Publications associées à An analysis of the optimal band gaps of light absorbers in integrated tandem photoelectrochemical water-splitting systems

Publications associées (39)

All-perovskite tandem solar cells achieving >29% efficiency with improved (100) orientation in wide-bandgap perovskites

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, Nikolaos Lempesis, Mingyang Wei, Virginia Carnevali, Lorenzo Agosta, Vladislav Slama

Monolithic all-perovskite tandem solar cells present a promising approach for exceeding the efficiency limit of single-junction solar cells. However, the substantial open-circuit voltage loss in the wide-bandgap perovskite subcell hinders further improveme ...

NATURE PORTFOLIO2025

Durable Perovskite Solar Cells with 24.5% Average Efficiency: The Role of Rigid Conjugated Core in Molecular Semiconductors

Michael Graetzel, Shaik Mohammed Zakeeruddin, Peng Wang, Felix Thomas Eickemeyer

Efficient and robust n-i-p perovskite solar cells necessitate superior organic hole-transport materials with both mechanical and electronic prowess. Deciphering the structure-property relationship of these materials is crucial for practical perovskite sola ...

Wiley-V C H Verlag Gmbh2024

Enhancing lifetime, forecasting, and economic benefits of photovoltaic technologies undergoing UV-induced degradation with optical filtering

Christophe Ballif, Antonin Faes, Marion Solange Madeleine Dussouillez, Christian Michael Wolff

Ultraviolet-induced degradation (UV-ID) of various PV cell types was analyzed under optical UV filters with different cutoff wavelengths. Cell types studied included interdigitated back contact (IBC), passivated emitter and rear totally diffused (PERT), an ...

2025

High-throughput parallel testing of ten photoelectrochemical cells for water splitting: case study on the effects of temperature in hematite photoanodes

Sophia Haussener, Isaac Thomas Holmes-Gentle, Roberto Valenza, Franky Esteban Bedoya Lora

High-throughput testing of photoelectrochemical cells and materials under well-defined operating conditions can accelerate the discovery of new semiconducting materials, the characterization of the phenomena occurring at the semiconductor-electrolyte inter ...

Royal Soc Chemistry2024

Unraveling the Role of Electron-Withdrawing Molecules for Highly Efficient and Stable Perovskite Photovoltaics

Michael Graetzel, Shaik Mohammed Zakeeruddin, Mingyang Wei, Likai Zheng

Electron-withdrawing molecules (EWMs) have exhibited remarkable efficacy in boosting the performance of perovskite solar cells (PSCs). However, the underneath mechanisms governing their positive attributes remain inadequately understood. Herein, we conduct ...

Wiley-VCH Verlag GmbH2025

Visualising ionic screening in perovskite solar cells: a bumpy ride along the J–V curve

Frank Nüesch

The J–V bump and hysteresis in perovskite solar cells are studied combining measurement and simulation, linking them to spatial collection efficiency changes from ionic charge accumulation, as visualised in external quantum efficiency (EQE) spectra. ...

Royal Society of Chemistry (RSC)2025

Green hydrogen production using Shewanella oneidensis MR-1 bioanode and cuprous oxide-based photocathode

Michele Morgante

In recent years, many efforts have been made to find alternative renewable energy sources that can ideally replace the use of fossil fuels in all aspects. One of the new emerging energy technologies is the bioelectrochemical system, of which two types are ...

EPFL2024

Facile and Low-Cost Design Alternative of Spiro-OMeTAD as p-Type Semiconductor for Efficient Perovskite Solar Cells

Mohammad Khaja Nazeeruddin

A simple diphenylamine-based hole transporting material V1553 was synthesized and incorporated into a perovskite solar cell, which showed remarkable power conversion efficiency close to 23%. The investigated HTM was synthesized via one-step catalyst-free c ...

WILEY-V C H VERLAG GMBH2025

Hybrid Ag-mesh/Ta-doped TiO2 thin film configuration as a visible and near-infrared transparent electrode

Andreas Schueler, Jérémy Jacques Antonin Fleury, Krishna Manwani

This study focuses on the fabrication of a hybrid Ag-mesh/Ta-doped TiO2 (TTO) electrode that has a low sheet resistance and high transparency in the visible and near-infrared region, thereby holding significant commercialization potential. Here, ∼82 nm thi ...

2025

Buried SnI2 Induces Gradient Heterojunctions in Sn–Pb Perovskite Solar Cells

Chenxu Zhao

Tin–lead (Sn–Pb) mixed perovskite solar cells (PSCs) offer the potential for higher power conversion efficiency (PCE) than their pure lead counterparts. However, the lack of a well-defined Sn/Pb compositional profile results in disordered internal electric ...

