Publications associées à Subsolidus phase equilibria in the PbO-poor part of the TiO2–PbO–SiO2 system and its application in low-temperature thick-film dielectrics

Publications associées (35)

Hydrogen-induced tunable remanent polarization in a perovskite nickelate

Materials with field-tunable polarization are of broad interest to condensed matter sciences and solid-state device technologies. Here, using hydrogen (H) donor doping, we modify the room temperature metallic phase of a perovskite nickelate NdNiO3 into an ...

Nature Portfolio2024

Control of intermetallics in the interface in directed energy deposition of titanium on stainless steel 316L

Di Cui

Application of a single metal or alloy is often restricted by its properties from optimal combination of performance and cost. Therefore, there is a vast need of joining dissimilar metals for various applications in biomedical, aerospace, automobile and ma ...

EPFL2023

Evaluation of the role of superoxide radical as chain carrier for the formation of hydroxyl radical during ozonation

Urs von Gunten, Gang Yu

Superoxide radicals (O-2(center dot-)) have been suggested as an important chain carrier in the radical chain reaction that promotes ozone (O-3) decomposition to hydroxyl radicals ((OH)-O-center dot) during ozonation. However, due to the difficulty in meas ...

PERGAMON-ELSEVIER SCIENCE LTD2023

Assessing the value of kinetic results from biochemical methane potential tests: Reproducibility from a large inter-laboratory study

Christof Holliger

Kinetic information extracted from biochemical methane potential (BMP) tests is often reported but its value is unclear. Inter-laboratory reproducibility provides a useful indication of its value. Here we extracted estimates of the first-order rate constan ...

2022

Operando XAS insight in the redox dynamics of VOx species and reducible supports involved in oxidative dehydrogenation of alcohols

Anna Zabilska

Supported vanadia (VOx) belongs to some of the most versatile selective oxidation and reduction catalysts applied for many reactions in the chemical industry and pollution control. Among them, the oxidative dehydrogenation (ODH) of alcohols is particularly ...

EPFL2022

OSCAR: an extensive repository of chemically and functionally diverse organocatalysts

Anne-Clémence Corminboeuf, Alberto Fabrizio, Rubén Laplaza Solanas, Sergio Vela Llausi, Simone Gallarati, Puck Elisabeth van Gerwen

The automated construction of datasets has become increasingly relevant in computational chemistry. While transition-metal catalysis has greatly benefitted from bottom-up or top-down strategies for the curation of organometallic complexes libraries, the fi ...

ROYAL SOC CHEMISTRY2022

van der Waals Epitaxy of Co10–xZn10–yMnx+y Thin Films: Chemical Composition Engineering and Magnetic Properties

Anna Fontcuberta i Morral, Dirk Grundler, Jean-Baptiste Leran, Simon Robert Escobar Steinvall, Rajrupa Paul, Ping Che, Mohammad Hamdi, Andrea Mucchietto

Topologically protected magnetic skyrmions have raised interest for future spintronics applications. One of the main challenges is the synthesis of room temperature skyrmion-hosting materials that are compatible with thin-film technology. We present an app ...

2021

A universal signature in the melting of metallic nanoparticles

Kevin Rossi

Predicting when phase changes occur in nanoparticles is fundamental for designing the next generation of devices suitable for catalysis, biomedicine, optics, chemical sensing and electronic circuits. The estimate of the temperature at which metallic nanopa ...

ROYAL SOC CHEMISTRY2021

Thermal coarsening of individual titanate nanowires and their assemblies: Surface vs. bulk diffusion

László Forró, Luca Rossi, Endre Horvath, Massimo Spina, Sergiy Katrych, Laurent Syavoch Bernard, Lidia Rocoffort de Vinnière

The thermal coarsening of titanate nanowires was investigated from room temperature to 1000 degrees C by AFM, SEM, XRD and Raman spectroscopy. Phase transformation kinetics and the external morphology were studied in two configurations: i) as individual an ...

