Synthesis and equation of state of perovskites in the (Mg, Fe)(3)Al2Si3O12 system to 177 GPa

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The impacts of halide and nonhalide sources of guanidinium cations, including guanidinium chloride (GCl) ((NH2)(3)CCl) and guanidinium thiocyanate (GTC) ((NH2)(3)CSCN), are comparatively analyzed on the structural, morphological, and photophysical properti ...

Perovskite derived Ni catalysts offer the remarkable benefit of regeneration after catalyst poisoning or Ni particle growth through the reversible segregation of Ni from the perovskite-type oxide host. Although this property allows for repeated catalyst re ...

Perovskite-derived Ni catalysts offer the remarkable benefit of redox stability that allows their regeneration after deactivation through poisoning or Ni particle growth. Here, the catalytic activity of LaFe0.8Ni0.2O3 towards CO2 methanation was improved b ...

The heat flux across the core-mantle boundary (Q(CMB)) is the key parameter to understand the Earth's thermal history and evolution. Mineralogical constraints of the Q(CMB) require deciphering contributions of the lattice and radiative components to the th ...

The strategy of mixing cations and halides in hybrid organic lead halide perovskites has recently been shown to be very successful in achieving high efficiency with long-term perovskite solar cell stability. In this study, the effect of photoexcitation on ...

In this work, Li-rich Li1.2Mn0.43+Mnx4+Ti0.4-xO2 (LMMxTO, 0

Identifying extant materials that act as compositional proxies for Earth is key to understanding its accretion. Copper and sulfur are both moderately volatile elements; however, they display different geochemical behavior (e.g., phase affinities). Thus, in ...

We report on the coexistence of magnetic order and disorder in the atomically disordered double perovskites Ca2FeRuO6 and CaSrFeRuO6. Powder x-ray and neutron diffraction were used to investigate the crystal structure and magnetic ordering of these oxides. ...

Dwell-time based stability conditions for a class of LPV systems with piecewise constant parameters under time-varying delay are derived using clock-dependent Lyapunov-Krasovskii functional. Sufficient synthesis conditions for clock-dependent gain-schedule ...

Vacancy-ordered double perovskites is a new branch of lead-free halide perovskites with properties promising for photovoltaic application. In this study, data about the crystal structure of 170 known A(2)BX(6) (X = I, Br, Cl, F) are collected and analyzed ...

Magnesium partitioning between metal and silicate was experimentally investigated between 34 and 138GPa, 3,500 and 5,450K using laser-heated diamond anvil cells. The 22 measurements are combined with previously published data (total of 49 measurements) to ...

Planetesimal were the first planetary objects to form in the solar system, which later grew to make the proto-planets. Most of these bodies were differentiated as a result of internal heating. Several differentiated bodies have, then, been accreted followi ...

Solute accelerated cross-slip of pyramidal < c + a > screw dislocations has recently been recognized as a crucial mechanism in enhancing the ductility of solid-solution Mg alloys. In pure Mg, cross-slip is ineffective owing to the energy difference between ...

Double perovskite oxides A(2)BB'O-6 combining 3d and 4d or 5d transition metal ions at the B and B' sites feature a variety of magnetic and magneto-electric properties. Targeting Ba2FeOsO6, we synthesized powder samples of nonstoichiometric Ba2Fe1.12Os0.88 ...

We report the possibility to simultaneously perform wide-field nitrogen-vacancy (NV) diamond magnetic microscopy and synchrotron x-ray diffraction measurements at high pressure. NV color centers are created on the culet of a diamond anvil which is integrat ...

Perovskite-type oxides have shown the ability to reversibly segregate precious metals from their structure. This reversible segregation behavior was explored for a commonly used catalyst metal, Ni, to prevent Ni sintering, which is observed on most catalys ...

The high-pressure, high-temperature behavior of iron was investigated to 140 GPa and 3500 K with in situ synchrotron X-ray diffraction. Iron samples were compressed in diamond-anvil cells and heated up with the double-sided laser-heating system installed a ...

Synthesis and equation of state of perovskites in the (Mg, Fe)(3)Al2Si3O12 system to 177 GPa

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Halide Versus Nonhalide Salts: The Effects of Guanidinium Salts on the Structural, Morphological, and Photovoltaic Performances of Perovskite Solar Cells

Segregation of Nickel/Iron Bimetallic Particles from Lanthanum Doped Strontium Titanates to Improve Sulfur Stability of Solid Oxide Fuel Cell Anodes

Increased nickel exsolution from LaFe0.8Ni0.2O3 perovskite-derived CO2 methanation catalysts through strontium doping

Blocked radiative heat transport in the hot pyrolitic lower mantle

Photoinduced Lattice Symmetry Enhancement in Mixed Hybrid Perovskites and Its Beneficial Effect on the Recombination Behavior

Mn4+-Substituted Li-Rich Li1.2Mn0.43+Mnx4+Ti0.4-xO2 Materials with High Energy Density

Investigating Earth's Formation History Through Copper and Sulfur Metal-Silicate Partitioning During Core-Mantle Differentiation

Reentrant magnetism at the borderline between long-range antiferromagnetic order and spin-glass behavior in the B-site disordered perovskite system Ca2-x SrxFeRuO6

Dwell-time based stability analysis and L-2 control of LPV systems with piecewise constant parameters and delay

The Role of Goldschmidt's Tolerance Factor in the Formation of A(2)BX(6) Double Halide Perovskites and its Optimal Range

Magnesium Partitioning Between Earth's Mantle and Core and its Potential to Drive an Early Exsolution Geodynamo

From 2D to 3D Characterization of Materials Subjected to Extreme Pressure and Temperature Conditions

Analysis of double cross-slip of pyramidal I < c plus a > screw dislocations and implications for ductility in Mg alloys

High-Temperature Ferrimagnetism with Large Coercivity and Exchange Bias in the Partially Ordered 3d/5d Hexagonal Perovskite Ba2Fe1.12Os0.88O6

Combined synchrotron x-ray diffraction and NV diamond magnetic microscopy measurements at high pressure

Structural Reversibility and Nickel Particle stability in Lanthanum Iron Nickel Perovskite-Type Catalysts

A New Reference for the Thermal Equation of State of Iron