Publications associées à High Extinction Coefficient "Antenna" Dye in Solid-State Dye-Sensitized Solar Cells: A Photophysical and Electronic Study

Publications associées (19)

A spiro-type self-assembled hole transporting monolayer for highly efficient and stable inverted perovskite solar cells and modules

Self-assembled monolayers (SAMs) have significantly contributed to the advancement of hole transporting materials (HTMs) for inverted perovskite solar cells (PSCs). However, uneven distribution of SAMs on the substrate largely decreases the PSC performance ...

2024

Controlling Tin Halide Perovskite Oxidation Dynamics in Solution for Perovskite Optoelectronic Devices

Mohammad Khaja Nazeeruddin, Paul Joseph Dyson, Zhaofu Fei, Aurélien Bornet, Roland Christopher Turnell-Ritson, Shun Tian, Guixiang Li

As a leading contender to replace lead halide perovskites, tin-based perovskites have demonstrated ever increasing performance in solar cells and light-emitting diodes (LEDs). They tend to be processed with dimethyl sulfoxide (DMSO) solvent, which has been ...

Wiley-VCH Verlag GmbH2024

Free Charge Carrier Generation by Visible-Light-Absorbing Organic Spacers in Ruddlesden-Popper Layered Perovskites

Jacques-Edouard Moser, Jun Ho Yum, Kevin Sivula, Natalie Renuka Banerji, Aaron Tomas Terpstra, Simon Nussbaum

Incorporating organic semiconductor building blocks as spacer cations into layered hybrid perovskites provides an opportunity to develop new materials with novel optoelectronic properties, including nanoheterojunctions that afford spatial separation of ele ...

2024

Molecular engineering of low-cost, efficient, and stable photosensitizers for dye-sensitized solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Marina Freitag, Jing Gao, Felix Thomas Eickemeyer, Zhongjin Shen, Lukas Pfeifer

The cost, stability, and photovoltaic performance of photosensi-tizers play a key role in the commercialization of dye-sensitized solar cells (DSCs). Herein, three novel sensitizers termed ZS10, ZS11, and ZS12 are described based on the simple chemical str ...

Cell Press2023

Investigation in Crystal Growth/Morphology and Interface Engineering of Perovskite Solar Cells by Different Deposition Methods

Nadja Isabelle Desiree Klipfel

A new and promising technology has emerged to compete with traditional silicon photovoltaic semiconductors. The low material and processing costs and high-power conversion efficiencies of organic-inorganic metal halide perovskites make these a promising te ...

EPFL2022

Urea Derivative-Promoted CsPbl(2)Br Perovskite Solar Cells with High Open-Circuit Voltage

Bowen Yang

Inorganic perovskite solar cells (PSCs) have witnessed extraordinary advances owing to their prominent stability against thermal aging. However, they suffer from a phase transition from black phase to yellow phase under ambient conditions and serious energ ...

WILEY-V C H VERLAG GMBH2022

Nanoscale Phase Segregation in Supramolecular π-Templating for Hybrid Perovskite Photovoltaics from NMR Crystallography

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, Ulf Anders Hagfeldt, Marko Mladenovic, Dominik Józef Kubicki, Manuel Cordova, David Lyndon Emsley, Farzaneh Jahanbakhshi, Paramvir Ahlawat, Yuhang Liu, Brian Irving Carlsen, Jovana Milic, Rashmi Runjhun, Aditya Mishra, Michael Allan Hope

The use of layered perovskites is an important strategy to improve the stability of hybrid perovskite materials and their optoelectronic devices. However, tailoring their properties requires accurate structure determination at the atomic scale, which is a ...

2021

Third-Generation Solar Cells: Toxicity and Risk of Exposure

Thierry Meyer, Anna Maria Novello, Elina Buitrago

Solar energy is considered clean energy, and its use is predicted to increase in the near future. Most installed units today are crystalline solar cells, but the field is in constant development, and when the first dye sensitized solar cell was published b ...

2020

Electron-Selective Layers for Dye-Sensitized Solar Cells Based on TiO2 and SnO2

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ladislav Kavan

Titanium dioxide (anatase, rutile) and quasi-amorphous tin dioxide are prepared on F-doped SnO2 in the form of dense thin films, which can serve as electron-selective layers in perovskite solar cells and dye-sensitized solar cells (DSSCs). The present stud ...

2020

The Advent of Molecular Photovoltaics and Hybrid Perovskite Solar Cells

Michael Graetzel, Jovana Milic

Over the past decade, we witnessed a remarkable development of a new generation of photovoltaic technologies, in particular dyesensitized and perovskite solar cells. These systems have demonstrated potential to provide solutions for a more sustainable futu ...

