Publications associées à Synergistic Integration of a Ru(bda)-Based Catalyst in a Covalent Organic Framework for Enhanced Photocatalytic Water Oxidation

Publications associées (19)

Decoration of ZnO Nanorod Arrays with Heterojunction of Graphene Quantum Dots and MoS2 Nanoparticles for Photoelectrochemical Water Splitting

Conversion of sunlight to a chemical fuel through photoelectrochemical (PEC) water splitting is deemed to be a promising solution to satisfy future energy needs. In this study, a photoanode based on the triple heterojunction of MoS2/graphene quantum dots/Z ...

2025

Ternary Oxides of s - and p -Block Metals for Photocatalytic Solar-to-Hydrogen Conversion

Iurii Timrov

Oxides containing metals or metalloids from the p block of the periodic table (e.g., In, Sn, Sb, Pb, and Bi) are of technological interest as transparent conductors and light absorbers for solar-energy conversion due to the tunability of their electronic c ...

2024

Boosting solar fuel production of bismuth ferrite thin film by incorporating reduced graphene oxide

Mohammadreza Golobostanfard

In this study, a facile chemical approach was utilized to successfully fabricate a porous bismuth ferrite (BiFeO3, BFO)/reduced graphene oxide (rGO) nanocomposite thin film as a photoanode for photoelec-trochemical (PEC) water splitting. The BFO nanopartic ...

2023

Techno-economic analysis of solar hydrogen production via PV power/concentrated solar heat driven solid oxide electrolysis with electrical/thermal energy storage

Jan Van Herle

Green hydrogen production via electrochemical water splitting is a promising approach for future sustainable energy and industry. Among the existing water electrolysis technologies, solid oxide steam electrolysis exhibits the highest electrical efficiency, ...

ELSEVIER2023

In situ construction of graphdiyne based heterojunctions by a deprotection-free approach for photocatalytic hydrogen generation

Cong Wang, Jian Li

Graphdiyne (GDY) with a direct bandgap, high charge carrier mobility, and ordered pore structure, is considered an excellent matrix for the construction of heterojunction photocatalysts. However, the traditional fabrication methods for GDY-based heterojunc ...

Royal Society of Chemistry2023

Robust Piperidinium-Enriched Polystyrene Ionomers for Anion Exchange Membrane Fuel Cells and Water Electrolyzers

Xile Hu, Fang Song, Nanjun Chen

Durable and efficient anion exchange polyelectrolytes (AEPs) are crucial for the long-term operation of cost-effective anion exchange membrane fuel cells (AEMFCs) and water electrolyzers (AEMWEs). Here, we present a new class of ?-amine-piperidinium-functi ...

AMER CHEMICAL SOC2023

An Organic Semiconductor Photoelectrochemical Tandem Cell for Solar Water Splitting

Kevin Sivula, Jun Ho Yum, Mounir Driss Mensi, Han-Hee Cho, Dan Zhang

Photoelectrochemical cells employing organic semiconductors (OS) are promising for solar-to-fuel conversion via water splitting. However, despite encouraging advances with the half reactions, complete overall water splitting remains a challenge. Herein, a ...

WILEY-V C H VERLAG GMBH2022

Construction of Fe3O4 bridged Pt/g-C3N4 heterostructure with enhanced solar to fuel conversion

Michael Graetzel, Shaik Mohammed Zakeeruddin

In this study, we report the effects of co-catalysts of Pt nanoparticles and Fe3O4 clusters on photocatalytic behaviors of g-C3N4 (CN) and the use of the resulting photocatalyst for CO2 photoreduction to solar fuels in a flow reactor operated at room-tempe ...

ELSEVIER2022

Electrochemically CO2 conversion using homogeneous and nanostructured heterogeneous Ru (II) electrocatalysts

Farzaneh Fadaei Tirani

The reduction of carbon dioxide to desirable products is an urgent goal in favour of the environment, the energy-cycle and mankind. We report the electrochemical reduction of CO2 to carbon monoxide by means of the ho-mogeneous electrocatalyst (1), [Ru(bpy) ...

ELSEVIER SCI LTD2022

Integrated production of urea and nitric acid in the pulp industry: techno-economic and environmental analysis of black liquor gasification-based processes

François Maréchal, Daniel Alexander Florez Orrego, Shivom Sharma, Meire Ellen Gorete Ribeiro Domingos

The pursuit of alternative energy sources for the nitrogen fertilizers sector has recently earned renewed interest due to increasing concerns regarding the world dependence on non-renewable energy resources and also motivated by the more stringent environm ...

