Publications associées à Development and characterization of electrochromic oxide and ion conductor deposited by reactive magnetron sputtering

Layered metals as polarized transparent conductors

Philip Johannes Walter Moll, Matthias Carsten Putzke, Chunyu Guo, Maja Deborah Bachmann

The quest to improve transparent conductors balances two key goals: increasing electrical conductivity and increasing optical transparency. To improve both simultaneously is hindered by the physical limitation that good metals with high electrical conducti ...

Nature Portfolio2023

Pathways to enhance electrochemical CO2 reduction identified through direct pore-level modeling

Sophia Haussener, Shuo Liu, Etienne Boutin, Evan Fair Johnson

Electrochemical conversion of CO2 to fuels and valuable products is one pathway to reduce CO2 emissions. Electrolyzers using gas diffusion electrodes (GDEs) show much higher current densities than aqueous phase electrolyzers, yet models for multi-physical ...

2023

In-vivo investigation of electrochemical behavior of Ti and CoCrMo alloy in human synovial fluids

Yueyue Bao

With the development of modern medical techniques, the application of orthopedic implants has been continually increasing in recent years. Passive materials, such as Ti and its alloys as well as CoCrMo alloys, are widely used in artificial joints due to th ...

EPFL2023

Tuning the Solar Performance of Building Facades through Polymer 3D Printing: Toward Bespoke Thermo-Optical Properties

Arno Schlueter, Stephen William Wasilewski

Facades are the primary interface controlling the flow of solar energy in buildings and affecting their energy balance and environmental impact. Recently, large-scale 3D printing (3DP) of translucent polymers has been explored as a technique for fabricatin ...

Wiley2023

Unraveling the Effect of the Chemical and Structural Composition of ZnxNi1-xFe2O4 on the Electron Transfer at the Electrochemical Interface

Sandro Carrara, Mallikarjun Madagalam

In order to deepen the understanding of the role of transition metal oxides in electron transfer at the electrochemical interface, the performance of ZnxNi1-xFe2O4 (x = 0, 0.2, 0.4, 0.6, 0.8, 1) nanomaterials in electrochemical sensing is studied. Nanomate ...

WILEY2023

Electronic Coupling of Metal-to-Insulator Transitions in Nickelate-Based Heterostructures

Jean-Marc Triscone, Duncan Thomas Lindsay Alexander, Bernat Mundet

In rare earth nickelates, the metal-to-insulator transition observed as a function of temperature can be described using an electronic and a structural order parameter. The electronic one is linked to the electronic disproportionation observed below the tr ...

WILEY2023

Effect of window glazing color and transmittance on human visual comfort

Marilyne Andersen, Jan Wienold, Sneha Jain

: Occupants’ visual comfort in an indoor space strongly depend on the quantity and quality of the daylight inside the space which can be altered with the type of window glazing. In this study, we compared the visual comfort perception of participants with ...

2022

Electronic properties and ion migration of “in vacuo” lithiated nanoporous WO3:Mo thin films

Andreas Schueler, Josef Andreas Schuler, Luc Burnier, Jérémy Jacques Antonin Fleury

Electrochromic (EC) glazing helps manage daylight and solar heat gains in building, thereby allowing a reduction in energy consumption caused by heating, cooling, and artificial lighting. This study relates the optical and electronic properties of nanoporo ...

2022

Strong coloration of nanoporous tungsten oxides by in-vacuo lithiation for all-solid-state electrochromic devices

Andreas Schueler, Olivia Valérie Charlotte Bouvard, Luc Burnier, Anna Krammer, Maxime Lagier

Electrochromic windows allow for an improved management of solar heat gains in buildings and enhanced visual comfort of building users. All-solid-state electrochromic devices can be especially durable. During their fabrication lithium has to be inserted, p ...

ELSEVIER SCIENCE SA2021

Behind electrochromic glazing: Assessing user's perception of glare from the sun in a controlled environment

Jan Wienold, Sneha Jain, Caroline Karmann

The adaptable transmittance of electrochromic glazing allows to control the solar radiation entering buildings, yet the level of transmittance needed to protect from glare is still an unanswered question. To bridge this gap, this study evaluates the level ...

