Publications associées à Lamellar carbon-aluminosilicate nanocomposites with macroscopic orientation

Continuous Supercritical Water Impregnation Method for the Preparation of Metal Oxide on Activated Carbon Composite Materials

Metal oxide (MexOy) nanomaterials are used as catalysts and/or sorbents in processes taking place in supercritical water (scH2O), which is the “green” solvent needed to obtain energy-relevant products. Their properties are significantly influenced by the s ...

2024

Design and Synthesis of Bio-based Amphiphiles from Lignocellulosic Biomass

Songlan Sun

In the pursuit of a carbon-neutral chemical industry, minimizing fossil feedstock consumption while integrating renewable carbon sources is imperative. Surfactants, inherently amphiphilic, pose challenges in separation and recovery processes. Given their e ...

EPFL2024

Understanding the role of surface oxygen-containing functional groups on carbon-supported cobalt catalysts for the oxygen evolution reaction

Thi Ha My Pham, Andreas Züttel, Youngdon Ko, Kangning Zhao, Liping Zhong, Manhui Wei

Supported Co-based catalysts exhibit promising catalytic activities in the oxygen evolution reaction (OER) during alkaline water electrolysis. Surface functionalization of the support modulates the dispersion of the catalysts and their interaction with the ...

Royal Society of Chemistry2023

Metabolic Performance and Fate of Electrons during Nitrate-Reducing Fe(II) Oxidation by the Autotrophic Enrichment Culture KS Grown at Different Initial Fe/N Ratios

Natalia Jakus

Autotrophic nitrate-reducing Fe(II)-oxidizing (NRFeOx) microorganisms fix CO2 and oxidize Fe(II) coupled to denitrification, influencing carbon, iron, and nitrogen cycles in pH-neutral, anoxic environments. However, the distribution of electrons from Fe(II ...

AMER SOC MICROBIOLOGY2023

Two-dimensional atomically bridged nanoporous silicate-based membranes for gas separation

Mostapha Dakhchoune

The synthesis of molecular-sieving two-dimensional zeolitic membranes by the assembly of crystalline building blocks without resorting to the secondary growth process is highly desirable. The precise pore size for molecular sieving, ultrathin thickness, an ...

EPFL2021

Stabilizing Unusual Oxidation States of Lanthanides in Molecular Complexes: Synthesis, Properties, and Reactivity

Aurélien René Willauer

The chemistry of divalent lanthanides has generated increasing interest in the past years due to their redox properties and unique reaction pathways. Notably, molecular complexes of low-valent lanthanides have been shown to be suitable one-electron reducta ...

EPFL2022

Tandem electrocatalytic CO2 reduction with Fe-porphyrins and Cu nanocubes enhances ethylene production

Raffaella Buonsanti, Anna Loiudice, Min Wang

Copper-based tandem schemes have emerged as promising strategies to promote the formation of multi-carbon products in the electrocatalytic CO2 reduction reaction. In such approaches, the CO-generating component of the tandem catalyst increases the local co ...

ROYAL SOC CHEMISTRY2022

Multiscale microshaping of functionally graded polymer-derived SiCN ceramics

Lorenz Hagelüken

Polymer-derived ceramics (PDCs) exhibit excellent properties and are compatible with many shaping techniques due to the liquid character of the preceramic polymers (PCPs). Furthermore, their properties are adjustable by modifying the precursor composition ...

EPFL2022

Substantial decrease in CO2 emissions from Chinese inland waters due to global change

Tom Ian Battin

Carbon dioxide (CO2) evasion from inland waters is an important component of the global carbon cycle. However, it remains unknown how global change affects CO2 emissions over longer time scales. Here, we present seasonal and annual fluxes of CO2 emissions ...

Nature Research2021

Global carbon dioxide efflux from rivers enhanced by high nocturnal emissions

Tom Ian Battin, Hannes Markus Peter, Asa Lovisa Viktoria Horgby, Luis Gómez Gener

Carbon dioxide (CO2) emissions to the atmosphere from running waters are estimated to be four times greater than the total carbon (C) flux to the oceans. However, these fluxes remain poorly constrained because of substantial spatial and temporal variabilit ...

2021

Carbon fluxes and productivity regimes in Alpine streams

Marta Boix Canadell

High-altitude catchments have a major role in the transport of organic matter to streams due to the storage of dissolved organic carbon (DOC) in soils and glacier ice and the subsequent mobilization during the melting processes. Yet, stream function goes b ...

EPFL2020

Comparison of high density and nitrogen seeded detachment using SOLPS-ITER simulations of the tokamak a configuration variable

Basil Duval, Holger Reimerdes, Christian Gabriel Theiler, Hugo De Oliveira, Kevin Henricus Annemarie Verhaegh, Mirko Wensing, Lorenzo Martinelli

First of a kind SOLPS-ITER simulations on tokamak a configuration variable (TCV) that include nitrogen have been performed to model recent nitrogen seeded detachment experiments. Based on spectroscopic measurements, a nitrogen recycling coefficient R-p(N) ...