2022

Computational studies for the description of electronic and optical properties for photocatalysis in Metal Organic Frameworks

Andres Adolfo Ortega Guerrero

Metal-organic frameworks(MOFs) are promising materials for photocatalytic applications. MOFs modular and porosity structure provides a platform to assemble photo-active and catalytic-sites building block units that can offer unique photo-physics. This feat ...

EPFL2021

Spray Synthesis of CuFeO2 Photocathodes and In-Operando Assessment of Charge Carrier Recombination

Kevin Sivula, Nestor Guijarro Carratala, Florian Le Formal, Yongpeng Liu, Florent Alexandre Boudoire, Charles Roger Jean Lhermitte

Semiconducting delafossite-phase CuFeO2 is a promising photocathode material for solar-driven hydrogen production given its suitable energy levels and established robustness for photoelectrochemical water reduction. Nevertheless, reported methods for prepa ...

AMER CHEMICAL SOC2021

Techno-economic evaluation of biomass-to-fuels with solid-oxide electrolyzer

François Maréchal, Jan Van Herle, Ligang Wang

Thermochemical biomass-to-fuel conversion requires an increased hydrogen concentration in the syngas derived from gasification, which is currently achieved by water–gas-shift reaction and CO2 removal. State-of-the-art biomass-to-fuels convert less than hal ...

2020

Techno-economic optimization of biomass-to-methanol with solid-oxide electrolyzer

François Maréchal, Jan Van Herle, Ligang Wang, Maria del Mar Perez Fortes

The purpose of this paper is to assess techno-economically the integration of solid-oxide electrolysis in biomass-to-methanol processes: (1) The hydrogen produced by electrolysis can be used to adjust the composition of syngas from gasification to increase ...

ELSEVIER SCI LTD2020

Effects of Se Incorporation in La5Ti2CuS5O7 by Annealing on Physical Properties and Photocatalytic H-2 Evolution Activity

Takashi Hisatomi, Swarnava Nandy

Oxysulfoselenide semiconductor photocatalysts absorb light at longer wavelengths than the corresponding oxysulfides. However, the synthesis of oxysulfoselenides is challenging due to excessive particle growth and the limited availability of metal selenide ...

AMER CHEMICAL SOC2019

Piezoelectric materials for catalytic/photocatalytic removal of pollutants: Recent advances and outlook

Sami Rtimi

The accumulation of various contaminants in air, soil and water is threatening the natural environment. The remediation of the environmental contaminations is today an urge. Among the remediation methods employed, advanced oxidation processes (AOPs) are a ...

ELSEVIER SCIENCE BV2019

Insights into the interfacial carrier behaviour of copper ferrite ( CuFe2O4) photoanodes for solar water oxidation

Kevin Sivula, Liang Yao, Nestor Guijarro Carratala, Florian Le Formal, Yongpeng Liu, Florent Alexandre Boudoire

Designing efficient yet robust photoanodes for water oxidation stands out as a major bottleneck in the realization of a feasible photoelectrochemical tandem cell for solar water splitting. Spinel copper ferrite (CuFe2O4) has been recently reported as a pot ...

Royal Society of Chemistry2019

Integrating urban form and distributed energy systems: Assessment of sustainable development scenarios for a Swiss village to 2050

Jean-Louis Scartezzini, Silvia Coccolo, Amarasinghage Tharindu Dasun Perera, Nahid Mohajeri Pour Rayeni, Lucas Mosca

The integration of renewable energy in the built environment, improving the energy efficiency of buildings, and optimizing distributed energy systems are three interconnected activities that are central for the transition to sustainable cities. Here, a met ...

Pergamon-Elsevier Science Ltd2019

Porous NiTiO3/TiO2 nanostructures for photocatatalytic hydrogen evolution

Kevin Sivula, Nestor Guijarro Carratala, Yongpeng Liu, Yu Zhang

We present a strategy to produce porous NiTiO3/TiO2 nanostructures with excellent photocatalytic activity toward hydrogen generation. In a first step, nickel-doped TiO2 needle bundles were synthesized by a hydrothermal procedure. Through the sintering in a ...

Royal Society of Chemistry2019