Publications associées à Diketopyrrolopyrole (dpp)-based sensitizers for electrochemical or optoelectronic devices

Publications associées (30)

Shortwave Infrared-Sensitive, Narrowband Organic Upconversion Devices with a Gain

Sensing and imaging of light in the shortwave infrared (SWIR) range is increasingly used in various fields, including bio-imaging, remote sensing, and semiconductor process control. SWIR-sensitive organic photodetectors (OPDs) are promising because organic ...

EPFL2024

Assessing the Charge Carrier Dynamics at Hybrid Interfaces of Organic Photoanodes for Solar Fuels

Kevin Sivula, Yongpeng Liu, Han-Hee Cho

Organic semiconductors (OSCs) have emerged as promising active layers for photoanodes to drive photoelectrochemical (PEC) oxidation reactions. Interfacing an OSC with an inorganic electron transport layer (ETL) is key to enabling both high performance and ...

Amer Chemical Soc2024

Durable Perovskite Solar Cells with 24.5% Average Efficiency: The Role of Rigid Conjugated Core in Molecular Semiconductors

Michael Graetzel, Shaik Mohammed Zakeeruddin, Peng Wang, Felix Thomas Eickemeyer

Efficient and robust n-i-p perovskite solar cells necessitate superior organic hole-transport materials with both mechanical and electronic prowess. Deciphering the structure-property relationship of these materials is crucial for practical perovskite sola ...

Wiley-V C H Verlag Gmbh2024

Photo-doping of spiro-OMeTAD for highly stable and efficient perovskite solar cells

Michael Graetzel, Jacques-Edouard Moser, Etienne Christophe Socie, George Cameron Fish, Aaron Tomas Terpstra, Kai Zhu

A widely used component of high-efficiency perovskite solar cells (PSCs) is the molecular hole-transport material (HTM) spiro-OMeTAD. This organic solid needs to be p-doped to acquire sufficient hole conductivity. However, the conventional doping method us ...

2024

Influence of triphenylamine derivatives in efficient dye-sensitized/organic solar cells

Mohammad Khaja Nazeeruddin

Dye-sensitized/organic solar cells (DS/O-SCs) have gradually improved their power conversion efficiencies (PCEs) and are now being considered for commercialization. This comprehensive review focuses on a prominent class of small organic molecules called tr ...

Royal Society of Chemistry2023

Photoelectrochemical Cell Engineering for Solar Energy Conversion

Dan Zhang

Solar energy is the most abundant energy source, harnessing solar energy holds the solution to the challenge of increasing global energy demand and reducing our dependence on fossil fuels. Photovoltaics which directly convert solar energy into electricity ...

EPFL2023

Data-driven design of organic electronic materials

Jacob Terence Blaskovits

Singlet fission (SF) is a multiexciton-generating process whereby an excited state singlet (S1) is converted into two lower-energy triplets (T1). The inclusion of a SF-capable material into a photovoltaic device offers the potential for the absorption of p ...

EPFL2023

A Triethyleneglycol C-60 Mono-adduct Derivative for Efficient Electron Transport in Inverted Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Konstantina Kalliopi Armadorou

Inverted perovskite solar cells (PSCs) have attracted increasing attention in recent years owing to their low-temperature fabrication proces s. However, they suffer from a limited number of electron transport materials available with [6,6]-phenyl C-61 buty ...

WILEY-V C H VERLAG GMBH2023

Organic Semiconductors For Photoelectrochemical Applications

Arvindh Sekar

The capture and conversion of solar energy into other useful forms has been the topic of discussion for the past few decades, accentuated by the need to combat climate change and face the challenge of non-renewability of conventional sources of fuel for ou ...

EPFL2022

Bulk Heterojunction Organic Semiconductor Photoanodes: Tuning Energy Levels to Optimize Electron Injection

Kevin Sivula, Jun Ho Yum, Liang Yao, Nestor Guijarro Carratala, Yongpeng Liu, Arvindh Sekar, Han-Hee Cho, Juan Manuel Moreno Naranjo, Barbara Alexandra Primera Darwich

The use of a bulk heterojunction of organic semiconductors to drive photoelectrochemical water splitting is an emerging trend; however, the optimum energy levels of the donor and acceptor have not been established for photoanode operation with respect to e ...

