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Weakly Conjugated Hybrid Zinc Porphyrin Sensitizers for Solid-State Dye-Sensitized Solar Cells

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Machine Learning for Screening Small Molecules as Passivation Materials for Enhanced Perovskite Solar Cells

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Utilization of small molecules as passivation materials for perovskite solar cells (PSCs) has gained significant attention recently, with hundreds of small molecules demonstrating passivation effects. In this study, a high-accuracy machine learning model i ...

Wiley-VCH Verlag Gmbh2024

Tracking deep-level defects in degrading perovskite solar cells with a multifactorial approach

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In this work, we provide a mechanistic understanding of the degradation of perovskite solar cells in operation by focusing on methylammonium lead triiodide (CH3NH3PbI3 or MAPbI3) and tracking the evolution of electronic defects via photo-induced current tr ...

Elsevier2024

Advanced Manufacturing and Characterization of Building-Integrated Photovoltaic Modules

Alejandro Borja Block

Photovoltaic (PV) technology is necessary for global decarbonization. However, one of the challenges of the technology is that its land use may conflict with other space demands. Building-integrated photovoltaic (BIPV) is a solution to efficiently use the ...

EPFL2024

Microstructural and electrical characterization of high temperature passivating contacts for silicon solar cells

Sofia Libraro

Recombination at metal/semiconductor interfaces represents the main limitation in mainstream c-Si solar cells, primarily based on the passivated emitter and rear cell (PERC) concept. Full-area passivating contacts based on SiOx/poly-Si stacks are a candida ...

EPFL2024

Correlating long-term performance and aging behaviour of building integrated PV modules

Christophe Ballif, Alessandro Francesco Aldo Virtuani, Ebrar Özkalay

Because building-integrated photovoltaic (BIPV) modules are fully integrated into a building envelope, the back of the module can be exposed to little or no ventilation, resulting in increased operating temperatures. As the temperature increases, the perfo ...

Elsevier Science Sa2024

From PV to EV: Mapping the Potential for Electric Vehicle Charging with Solar Energy in Europe

Christophe Ballif, Nicolas Würsch, Alejandro Pena Bello, Noémie Alice Yvonne Ségolène Jeannin, Jérémy Dumoulin

The electrification of the transport sector is a key element in decarbonizing our societies. However, energy systems will have to cope with additional electricity demand due to the charging needs of electric vehicles (EVs) together with the integration of ...

2024

Shortwave Infrared-Sensitive, Narrowband Organic Upconversion Devices with a Gain

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Sensing and imaging of light in the shortwave infrared (SWIR) range is increasingly used in various fields, including bio-imaging, remote sensing, and semiconductor process control. SWIR-sensitive organic photodetectors (OPDs) are promising because organic ...

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Molecular hypergraph neural networks

Philippe Schwaller, Junwu Chen

Graph neural networks (GNNs) have demonstrated promising performance across various chemistry-related tasks. However, conventional graphs only model the pairwise connectivity in molecules, failing to adequately represent higher order connections, such as m ...

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Synergistic Redox Modulation for High-Performance Nickel Oxide-Based Inverted Perovskite Solar Modules

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Nickel oxide (NiOx)-based inverted perovskite solar cells stand as promising candidates for advancing perovskite photovoltaics towards commercialization, leveraging their remarkable stability, scalability, and cost-effectiveness. However, the interfacial r ...

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Photo-doping of spiro-OMeTAD for highly stable and efficient perovskite solar cells

Michael Graetzel, Jacques-Edouard Moser, Etienne Christophe Socie, George Cameron Fish, Aaron Tomas Terpstra, Kai Zhu

A widely used component of high-efficiency perovskite solar cells (PSCs) is the molecular hole-transport material (HTM) spiro-OMeTAD. This organic solid needs to be p-doped to acquire sufficient hole conductivity. However, the conventional doping method us ...

2024

A thermotropic liquid crystal enables efficient and stable perovskite solar modules

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Perovskite solar cells have seen impressive progress in performance and stability, yet maintaining efficiency while scaling area remains a challenge. Here we find that additives commonly used to passivate large-area perovskite films often co-precipitate du ...

