Synthesis and spectroscopy of anionic tridentate benzimidazole-pyridine carboxylate and tetrazolate chromophore ligands

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The high stability of the + IVoxidation state limits thorium redox reactivity. Here we report the synthesis and the redox reactivity of two Th(IV) complexes supported by the arene-tethered tris(siloxide) tripodal ligands [(KOSiR2Ar)3-arene)]. The two-elect ...

This dataset accompanies the publication "Best practices in measuring absorption at the macro- and microscale" published in APL Photonics. The data can be used to reproduce original plots in figures 1-4 in the main text and all original plots in the suppor ...

Multilayer vesicles with an onion-like architecture can form by self-assembly of organic amphiphiles such as dendrimers, small-molecule surfactants, and block copolymers. Thus far, there are limited reports about multilayer vesicles based on coordination c ...

The combination of palladium salts and bipyridyl ligands can lead to the formation of a large variety of coordination complexes, with different shapes and sizes, displaying a very versatile host-guest chemistry. Increasing their structural complexity remai ...

Bent (hetero)allenes such as carbodicarbenes and carbodiphosphoranes can act as neutral C-donor ligands, and diverse applications in coordination chemistry have been reported. N-Heterocyclic diazoolefins are heterocumulenes, which can function in a similar ...

Solving native structures of such large molecules, like biomolecules, is often challenging, particularly due to the potentially infinite number of non-covalent interactions with water. In this thesis, we report the use of cold ion gas-phase action spectros ...

The isomerization of iridium(III) complexes with metalated N-heterocyclic carbene (NHC) ligands was studied. The fac isomers of complexes with 1-phenyl-3-methylbenzimidazolin-2-ylidene or 1-phenyl-3-benzylbenzimidazolin-2-ylidene ligands are transformed cl ...

This study examines the impact of light absorption from biomass burning (BB) brown carbon (BrC) in the Mediterranean basin from local and distant fire incidents during a typical fire season in August 2019 and under severe fire activity in August 2021. The ...

The chemistry of divalent lanthanides has generated increasing interest in the past years due to their redox properties and unique reaction pathways. Notably, molecular complexes of low-valent lanthanides have been shown to be suitable one-electron reducta ...

Sound absorption at low frequencies still remains a challenge in both scientific research and engineering practice. Natural porous materials are ineffective in this frequency range, as well as acoustic resonators which present too narrow bandwidth of absor ...

Biomass burning emissions often contain brown carbon (BrC), which represents a large family of light-absorbing organics that are chemically complex, thus making it difficult to estimate their absorption of incoming solar radiation, resulting in large uncer ...

Light matter interactions such as extinction, reflection, and transmission can be described by classical optics. Dur-ing the past decades, research focused on a novel resonant extinction type called plasmonics that allows for en-hancement of both types of ...

Pigments homologous to the green fluorescent protein (GFP) have been proposed to fine-tune the internal light microclimate of corals, facilitating photoacclimation of photosynthetic coral symbionts (Symbiodiniaceae) to life in different reef habitats and e ...

The visual appearance of any colorized object is usually determined by the spectral absorption of either pigments or dyes. One can however also colorize objects with structural colors that typically have an iridescent appearance, as seen on many beetles. T ...

Most logic synthesis algorithms work on graph representations of logic functions with nodes associated with arbitrary logic expressions or simple logic functions and iteratively optimize such graphs. While recent multilevel logic synthesis efforts focused ...

In snow and ice, light-absorbing particles (LAPs), such as black carbon (BC) and dust, accelerate the melting of Third Pole glaciers (TPGs). In this study, we revaluated LAP concentrations in the snow pits of TPGs (SP-TPGs), measured LAP mass absorption cr ...

Metal-organic frameworks(MOFs) are promising materials for photocatalytic applications. MOFs modular and porosity structure provides a platform to assemble photo-active and catalytic-sites building block units that can offer unique photo-physics. This feat ...

This study focuses on the effects of ozonation on the optical and photochemical properties of dissolved organic matter (DOM). Upon ozonation, a decrease in light absorption properties of DOM was observed concomitantly with a large increase in singlet oxyge ...

The increasing interest in the fate of organic contaminants in the aquatic environment requires the elucidation of relevant abiotic transformation processes. These processes often involve the ubiquitous dissolved organic matter (DOM), a complex mixture of ...

Non-covalent interactions are ubiquitous in nature. The diversity and functionality of these interactions are employed by nature as a universal tool for building the molecular mechanism of life. Although weak, these interactions play a key role in both for ...

Synthesis and spectroscopy of anionic tridentate benzimidazole-pyridine carboxylate and tetrazolate chromophore ligands

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Two-Electron Redox Reactivity of Thorium Supported by Redox-Active Tripodal Frameworks

Dataset to accompany publication "Best practices in measuring absorption at the macro- and microscale"

Nano onions based on an amphiphilic Au3(pyrazolate)3 complex

Palladium-based supramolecular assemblies: from complex structures to water-soluble anion-receptors

Synthesis and Reactivity of an Anionic Diazoolefin

Bridging Native and Intrinsic Structures of Microhydrated Biomolecules by Cold Ion Spectroscopy

The acid-mediated isomerization of iridium(iii) complexes with cyclometalated NHC ligands: kinetic vs. thermodynamic control

Brown carbon absorption in the Mediterranean basin from local and long-range transported biomass burning air masses

Stabilizing Unusual Oxidation States of Lanthanides in Molecular Complexes: Synthesis, Properties, and Reactivity

PID-like active impedance control for electroacoustic resonators to design tunable single-degree-of-freedom sound absorbers

Light absorption by brown carbon over the South-East Atlantic Ocean

Engineering Absorption for Foil Applications

Green fluorescent protein-like pigments optimise the internal light environment in symbiotic reef-building corals

Remarkable Color Gamut Enhancement of Dye Lacquers Using Corrugated Surfaces

Three-Input Gates for Logic Synthesis

Black carbon and dust in the Third Pole glaciers: revaluated concentrations, mass absorption cross-sections and contributions to glacier ablation

Computational studies for the description of electronic and optical properties for photocatalysis in Metal Organic Frameworks

Optical properties and photochemical production of hydroxyl radical and singlet oxygen after ozonation of dissolved organic matter

Phototransformation of Organic Contaminants in Aquatic Systems: Characterization of Long-Lived Photooxidants Derived from Dissolved Organic Matter

Structural and analytical identifications of biomolecules by cold ion spectroscopy of non-covalent complexes