Ligands for metal organic frameworks and a catalyst-free method of making such

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Publications associées (4)

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Ionic mononuclear [Fe] and heterodinuclear [Fe,Ru] bis (diphenylphosphino)alkane complexes: Synthesis, spectroscopy, DFT structures, cytotoxicity, and biomolecular interactions

Mouna Hadiji

Iron(II) and Ru(II) half-sandwich compounds encompass some promising pre-clinical anticancer agents whose efficacy may be tuned by structural modification of the coordinated ligands. Here, we combine two such bioactive metal centres in cationic bis(dipheny ...

2023

Combined Effects of Fe(III)-Bearing Clay Minerals and Organic Ligands on U(VI) Bioreduction and U(IV) Speciation

Zezhen Pan

Reduction of U(VI) to U(IV) drastically reduces its solubility and has been proposed as a method for remediation of uranium contamination. However, much is still unknown about the kinetics, mechanisms, and products of U(VI) bioreduction in complex systems. ...

AMER CHEMICAL SOC2021

Solvent effects in catalysis: rational improvements of catalysts via manipulation of solvent interactions

Paul Joseph Dyson

In homogeneous catalysis, the main emphasis on improving catalyst performance (rate, yield and selectivity) is directed towards manipulation of the ligands. The steric and electronic effects of ligands are extremely well understood and the rational design ...

2016

Benign synthesis of the unsymmetrical ligand N-(quinolin-8-yl) pyrazine-2-carboxamide. Preparation, electrochemistry, antibacterial activity, and crystal structures of Cu(II) and Zn(II) complexes

Farzaneh Fadaei Tirani

Hqpzc has been synthesized by a highly efficient procedure using the ionic liquid TBAB as an environmentally benign reaction medium. [Cu(qpzc)(OAc)]H2O (1) and [Zn(qpzc)(OAc)(H2O)] (2), complexes of the deprotonated ligand, qpzc [qpzc ...

Taylor & Francis Ltd2013