AMER CHEMICAL SOC2022

Unravelling the mechanism of ultrafast photoinduced charge generation in organic and hybrid photovoltaic systems

George Cameron Fish

At the current time, the world as we know it is at a crossroads; there is an urgent need to lower greenhouse gas emissions to limit the global rise in temperature. However, this is at odds with the increasing energy demands of the world's growing populatio ...

EPFL2022

Ultrafast carrier and quasiparticle dynamics in strongly confined perovskite nanoplatelets

Etienne Christophe Socie

Over the past decade, lead halide perovskites (LHPs) have received considerable attention thanks to their impressive optoelectronic properties. Today, LHP-based devices are one of the most efficient single-junction solar cells, with power-conversion effici ...

EPFL2022

Integration of thin n-type nc-Si:H layers in the window-multilayer stack of heterojunction solar cells

Christophe Ballif, Mathieu Gérard Boccard, Luca Massimiliano Antognini, Julie Amandine Dreon, Vincent Philippe Paratte, Laurie-Lou Senaud

N-type nanocrystalline silicon (nc-Si:H(n)) layers are good candidates to improve current and transport properties in heterojunction solar cells. In this work, we perform thickness series alongside PH3 doping series to unravel the desirable characteristics ...

ELSEVIER2022

Understanding the design principles of organic sensitizers for highly efficient dye sensitized solar cells

Marko Stojanovic

The conversion of solar to electrical power has presented itself as a solution to meet the growing energy demand and replace our current fossil fuel dependence, which causes dramatic damages to the environment. At the heart of this challenge lies the perfo ...

EPFL2021

Robust Inorganic Hole Transport Materials for Organic and Perovskite Solar Cells: Insights into Materials Electronic Properties and Device Performance

Mohammad Khaja Nazeeruddin, Antonio Abate, Tom Theodorus Antonius Lummen

Interfaces in perovskite and organic solar cells play a central role in advancing efficiency and prolong device durability. They improve charge transport/transfer from the absorber layer to the collecting electrodes, while also blocking the opposite charge ...

2021

Critical role of H-aggregation for high-efficiency photoinduced charge generation in pristine pentamethine cyanine salts

Jacques-Edouard Moser, Frank Nüesch, George Cameron Fish, Juan Manuel Moreno Naranjo

The mechanism of photoinduced symmetry-breaking charge separation in solid cyanine salts at the base of organic photovoltaic and optoelectronic devices is still debated. Here, we employ femtosecond transient absorption spectroscopy (TAS) to monitor the cha ...

2021

Synthesis of NIR-Absorbing Squaraine Dyes and their Use in Organic Upconversion Devices

Karen Verena Strassel

Squaraines are organic dyes showing the advantages of a simple synthesis, high absorption coefficients and tunable bandgaps from the visible to the near-infrared (NIR) region. Their molecular structure is based on a polymethine chain and a donor-acceptor-d ...

EPFL2021

The Advantage of Nanowire Configuration in Band Structure Determination

Anna Fontcuberta i Morral, Simon Robert Escobar Steinvall, Elias Zsolt Stutz, Mirjana Dimitrievska

Earth-abundant and environmentally friendly semiconductors offer a promising path toward low-cost mass production of solar cells. A critical aspect in exploring new semiconducting materials and demonstrating their enhanced functionality consists in disenta ...

2021

Novel Interfacial Characterization and Surface Engineering in Semiconductor Electrodes for Optimized Solar Fuel Production

Yongpeng Liu

Harvesting sunlight, the ultimate renewable power source, in a cost-effective way has been long recognized as a necessary route to meet the global energy challenges. Solar energy can be transformed into electricity by means of photovoltaic devices to suppl ...

EPFL2021

Phosphorene Nanoribbon-Augmented Optoelectronics for Enhanced Hole Extraction

Vasiliki Tileli

Phosphorene nanoribbons (PNRs) have been widely predicted to exhibit a range of superlative functional properties; however, because they have only recently been isolated, these properties are yet to be shown to translate to improved performance in any appl ...

AMER CHEMICAL SOC2021