sicairos

Injection molding is known to create a layered anisotropicmorphologyacross the sample thickness due to varying shear and cooling ratesduring the manufacturing process. In this study, scanning small-angleX-ray scattering was used to visualize and quantify t ...

AMER CHEMICAL SOC2023

Quantified Effects of Multiple Parameters on Inputs and Potential Sources of Microplastics from a Typical River Flowing into the Sea

Florian Frédéric Vincent Breider, Wenxin Liu, Yang Liu

As an important connection of terrestrial and marine ecosystems, rivers input multitudinous (micro)plastics into the oceans. However, comparisons of field and estimated riverine inputs of (micro)plastics and contributions of multiple parameters are limited ...

2022

Water Orientation at the Anatase TiO2 Nanoparticle Interface: A Probe of Surface pKa Values

Arianna Marchioro, Marie Bischoff

The acid-base properties of surfaces significantly influence catalytic and (photo)electrochemical processes. Estimation of acid dissociation constants (pKa values) for colloids is commonly performed through electroanalytical techniques or spectroscopic met ...

AMER CHEMICAL SOC2022

Insights into the Horizontal and Vertical Profiles of Microplastics in a River Emptying into the Sea Affected by Intensive Anthropogenic Activities in Northern China

Florian Frédéric Vincent Breider, Wenxin Liu, Yang Liu

Studies focused only on surface water may underestimate microplastic abundance in aquatic environments. This was the first survey to investigate the vertical (surface, intermediate, and bottom waters) distribution and composition of microplastics (MPs) in ...

2021

Highly Efficient Activation of HCl Dissociation on Au(111) via Rotational Preexcitation

Rainer Beck

The probability for dissociation of molecules on metal surfaces, which often controls the rate of industrially important catalytic processes, can depend strongly on how energy is partitioned in the incident molecule. There are many example systems where th ...

2021

Development and Characterization of Rice Husk and Recycled Polypropylene Composite Filaments for 3D Printing

Véronique Michaud

Nowadays the use of natural fiber composites has gained significant interest due to their low density, high availability, and low cost. The present study explores the development of sustainable 3D printing filaments based on rice husk (RH), an agricultural ...

2021

The Solvent Effect on H2O2 Generation at Room Temperature Ionic Liquid|Water Interface

Hubert Girault

H2O2 is a versatile chemical and can be generated by the oxygen reduction reaction (ORR) in proton donor solution in molecular solvents or room temperature ionic liquids (IL). We investigated this reaction at interfaces formed by eleven hydrophobic ILs and ...

2021

Past and future impacts of climate change on swiss river temperature and discharge investigated with data analysis and numerical modelling

Adrien Michel

This thesis presents the first large-scale assessment of past, present and future impacts of climate change on river temperatures in Switzerland. Water temperature is a crucial factor influencing, among others, the health of aquatic ecosystems, the industr ...

EPFL2021

Effects of Anthropogenic Discharge and Hydraulic Deposition on the Distribution and Accumulation of Microplastics in Surface Sediments of a Typical Seagoing River: The Haihe River

Florian Frédéric Vincent Breider, Wenxin Liu, Yang Liu

Microplastics pollution in river systems has generated great concern; however, few studies have focused on the contributions of multiple influencing factors to microplastics in river systems. In the current study, we utilized data on microplastics in surfa ...

2020

Investigation and modeling of odors release from membrane holes on daily overlay in a landfill and its impact on landfill odor control

Sami Rtimi

In the present work, we studied the NH(3)and H2S odor fluxes between the exposed working area and the HDPE covering film holes of the daily overlay in an actual landfill site with a daily operating area of 1600 m(2)in Hangzhou, China. We showed that the od ...

2021

Reversibly Cross-Linking Polymer Brushes Using Interchain Disulfide Bonds

Harm-Anton Klok, Piotr Mocny

The introduction of interchain cross-links in surface-grafted polymer brushes increases the robustness and mechanical properties of these thin polymer films. In most cases, cross-linked polymer brushes contain permanent interchain cross-links. The use of r ...

American Chemical Society2020

Trace Iridium Engineering on Nickel Hydroxide Nanosheets as High-active Catalyst for Overall Water Splitting

Pengzuo Chen, Yun Tong

Designing cost-effective electrocatalysts for electrochemical water splitting to generate the hydrogen energy as a future energy source is pivotal. An excellent catalyst should show high catalytic activity for both hydrogen evolution reaction (HER) and oxy ...

Wiley-VCH Verlag2020

Hydropeaking mitigation measures in the Swiss Upper-Rhône basin

Pedro Filipe De Almeida Manso, Steve Crettenand, Sabine Chamoun, Mathieu Pierre Guy Barnoud

Hydropower operations can cause hydropeaking particularly in the case of pumped storage systems located in mountainous regions. Due to the rapidly varying discharge conditions, hydropeaking leads to several problems such as stranding of fishes and inverteb ...

2019

Testing diﬀerent (e)DNA metabarcoding approaches to assess aquatic oligochaete diversity and the biological quality of sediments

Régis Lionel Vivien

Aquatic oligochaetes are important bioindicators of sediment quality in watercourses and lakes, but their morphological identiﬁcation to the species level is challenging and sometimes impossible. The use of DNA barcoding and metabarcoding could greatly fac ...

2019

Detailed Analysis of Estimated pH, Activity Coefficients, and Ion Concentrations between the Three Aerosol Thermodynamic Models

Yan Feng, Athanasios Nenes

In this work, we utilize a rich set of simulated and ground-based observational data in Tianjin, China to examine and compare the differences in aerosol acidity and composition predicted by three popular thermodynamic equilibrium models: ISORROPIA II, the ...

AMER CHEMICAL SOC2019

Next generation UHPFRC for sustainable structural applications

Emmanuel Denarié, Amir Hajiesmaeili

Over the last few decades, ever-increasing demands of society to the built environment have continually increased consumption of energy and materials for the construction and maintenance of structures. Meanwhile, Strain Hardening Ultra High-Performance Fib ...

2018

Extracellular bacterial inactivation proceeding without Cu-ion release: Drastic effects of the applied plasma energy on the performance of the Cu-polyester (PES) samples

Michaël Bensimon, Sami Rtimi

The widely different effects of Cu-polyester (PES) sputtered by high power impulse magnetron sputtering (HIPIMS) compared to the lower energy direct current magnetron sputtering (DCMS) leading to bacterial inactivation are addressed during the course of th ...

ELSEVIER SCIENCE BV2018

Equilibrium and Out-of-Equilibrium Adherence of Hydrogels against Polymer Brushes

Costantino Creton, Jennifer Mary Adrienne Alice Macron

At low pH, underwater adherence between poly(N,N-dimethylacrylamide) hydrogels and poly(acrylic acid) brushes is due to the formation of multiple hydrogen bonds. The effect of the key parameters controlling the formation of these interactions (contact time ...

American Chemical Society2018