Publications associées à Coordination Chemistry as a Universal Strategy for a Controlled Perovskite Crystallization

Publications associées (22)

Making from Breaking: Degradation Inversion Enables Vapor-Phase Synthesis of Halide Perovskites in Ambient Conditions

Christophe Ballif, Aïcha Hessler-Wyser, Christian Michael Wolff, Kerem Artuk, Mostafa Rabie Shlaly Bahr Othman, Austin George Kuba

Vapor phase deposition of formamidinium-rich perovskites is hampered by the decomposition of formamidine in the vapor phase. We use the reversibility of this reaction to establish a dynamic equilibrium that enables the vapor-phase synthesis of formamidiniu ...

American Chemical Society (ACS)2025

Solar photons beyond the band gap wavelengths: their effect on solution-processed solar cells

Michael Graetzel

A deep understanding of how solution-processed solar cells (SSCs) perform under varying temperatures and irradiance is crucial for their optimal design, synthesis, and use. However, current partial spectral characterization, primarily below the band gap wa ...

Royal Society of Chemistry2025

High-Efficiency Carbon Perovskite Solar Cells via Cathode Interface Engineering by using CuPc Hole-Transporting Layers

Mohammad Khaja Nazeeruddin

Carbon perovskite solar cells (C-PSCs) represent a promising photovoltaic (PV) technology that addresses the long-term operating stability needed to compete with commercial Si solar cells. However, the poor interface contacts between the carbon electrode a ...

2025

Localized Tunneling 1D Perovskitoid Passivated Contacts for Efficient and Stable Perovskite Solar Modules

Mohammad Khaja Nazeeruddin, Yong Ding, Kai Zhang

Interface engineering has proven to be an effective approach for passivating interfacial imperfections to mitigate non-radiative recombination, but the subpar interface quality between the perovskite and the charge transport layer has hindered advancements ...

2025

Towards Quantitative Terahertz Characterisation of Zinc Phosphide Thin Films for Photovoltaic Applications

Anna Fontcuberta i Morral, Jean-Baptiste Leran, Simon Robert Escobar Steinvall, Elias Zsolt Stutz, Rajrupa Paul, Mirjana Dimitrievska, Léa Buswell

The earth-abundant and non-toxic material Zinc phosphide (Zn3P2) is a promising candidate for solar cell applications. However, growth of defect-free, high-quality thin films on substrates that can integrate with current technology (e.g. silicon) remains c ...

IEEE Computer Society2024

Triarylamine Trisamide Interfacial Modulation for Perovskite Photovoltaics

Runzhong Zhang, Michael Graetzel, Shaik Mohammed Zakeeruddin, Felix Thomas Eickemeyer, Ghewa Alsabeh

Hybrid perovskites stand out as one of the leading materials in the new generation of photovoltaics. Their stability under operating conditions, however, remains an ongoing challenge. In particular, aging at the interface with the charge transport material ...

Wiley2024

Assessing the Influence of Illumination on Ion Conductivity in Perovskite Solar Cells

Christophe Ballif, Aïcha Hessler-Wyser, Christian Michael Wolff, Mostafa Rabie Shlaly Bahr Othman

Whether illumination influences the ion conductivity in lead-halide perovskite solar cells containing iodide halides has been an ongoing debate. Experiments to elucidate the presence of a photoconductive effect require special devices or measurement techni ...

2024

Mobility Gaps of Hydrogenated Amorphous Silicon Related to Hydrogen Concentration and Its Influence on Electrical Performance

Nicolas Würsch, Jonathan Emanuel Thomet, Sylvain Dunand

This paper presents a comprehensive study of hydrogenated amorphous silicon (a-Si)-based detectors, utilizing electrical characterization, Raman spectroscopy, photoemission, and inverse photoemission techniques. The unique properties of a-Si have sparked i ...

2024

Influence of F-Containing Materials on Perovskite Solar Cells

Likai Zheng

Perovskite solar cells (PSCs) are usually modified and passivated to improve their performance and stability. The interface modification and bulk doping are the two basic strategies. Fluorine (F)-containing materials are highly favored because of their uni ...

2024

Poly(3-hexylthiophene)/perovskite Heterointerface by Spinodal Decomposition Enabling Efficient and Stable Perovskite Solar Cells

Mohammad Khaja Nazeeruddin

The best research-cell efficiency of perovskite solar cells (PSCs) is comparable with that of mature silicon solar cells (SSCs); However, the industrial development of PSCs lags far behind SSCs. PSC is a multiphase and multicomponent system, whose conseque ...