2022

Machines for Materials and Materials for Machines: Metal-Insulator Transitions and Artificial Intelligence

Bernat Mundet

In this perspective, we discuss the current and future impact of artificial intelligence and machine learning for the purposes of better understanding phase transitions, particularly in correlated electron materials. We take as a model system the rare-eart ...

2021

Metasurfaces for label-free biosensing mid-infrared optics and active photonic devices

Aleksandrs Leitis

Novel two-dimensional metamaterials, known as metasurfaces, have emerged as a breakthrough platform for controlling electromagnetic wave properties at the nanoscale. These metasurfaces consist of subwavelength nanoantennas or so-called meta-atoms, which ca ...

EPFL2021

Defect formation and mitigation during laser powder bed fusion of copper

Carl Tore Viktor Lindström

Additive manufacturing (AM) is a group of processing technologies which has the potential to revolutionize manufacturing by allowing easy manufacturing of complex shapes and small series. One AM-method which is of high interest for processing of metals is ...

EPFL2021

In situ nanoscale studies of copper-based catalysts for carbon dioxide electroreduction

Karla Banjac

The urgency of climate change demands the simultaneous removal of carbon dioxide from the atmosphere and the transition to renewable energy sources. This aim is realizable through electrochemical reduction of carbon dioxide (CO2RR), which is a promising ro ...

EPFL2021

Optical gap and fundamental gap of oligoynes and carbyne

Jan Cornelius Brauer, Laurent Alexis Clément Vannay, Anne-Clémence Corminboeuf, Holger Frauenrath, Stephen Schrettl, Emmanuel Romaric Contal, Eric Albert Georges Bremond

The optoelectronic properties of various carbon allotropes and nanomaterials have been well established, while the purely sp-hybridized carbyne remains synthetically inaccessible. Its properties have therefore frequently been extrapolated from those of def ...

Nature Research2020

Lithium-Gold Reference Electrode for Potential Stability DuringIn SituElectron Microscopy Studies of Lithium-Ion Batteries

Nikolaos Nianias, Jing Hou, Vasiliki Tileli, Jialiang Fan, Tzu-Hsien Shen, Robin Pierre Alain Girod

Electrochemical liquid-phase transmission electron microscopy (TEM) is showing excellent promise in fundamental studies of energy-related processes including lithium-ion battery (LIB) cycling. A key requirement to accurately interpret the measurements and ...

2020

Mapping of Chemical Heterogeneity at Surfaces with High-Throughput Wide-Field Second Harmonic Microscopy

Igor Nahálka

Many industrial processes are based on electrochemical reactions using engineered electrocatalysts. However, the current lack of theoretical knowledge obscures efforts to maximize catalysts' efficiency, and the optimization process is mostly empirical. To ...

EPFL2020

Radio-Frequency Characteristics of Ge-doped Vanadium Dioxide Thin Films with Increased Transition Temperature

Igor Stolichnov, Mihai Adrian Ionescu, Andreas Schueler, Teodor Rosca, Anna Krammer, Riyaz Mohammed Abdul Khadar, Matteo Cavalieri, Fatemeh Qaderi Rahaqi, Andrei Müller

This work investigates and reports on the radio-frequency (RF) behavior in the frequency range of 5 – 35 GHz of germanium-doped (Ge-doped VO2) vanadium dioxide thin films, deposited on silicon substrates via sputtering and pulsed laser deposition (PLD) wit ...

2020

Electrochemical and morphological engineering of 2D materials for nanopore sensing

Martina Lihter

Nanopores are nanometer-sized holes that were initially proposed for DNA sequencing. Several years ago sequencing was made possible with biological nanopores. However, solid-state nanopores have plenty of advantages to offer compared to their biological co ...

EPFL2020

Precise and accurate image-based measurements of optical material properties

Marjan Shahpaski

The appearance of objects is governed by how they reflect, transmit and absorb the light they receive. That, in turn, depends on the material's internal structure, surface structure, and viewing and illumination directions. Changes in those characteristics ...

EPFL2020