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Alleviating nanostructural phase impurities enhances the optoelectronic properties, device performance and stability of cesium-formamidinium metal-halide perovskites

Anaël Morgane Jaffrès, Christophe Ballif, Quentin Thomas Jeangros, Aïcha Hessler-Wyser, Christian Michael Wolff, Mostafa Rabie Shlaly Bahr Othman, Daniel Anthony Jacobs, Austin George Kuba

The technique of alloying FA+ with Cs+ is often used to promote structural stabilization of the desirable alpha-FAPbI3 phase in halide perovskite devices. However, the precise mechanisms by which these alloying approaches improve the optoelectronic quality ...

Royal Soc Chemistry2024

Reliability and Long-term Performance of Building Integrated Photovoltaic (BIPV) Modules

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Solar photovoltaics (PV) is one of the most competitive renewable energy technologies in order to meet the increasing global energy demand and decrease CO2 emissions by competing effectively with fossil fuels. One of the important applications of PV energy ...

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A comprehensive physical model for the sensitivity of silicon heterojunction photovoltaic modules to water ingress

Christophe Ballif, Alessandro Francesco Aldo Virtuani, Luca Gnocchi, Olatz Arriaga Arruti

Silicon heterojunction (SHJ)-solar modules-when encapsulated with ethylene vinyl acetate (EVA)-are known to be extremely sensitive to water ingress. The reason for this is, however, not clear. Here, we explain the root causes of this degradation mechanism ...

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Encapsulation strategies for mechanical impact and damp heat reliability improvement of lightweight photovoltaic modules towards vehicle-integrated applications

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Lightweight modules are essential for next-generation vehicle-integrated photovoltaic (VIPV) applications, such as solar-powered cars, allowing integration of solar cells beyond the roof, and on the hood, boot and body panels, and thereby extending the dri ...

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High-throughput parallel testing of ten photoelectrochemical cells for water splitting: case study on the effects of temperature in hematite photoanodes

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High-throughput testing of photoelectrochemical cells and materials under well-defined operating conditions can accelerate the discovery of new semiconducting materials, the characterization of the phenomena occurring at the semiconductor-electrolyte inter ...

Royal Soc Chemistry2024

Towards Quantitative Terahertz Characterisation of Zinc Phosphide Thin Films for Photovoltaic Applications

Anna Fontcuberta i Morral, Jean-Baptiste Leran, Simon Robert Escobar Steinvall, Elias Zsolt Stutz, Rajrupa Paul, Mirjana Dimitrievska, Léa Buswell

The earth-abundant and non-toxic material Zinc phosphide (Zn3P2) is a promising candidate for solar cell applications. However, growth of defect-free, high-quality thin films on substrates that can integrate with current technology (e.g. silicon) remains c ...

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Network time series forecasting in photovoltaics power production

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Accurate forecasting of photovoltaic (PV) power production is crucial for the integration of more renewable energy sources into the power grid. PV power production is highly intermittent, due to the stochastic cloud behaviour and cloud dynamics. Previous w ...

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Enhanced performance of perovskite solar cell via up-conversion YLiF4:Yb, Er nanoparticles

Mounir Driss Mensi, Masaud Hassan S Almalki, Anwar Qasem M Alanazi

We report a simple and effective method for producing lanthanide ion-doped lithium-fluoride-based nanocrystals (YLiF4). We utilized those nanoparticles for up-conversion in fabricated perovskite solar cells. The obtained results shows that the up-conversio ...

Elsevier2024

Cu(II) and Ni(II) Phthalocyanine-Based Hole-Transporting Materials for Stable Perovskite Solar Cells with Efficiencies Reaching 20.0%

Mohammad Khaja Nazeeruddin, Jianxing Xia

Herein, Cu(II)Pcs and Ni(II)Pcs peripherally tetra-functionalized with 5-hexylthiophene (HT), 5-hexyl-2,2 '-bithiophene (HBT), and tertbutyl groups (TB) are readily synthesized and employed as hole-transporting materials (HTMs) in mixed-ion perovskite ([FA ...

WILEY-V C H VERLAG GMBH2024