2020

Radio-Frequency Characteristics of Ge-doped Vanadium Dioxide Thin Films with Increased Transition Temperature

Mihai Adrian Ionescu, Andreas Schueler, Igor Stolichnov, Anna Krammer, Riyaz Mohammed Abdul Khadar, Matteo Cavalieri, Andrei Müller, Teodor Rosca, Fatemeh Qaderi Rahaqi

This work investigates and reports on the radio-frequency (RF) behavior in the frequency range of 5 – 35 GHz of germanium-doped (Ge-doped VO2) vanadium dioxide thin films, deposited on silicon substrates via sputtering and pulsed laser deposition (PLD) wit ...

2020

Heterogeneous catalyst preparation by liquid-phase atomic layer deposition

Benjamin Pierre Le Monnier

Heterogeneous catalyst preparation has been performed for close to a century but has been rapidly evolving spurred by the evolution in synthetic techniques and growing needs in energy, chemicals and materials. An increasing number of catalyst synthesis str ...

EPFL2020

Mechanisms of the Heterogeneously Catalyzed Reaction of CO2 Hydrogenation on Transition Metal Surfaces

Kun Zhao

Renewable energy supply and energy storage in a closed materials cycle are the urgent global challenges of the 21st century. Carbon dioxide (CO2) hydrogenation over catalysts is a method to produce synthetic fuels from renewable energy in a CO2 neutral cyc ...

EPFL2020

Synthesis of heterogeneous catalysts with metal oxide overcoat for renewable catalysis applications

Yuan-Peng Du

Metal oxide deposition is an emerging synthetic technique for designing heterogeneous catalysts. Depositing a nanoscale overcoat of metal oxide on heterogeneous catalysts can modify their structural and chemical characteristics. Many deposition approaches, ...

EPFL2020

Actuation of piezoelectric structures with ferroelectric thin films having multiple elements

Paul Muralt

A method for driving piezoelectric elements of a micro-system. The piezoelectric elements comprising a ferroelectric thin film, and being configured to be part of any one or a combination of items of a list comprising: a cantilever, a bridge, a diaphragm, ...

2020

Development of a new family of phosphorous-free Pt-based bulk metallic glasses

Ludger Weber, Maïté Blank, Hamed Kazemi, Cyrill Werner Cattin

New BMGs exhibiting strong glass forming ability combined with high hardness have been developed based on the Pt-Si-B ternary system. The effects of partial substitution of platinum by transition metals of the group iron, cobalt, nickel, and copper, as wel ...

Elsevier2017

Synthetic Calcium Silicate Hydrates

Abhishek Kumar

Since the introduction of cementitious materials over 200 years ago, its use has multiplied many fold to be currently at 3 billion tonnes per year, accounting for about 8% of worldwide carbon emission which is forecast to double within the next 30 years. U ...

EPFL2017

Cell-free soil bio-cementation with strength, dilatancy and fabric characterization

Lyesse Laloui, Dimitrios Terzis

A multi-disciplinary approach is adopted in the present work towards investigating bio-cemented geo-materials which extends from sample preparation, to microstructural inspection and mechanical behaviour characterization. We suggest a new way to induce “ce ...

2019

Transition metal clusters on h-BN/Rh(111) : surface interaction and catalytic activity

Hamed Achour

The main aim of this dissertation is to study the catalytic aspects of very small transition metal clusters supported on h-BN/Rh(111). The catalytic reactions of interest were ammonia synthesis and CO oxidation on mass selected and soft landed iron and pla ...

EPFL2017

Gas-Phase Ozone Reactions with a Structurally Diverse Set of Molecules: Barrier Heights and Reaction Energies Evaluated by Coupled Cluster and Density Functional Theory Calculations

Jeremy Samuel Arey, Peter Rudolf Tentscher, Daniela Trogolo

Reactions with ozone transform organic and inorganic molecules in water treatment systems as well as in atmospheric chemistry, either in the aqueous phase, at gas/particle interfaces, or in the gas phase. Computed thermokinetic data can be used to estimate ...

AMER CHEMICAL SOC2019

Antiferroelectric antiferromagnetic type-I multiferroic Cu9O2(SeO3)(4)Cl-6

Helmuth Berger

We report that Cu9O2(SeO3)(4)Cl-6 is a new multiferroic compound. Comprehensive studies of this compound have been carried out on single crystals as well as polycrystalline samples. Magnetic susceptibility chi and specific heat C with H parallel to c axis ...

AMER PHYSICAL SOC2019