2019

Solar-Electrochemical Devices for Water Splitting and Chlorine Generation

Enrico Chinello

Solar technologies hold the potential to ultimately counteract the effects of climate change. Nevertheless, the intermittency of sunlight poses technical challenges regarding the storage of the surplus production and the supply of the deficit. The generat ...

EPFL2019

Perovskite Solar Cells: 18% Efficiency Using Zn(II) and Cu(II) Octakis(diarylamine)phthalocyanines as Hole-Transporting Materials

Mohammad Khaja Nazeeruddin, Kasparas Rakstys, Valentin Ianis Emmanuel Queloz, Kyung Taek Cho, Marius Franckevicius, Sanghyun Paek, Hiroyuki Kanda

Metallophthalocyanines (MPcs) are currently emerging as alternative hole-transporting materials (HTMs) in perovskite solar cells (PSCs). However, the lack of systematic structure/photovoltaic properties investigations still hampers the rational design of M ...

2019

Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency

Michael Graetzel, Mohammad Khaja Nazeeruddin, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Konrad Domanski, Wolfgang Richard Tress, Juan-Pablo Correa-Baena, Antonio Abate, Jiyoun Seo, Michael Saliba

Today's best perovskite solar cells use a mixture of formamidinium and methylammonium as the monovalent cations. With the addition of inorganic cesium, the resulting triple cation perovskite compositions are thermally more stable, contain less phase impuri ...

Royal Society of Chemistry2016

Semi-transparent perovskite solar cells for tandems with silicon and CIGS

Michael Graetzel, Norman Pellet, Julian Burschka

A promising approach for upgrading the performance of an established low-bandgap solar technology without adding much cost is to deposit a high bandgap polycrystalline semiconductor on top to make a tandem solar cell. We use a transparent silver nanowire e ...

Royal Society of Chemistry2015

Resonance Raman and Excitation Energy Dependent Charge Transfer Mechanism in Halide-Substituted Hybrid Perovskite Solar Cells

Ulf Anders Hagfeldt

Organo-metal halide perovskites (OMHPs) are materials with attractive properties for optoelectronics. They made a recent introduction in the photovoltaics world by methylammonium (MA) lead triiodide and show remarkably improved charge separation capabiliti ...

American Chemical Society2015

Electrical transport in C-doped GaAs nanowires: surface effects

Anna Fontcuberta i Morral, Martin Heiss, Esther Alarcon Llado, Eleonora Russo, Alberto Casadei, Fauzia Jabeen

The resistivity and mobility of carbon-doped GaAs nanowires have been studied for different doping concentrations. Surface effects have been evaluated by comparing unpassivated with passivated nanowires. We directly see the influence of the surface: the pi ...

Wiley-Blackwell2013

Influence of the Anchoring Modes on the Electronic and Photovoltaic Properties of D−π–A Dyes

Michael Graetzel, Jacques-Edouard Moser, Shaik Mohammed Zakeeruddin, Robin Humphry-Baker, Takeru Bessho, Magdalena Anna Marszalek, Mateusz Barnaba Wielopolski

Five new donor−π-bridge−acceptor (D−π−A) organic sensitizers with cyano and/or triple bond substituted benzoic acid as acceptor/anchoring groups were synthesized and tested for their performance in dye-sensitized solar cells (DSCs). The systematic incorpor ...

Amer Chemical Soc2012

Increasing the efficiency of zinc-phthalocyanine based solar cells through modification of the anchoring ligand

Michael Graetzel, Mohammad Khaja Nazeeruddin, Jun Ho Yum

Several zinc-based phthalocyanines have been synthesized and used in Dye-Sensitized Solar Cells (DSSC). The results have been compared with the standard TT1 phthalocyanine, which shows good light-to-energy conversion efficiencies in comparison with other I ...

2011

CdSe quantum dot (QD) and molecular dye hybrid sensitizers for TiO2 mesoporous solar cells: working together with a common hole carrier of cobalt complexes

Michael Graetzel, Mohammad Khaja Nazeeruddin, Shaik Mohammed Zakeeruddin

Redox couples based on cobalt complexes were found to be effective in regenerating both inorganic CdSe quantum dot-and organic dye-sensitizers. The hybrid sensitizer composed of CdSe QD and ruthenium sensitizer (Z907Na) dye showed a maximum power conversio ...

Royal Society of Chemistry2010