Atmospheric breakdown chemistry of the new "green" solvent2,2,5,5-tetramethyloxolane via gas-phase reactions with OH and Cl radicals

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Metal ions are indispensable cofactors for many proteins and play crucial roles in numerous biological processes, yet the computational design of metalloproteins and the optimization of metal coordination sites poses significant challenges due to the comp ...

Ozonation is used worldwide for drinking water disinfection and increasingly also for micropollutant abatement from wastewater. Identification of transformation products formed during the ozonation of micropollutants is challenging due to several factors i ...

Mountain snowpack forecasting relies on accurate mass and energy input information in relation to the snowpack. For this reason, coupled snow-atmosphere models, which downscale input fields to the snow model using atmospheric physics, have been developed. ...

The chemistry of divalent lanthanides has generated increasing interest in the past years due to their redox properties and unique reaction pathways. Notably, molecular complexes of low-valent lanthanides have been shown to be suitable one-electron reducta ...

Turbulent mixing controls the vertical transfer of heat, gases and nutrients in stratified water bodies, shaping their response to environmental forcing. Nevertheless, due to technical limitations, the redistribution of wind-derived energy fuelling turbule ...

Uranium nitride compounds are important molecular analogues of uranium nitride materials such as UN and UN2 which are effective catalysts in the Haber-Bosch synthesis of ammonia, but the synthesis of molecular nitrides remains a challenge and studies of th ...

Low bioavailability of iron due to poor solubility of iron(hydr)oxides limits the growth of microorganisms and plants in soils and aquatic environments. Previous studies described accelerated dissolution of iron(hydr)oxides under continuous illumination, b ...

Gathering information on the atomic nature of reactive sites and trap states is key to fine tuning catalysis and suppressing deleterious surface voltage losses in photoelectrochemical technologies. Here, spectroelectrochemical and computational methods wer ...

Reaction of N-arylsulfonyl allylamines with alkyl nitriles in the presence of di-tert-butyl peroxide (DTBP) and a catalytic amount of copper salt afforded homologated aziridines in 43-86% yield. A sequence involving addition of the in situ generated cyanom ...

Atmospheric breakdown chemistry of the new "green" solvent2,2,5,5-tetramethyloxolane via gas-phase reactions with OH and Cl radicals

Chattez avec Graph Search

Engineering of stable and functional metalloproteins using evolutionary computation, deep learning and simulation

Achieving realistic ozonation conditions with synthetic water matrices comprising low-molecular-weight scavenger compounds

Seasonal snow-atmosphere modeling: let's do it

Stabilizing Unusual Oxidation States of Lanthanides in Molecular Complexes: Synthesis, Properties, and Reactivity

Seasonality modulates wind-driven mixing pathways in a large lake

Synthesis, structure, and reactivity of uranium(VI) nitrides

Catalytic effects of photogenerated Fe(II) on the ligand-controlled dissolution of Iron(hydr)oxides by EDTA and DFOB

Identifying Reactive Sites and Surface Traps in Chalcopyrite Photocathodes

Copper-Catalyzed Cyanoalkylative Aziridination of N-Sulfonyl Allylamines