Publications associées à Effect of different ions on dissolution rates of silica and feldspars at high pH

Publications associées (32)

Is there a future for 43Ca nuclear magnetic resonance in cement science?

Calcium and silicon are critical components of cement. While 29Si nuclear magnetic resonance (NMR) is widely used in cement science, 43Ca NMR has received comparatively less attention given the experimental challenges associated with it. To investigate the ...

2025

A Novel Uniaxial Penetration Approach to Investigate Sulfate Attack on Cement-Based Materials

Karen Scrivener, Qiao Wang

The sodium sulfate crystallization attack in cementitious materials is addressed in this paper. Portland cement, sulfate-resisting cement, and calcined clay limestone cement were compared by the evolution of expansion, sulfate ingress property, and suscept ...

Springer Science and Business Media B.V.2025

Optical Spatial Dispersion Via Wannier Interpolation

Stepan Tsirkin

We present a numerical implementation, based on Wannier interpolation, of a Kubo-Greenwood formalism for computing the spatially dispersive optical conductivity in crystals at first order in the wave vector of light. This approach is more efficient than di ...

AMER PHYSICAL SOC2025

Cooling rates and melt extraction timescales determined by diffusion chronometry on shallow crustal plutonic rocks

Stéphane Laurent Escrig

Diffusion chronometry has emerged as a valuable tool to track the timescales of magmatic processes and is now routinely applied on erupted volcanic products to infer crystal residence times and mixing-to-eruption timescales. Despite some attempts to apply ...

2025

43ca Freeze-quenched Mas-dnp for the Characterization of Transient Phases Involved in Nonclassical Formation of Hydroxyapatite

Tristan Axel Georges

Calcium orthophosphates, such as hydroxyapatite (HAP), have been shown to follow nonclassical nucleation and crystallization mechanisms involving intermediate species, including solute prenucleation species (PNS) that precede solid transient phases. Charac ...

AMER CHEMICAL SOC2025

Decarbonization potential of steel fibre-reinforced limestone calcined clay cement concrete one-way slabs

Hisham Tarek Mohamed Hafez, Beatrice Malchiodi

This study deals with a comparison of the environmental performance of one-way slabs utilizing steel fibrereinforced limestone calcined clay cement (LC3) concrete with the control case of Ordinary Portland cement concrete. The experimental program constitu ...

Elsevier Sci Ltd2024

Exploring High-Performance and Energy-Efficient Architectures for Edge AI-Enabled Applications

Joshua Alexander Harrison Klein

The desire and ability to place AI-enabled applications on the edge has grown significantly in recent years. However, the compute-, area-, and power-constrained nature of edge devices are stressed by the needs of the AI-enabled applications, due to a gener ...

EPFL2024

Water weakening and the compressive brittle strength of carbonates: Influence of fracture toughness and static friction

Marie Estelle Solange Violay, Corentin Jean-Marie Rémi Noël, Barnaby Padraig Fryer

Water is ubiquitous within the pore space of rocks and has been shown to affect their physical and mechanical behaviour. Indeed, water can act on the rock strength via mechanical (i.e., reducing the effective stresses) or chemical effects (e.g., mineral di ...

2024

Mesh-based topology, shape and sizing optimization of ribbed plates

Ahmad Abdulrahman Ahmad Majdouba

In this paper, we present a new parameterization and optimization procedure for minimizing the weight of ribbed plates. The primary goal is to reduce embodied CO2 in concrete floors as part of the effort to diminish the carbon footprint of the construction ...

Springer2024

Reuse of cut concrete slabs in new buildings for circular ultra-low-carbon floor designs

Corentin Jean Dominique Fivet, Numa Joy Bertola, Célia Marine Küpfer

The study explores an original idea that responds to the urgent need to reduce the detrimental environmental impacts of load-bearing floor construction in new buildings by reusing saw-cut reinforced concrete (RC) pieces salvaged from soon-to-be demolished ...