Wiley-V C H Verlag Gmbh2023

22.8% full-area bifacial n-PERT solar cells with rear side sputtered poly-Si (n) passivating contact

Christophe Ballif, Sylvain Nicolay, Andrea Ingenito, Bertrand Yves Paul Paviet-Salomon, Sofia Libraro

High-temperature compatible passivating contacts based on phosphorus doped polysilicon (poly-Si(n)) on a thin silicon oxide, employed on the rear side of bifacial n-PERT like solar cells provide an efficiency increase while being compatible with current ph ...

ELSEVIER2023

Rear textured p-type high temperature passivating contacts and their implementation in perovskite/silicon tandem cells

Christophe Ballif, Sylvain Nicolay, Quentin Thomas Jeangros, Antoine Descoeudres, Soo-Jin Moon, Andrea Ingenito, Philippe Wyss, Arnaud Walter

Silicon solar cells based on high temperature passivating contacts are becoming mainstream in the photovoltaic industry. Here, we developed a high-quality boron-doped poly-silicon hole contact. When combined with a co-processed phosphorus-doped poly-silico ...

Royal Soc Chemistry2023

Simulation and experimental characterization of VC precipitation and recovery stress formation in an FeMnSi-based shape memory alloy

Christian Leinenbach

In this study, TC-PRISMA was employed to simulate the precipitation (number density and radius) of an FeMnSi-based shape memory alloy (FeMnSi-SMA), with a chemical composition of Fe-17Mn-5Si-10Cr-4Ni-1(V, C) (wt%), during one-step and two-step aging proces ...

2023

How roughness emerges on natural and engineered surfaces

Jean-François Molinari, Ramin Aghababaei

Roughness, defined as unevenness of material surfaces, plays an important role in determining how engineering components or natural objects interact with other bodies and their environment. The emergence of fractal roughness on natural and engineered surfa ...

SPRINGER HEIDELBERG2023

Long-term performance and reliability of silicon heterojunction solar modules

Christophe Ballif, Alessandro Francesco Aldo Virtuani, Olatz Arriaga Arruti

The high-efficiency silicon heterojunction (SHJ) technology is now perceived mature enough to enter the Giga-Watt manufacturing scale with several players around the globe. The growth of the SHJ technology requires confidence from manufacturers, investors, ...

2023

Buried Interface Engineering Enables Efficient and 1,960-hour Isos-L-2i Stable Inverted Perovskite Solar Cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, Felix Thomas Eickemeyer, Xiong Li, Mathias Dankl, Mingyang Wei, Virginia Carnevali, Nikolaos Lempesis, Lorenzo Agosta

High-performance perovskite solar cells (PSCs) typically require interfacial passivation, yet this is challenging for the buried interface, owing to the dissolution of passivation agents during the deposition of perovskites. Here, we overcome this limitati ...

Zenodo2023

Perovskite Solar Cells with Carbon-Based Electrodes - Quantification of Losses and Strategies to Overcome Them

Ulf Anders Hagfeldt, Bowen Yang, Jiajia Suo

Carbon-based electrodes represent a promising approach to improve stability and up-scalability of perovskite photovoltaics. The temperature at which these contacts are processed defines the absorber grain size of the perovskite solar cell: in cells with lo ...

WILEY-V C H VERLAG GMBH2022

Corrosion testing of solar cells: Wear-out degradation behavior

Christophe Ballif, Alessandro Francesco Aldo Virtuani, Andrew Wayne Fairbrother, Luca Gnocchi

Corrosion is one of the main end-of-life degradation and failure modes in photovoltaic (PV) modules. However, it is a gradual process and can take many years to become a major risk factor because of the slow accumulation of water and acetic acid (from enca ...

ELSEVIER2022

Composition and Interface Engineering of High Performing Perovskite Solar Cells

Mousa Abdulla M E Abuhelaiqa

Perovskite solar cells have been established as a disruptive technology in the domain of photo-voltaics. Their facile, low-temperature processing and high-power conversion efficiency make them stand-out among other mature solar technologies. The performanc ...

EPFL2022

Employing 2D-Perovskite as an Electron Blocking Layer in Highly Efficient (18.5%) Perovskite Solar Cells with Printable Low Temperature Carbon Electrode

Mohammad Khaja Nazeeruddin, Hiroyuki Kanda, Hobeom Kim, So-Min Yoo, Jaekeun Lim

Interface engineering and passivating contacts are key enablers to reach the highest efficiencies in photovoltaic devices. While printed carbon-graphite back electrodes for hole-transporting material (HTM)-free perovskite solar cells (PSCs) are appealing f ...

WILEY-V C H VERLAG GMBH2022