2020

Amoebocytes facilitate efficient carbon and nitrogen assimilation in the Cassiopea -Symbiodiniaceae symbiosis

Anders Meibom, Stéphane Laurent Escrig, Louise Helene Soegaard Jensen, Sandrine Denise Françoise Bessette, Niclas Heidelberg Lyndby, Nils Rädecker, Michael Kühl

The upside-down jellyfish Cassiopea engages in symbiosis with photosynthetic microalgae that facilitate uptake and recycling of inorganic nutrients. By con- trast to most other symbiotic cnidarians, algal endosymbionts in Cassiopea are not restricted to th ...

2020

Assessing the responses of Sphagnum micro-eukaryotes to climate changes using high throughput sequencing

Alexandre Buttler, Enrique Lara, Edward Mitchell, Mariusz Lamentowicz, Vincent Eric Jules Jassey

Current projections suggest that climate warming will be accompanied by more frequent and severe drought events. Peatlands store ca. one third of the world's soil organic carbon. Warming and drought may cause peatlands to become carbon sources through stim ...

PEERJ INC2020

Hydrothermally Stable Sulfonated Carbons as Solid Acid Catalysts for the Hydrolysis of Lignocellulose

David Ferdinand Scholz

The recycling of homogeneous acids imposes great challenges to the feasibility of lignocellulose hydrolysis processes. Although heterogeneous catalysts would offer a perspective to circumvent these challenges, conventional solid acids are instable under th ...

EPFL2019

DORI Reveals the Influence of Noncovalent Interactions on Covalent Bonding Patterns in Molecular Crystals Under Pressure

Laurent Alexis Clément Vannay, Anne-Clémence Corminboeuf, Berend Smit, Senja Dominique Barthel, Amber Kashan Mace, Benjamin André René Meyer

The study of organic molecular crystals under high pressure provides fundamental insight into crystal packing distortions and reveals mechanisms of phase transitions and the crystallization of polymorphs. These solid-state transformations can be monitored ...

2019

Data-driven design of metal-organic frameworks for wet flue gas CO2 capture

Seyedmohamad Moosavi, Berend Smit, Kyriakos Stylianou, Peter George Boyd, Andrzej Gladysiak, Christopher Patrick Ireland, Arunraj Chidambaram, Pascal Alexander Schouwink, Enrique Garcia Diez, Susana Garcia Lopez

Limiting the increase of CO2 in the atmosphere is one of the largest challenges of our generation(1). Because carbon capture and storage is one of the few viable technologies that can mitigate current CO2 emissions(2), much effort is focused on developing ...

2019

Experimental evidence reveals impact of drought periods on dissolved organic matter quality and ecosystem metabolism in subalpine streams

Tom Ian Battin

Subalpine streams are predicted to experience lower summer discharge following climate change and water extractions. In this study, we aimed to understand how drought periods impact dissolved organic matter (DOM) processing and ecosystem metabolism of suba ...

American Society of Limnology and Oceanography2019

Composite Materials Based on (Cymene)Ru(II) Curcumin Additives Loaded on Porous Carbon Adsorbents from Agricultural Residues Display Efficient Antibacterial Activity

Paul Joseph Dyson

Alternative composite materials with antibacterial activity have been developed by combining the porosity of carbon materials and the antibacterial activity of half sandwich (cymene)Ru-curcumin complexes. Different types of activated carbon were used, from ...

2018

Tritium retention characteristics in dust particles in JET with ITER-like wall

Patrick Blanchard, Basil Duval, Ambrogio Fasoli, Yves Martin, Richard Pitts, Olivier Sauter, Henri Weisen, Robin Humphry-Baker, Stefano Coda, Martinus Gijs, Partha Dutta, Marco Wischmeier, Jan Horacek, Vlad Trifa, Yann Camenen, Jonathan Graves, Duccio Testa, Miguel Fernández Ruiz, Sun Hee Kim, Mikhail Maslov, Javier García Hernández, David Pfefferlé, José Pedro Rebelo Ferreira Marques, Julio Rodriguez, Pedro Camilo de Oliveira e Silva, Rebecca Hill, Daniel Scott Alessi, Jonnathan Cesar Hidalgo Acosta, Ana Francisca Leal Silva Soares, Dalziel Joseph Wilson, Pierre-Thomas Paul Brun, Jonathan Marc Philippe Faustin, Federico Nespoli, Alberto Hernando de Castro, Hamish William Patten, Bruno Emanuel Ferreira De Sousa Correia, Li Shuai, Nicola Vianello, Antonio José Pereira de Figueiredo, , , , , , , , ,