American Chemical Society (ACS)2025

Shortwave Infrared-Sensitive, Narrowband Organic Upconversion Devices with a Gain

Wei-Hsu Hu

Sensing and imaging of light in the shortwave infrared (SWIR) range is increasingly used in various fields, including bio-imaging, remote sensing, and semiconductor process control. SWIR-sensitive organic photodetectors (OPDs) are promising because organic ...

EPFL2024

Machine-learning-empowered FDTD/FEM simulations for predictive solar energy absorption in plasmonic metamaterial nanocavity arrays

Amir Jafargholi

FDTD/FEM simulations, strengthened by machine learning, achieve 95.44% optical absorption efficiency in TiO 2 /TiN plasmonic nanocavities for solar energy harvesting. ...

Royal Society of Chemistry (RSC)2025

Aryl-Acetylene Layered Hybrid Perovskites in Photovoltaics

Christophe Ballif, Aïcha Hessler-Wyser, Michael Graetzel, Ursula Röthlisberger, Mostafa Rabie Shlaly Bahr Othman, Masaud Hassan S Almalki, Fatemeh Ansari, Felix Thomas Eickemeyer, Ghewa Alsabeh, Lukas Pfeifer, Christian Michael Wolff, Nikolaos Lempesis, Virginia Carnevali, Vladislav Slama, Andrea Vezzosi

Metal halide perovskites have shown exceptional potential in converting solar energy to electric power in photovoltaics, yet their application is hampered by limited operational stability. This stimulated the development of hybrid layered (two-dimensional, ...

WILEY-V C H VERLAG GMBH2025

Phase-stable indium sulfide achieves an energy conversion efficiency of 14.3% for solar-assisted carbon dioxide reduction to formate

Michael Graetzel, Jingshan Luo, Jing Gao, Jun Li

Tremendous efforts have been made in developing highly selective catalysts for electrochemical CO 2 conversion to formate. However, the rapid deactivation resulting from structural reconstruction and phase transition poses considerable challenges to the sy ...

Cell Press2024

Spiro-Phenothiazine Hole-Transporting Materials: Unlocking Stability and Scalability in Perovskite Solar Cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Jaeki Jeong, Likai Zheng

Improving both the efficiency and long-term stability of perovskite solar cells (PSCs) is critical for their commercial deployment. Despite the widespread use of spiro-OMeTAD as a hole-transporting material (HTM), its inhomogeneous doping behavior and susc ...

2025

Reversible photo-electrochemical device for solar hydrogen and power generation

Sophia Haussener, Alexandre Dominique M. Cattry, Saurabh Yuvraj Tembhurne, Matthieu Jonin, Mahendra Patel

A reversible photo-electrochemical device operating under concentrated irradiation could offer a stand-alone solution for producing solar fuel (in photo-driven electrolysis mode) and power (in fuel cell mode). This strategy would present the advantage of h ...

2024

Low-Power Tunable Micro-Plasma Devices for Efficient and Scalable CO2 Conversion

Bartu Karakurt

CO2 conversion plays a vital role in addressing climate change by cutting greenhouse gas emissions and promoting a circular carbon economy. Rather than releasing carbon dioxide into the atmosphere, carbon dioxide recycling technologies allows transformatio ...

EPFL2025

Assessing the Charge Carrier Dynamics at Hybrid Interfaces of Organic Photoanodes for Solar Fuels

Kevin Sivula, Yongpeng Liu, Han-Hee Cho

Organic semiconductors (OSCs) have emerged as promising active layers for photoanodes to drive photoelectrochemical (PEC) oxidation reactions. Interfacing an OSC with an inorganic electron transport layer (ETL) is key to enabling both high performance and ...

Amer Chemical Soc2024

Microstructural and electrical characterization of high temperature passivating contacts for silicon solar cells

Sofia Libraro

Recombination at metal/semiconductor interfaces represents the main limitation in mainstream c-Si solar cells, primarily based on the passivated emitter and rear cell (PERC) concept. Full-area passivating contacts based on SiOx/poly-Si stacks are a candida ...

EPFL2024

Encapsulated Co–Ni alloy boosts high-temperature CO2 electroreduction

Jeremy Luterbacher, Xile Hu, Wenhao Ren, Seongmin Jin, Jiaming Tian, Wenchao Ma

Electrochemical CO 2 reduction into chemicals and fuels holds great promise for renewable energy storage and carbon recycling 1–3 . Although high-temperature CO 2 electroreduction in solid oxide electrolysis cells is industrially relevant, current catalyst ...

Springer Science and Business Media LLC2025