Conversion of cyclosporine A prodrugs in human tears vs rabbits tears

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Aromatic amines are aquatic contaminants for which phototransformation in surface waters can be induced by excited triplet states of dissolved organic matter ((DOM)-D-3*). The first reaction step is assumed to consist of a one-electron oxidation process of ...

The abatement of organic micropollutants during oxidation processes has become an emerging issue for various urban water systems such as drinking water, wastewater, and water reuse. Reaction kinetics and mechanisms play an important role in terms of effici ...

We explore the relation between the quantum and semiclassical instanton approximations for the reaction rate constant. From the quantum instanton expression, we analyze the contributions to the rate constant in terms of minimum-action paths and find that t ...

H-ZSM-5 zeolite has been shown to be an active catalyst for the synthesis of polyoxymethylene dimethyl ethers (OME). However, we demonstrated – by passivation of the zeolite's external surface – that the reaction rate is limited due to severe internal diff ...

Analysis of the dynamic and steady-state properties of biochemical networks hinges on information about the parameters of enzyme kinetics. The lack of experimental data characterizing enzyme activities and kinetics along with the associated uncertainties i ...

Cascade catalytic processes perform multi-step chemical transformations without isolating the intermediates. Here, we demonstrate a sequential cascade pathway to convert CO2 to C2+ hydrocarbons and oxygenates in a two-step electrocatalytic process using CO ...

This work presents a kinetic analysis of the exogenous photo-induced disinfection of E. coli in natural waters. Herein, the inactivation of bacteria by light and photo-generated transient species, i.e., hydroxyl radical (HO center dot), excited triplet sta ...

Marine emissions of dimethyl sulfide (DMS) to the atmosphere play a fundamental role in the global sulfur (5) cycle and have important consequences for the Earth's radiative balance. In the ocean, DMS is mainly produced by marine algae and bacteria via cle ...

The aim of this thesis is to contribute to the development of analysis methods that enable an improved investigation of the CO2 hydrogenation reaction such as quantitative mass spectrometry and infrared thermography. Furthermore, the contribution is in the ...

Conversion of cyclosporine A prodrugs in human tears vs rabbits tears

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Laser flash photolysis study of the photoinduced oxidation of 4-(dimethylamino)benzonitrile (DMABN)

Micropollutant Oxidation Studied by Quantum Chemical Computations: Methodology and Applications to Thermodynamics, Kinetics, and Reaction Mechanisms

Semiclassical analysis of the quantum instanton approximation

Prominent role of mesopore surface area and external acid sites for the synthesis of polyoxymethylene dimethyl ethers (OME) on a hierarchical H-ZSM-5 zeolite

Control Theory Concepts for Modeling Uncertainty in Enzyme Kinetics of Biochemical Networks

Sequential Cascade Electrocatalytic Conversion of Carbon Dioxide to C-C Coupled Products

Kinetic modeling of lag times during photo-induced inactivation of E. coli in sunlit surface waters: Unraveling the pathways of exogenous action

Hypobromous Acid as an Unaccounted Sink for Marine Dimethyl Sulfide?

Investigation of the heterogeneously catalysed gas phase CO2 hydrogenation reaction: Development of analysis methods and reaction analysis on pristine metal catalysts