2024

FLO:RE – A new floor system made of reused reinforced concrete and steel elements

Corentin Jean Dominique Fivet, Numa Joy Bertola, Maléna Bastien Masse, Célia Marine Küpfer

Carefully extracting reinforced concrete (RC) elements from soon-to-be demolished structures and reusing them as load-bearing components is an emerging circular low-carbon alternative to building new structures. As floor construction typically accounts for ...

IABSE2024

Photo-Fenton inactivation of MS2 bacteriophage at alkaline pH by Fe salts or nm to μm-sized oxides, and the Janus-faced effects of natural organic matter in surface waters

César Pulgarin, Stefanos Giannakis

In this study, MS2 bacteriophage was inactivated by homogeneous and heterogeneous photo-Fenton processes in an alkaline matrix (pH 8) using low concentrations of H2O2 and iron forms (1 mg/L), including Fe(II), Fe(III), and Fe (hydr)oxides. As a reference, ...

Elsevier2024

Shear and steel-fibre reinforcement for the punching resistance of flat slabs at internal and edge columns

Diego Hernández Fraile

Reinforced concrete flat slabs consist of a continuous, thin concrete plate that rests on a grid of columns. The supporting surface of the columns is very small compared to the floor plan dimensions, leading to concentrations of shear forces near the colum ...

EPFL2024

Reusability assessment of reinforced concrete components prior to deconstruction from obsolete buildings

Corentin Jean Dominique Fivet, Maléna Bastien Masse, Julie Rachel Devènes

A large part of building demolitions is motivated by purely socio-economic reasons. Hence, about-to-be-demolished structures, commonly made of reinforced concrete, very often present no or little degradation. When adaptive reuse of the entire building is n ...

2024

A concrete answer for circular construction: three prototypes reusing saw-cut elements

Corentin Jean Dominique Fivet, Maléna Bastien Masse, Célia Marine Küpfer

Existing concrete buildings should be retained for as long as possible to reduce the environmental burden of demolition and new construction. However, when urban pressure makes demolition unavoidable, salvaging and reusing concrete elements elsewhere in ne ...

2024

Microstructure - Electrochemical Surface Reactivity Relationship of Electrochemically Grown Manganese Oxides Films

Roberto Cestaro

This Thesis provides a comprehensive and correlative investigation of the microstructure, chemical state, and electrochemical reactivity of manganese oxide (MnOx) films, aiming to gain a deeper understanding of the deposition and dissolution mechanism of M ...

EPFL2024

Near-Room-Temperature Detection of Aromatic Compounds with Inkjet-Printed Plasticized Polymer Composites

Jürgen Brugger, Thomas Maeder, Mohammadmahdi Kiaee

Chemiresistive gas sensors composed of a thermoplastic polymer matrix and conductive fillers offer various advantages for detecting volatile organic compounds (VOCs), including low power consumption due to near-room-temperature operation, high sensitivity, ...

Amer Chemical Soc2024

Contributions to rebar-to-concrete interaction and its structural implications for design and monitoring applications

Enrique Corres Sojo

Bond between reinforcing bars and concrete has been the focus of extensive research over the last century. This is well-justified as the functioning of reinforced concrete intimately depends on the interaction between rebar and concrete, as for example cra ...

EPFL2024

Model uncertainties in action effects and load bearing capacity calculation in statically indeterminate reinforced concrete structures

Aurelio Muttoni, Alain Nussbaumer, Xhemsi Malja

For the dimensioning and assessment of structures, it is common practice to compare action effects with sectional resistances. Extensive studies have been performed to quantify the model uncertainty on the resistance side. However, for statically indetermi ...

Ernst & Sohn2024

Contradict mechanism of long-term magnesium and sodium sulfate attacks of nano silica-modified cement mortars - Experimental and thermodynamic modeling

Qiao Wang

The mechanisms of external sulfate attack on cement mortars containing nano silica have been studied under full immersion conditions after 3 years. The sulfate degradation processes were compared between sodium sulfate and magnesium sulfate solutions with ...

Elsevier Sci Ltd2024