Publications associées à Unimolecular fragmentation and radiative cooling of isolated PAH ions: A quantitative study

Publications associées (31)

Millisecond-time-scale Controlled Freeze-quench for Solute-intermediate Analysis by Solid-state Nmr

Crystallization is a fundamental process in biomineralization, yet its complexity increases significantly in non-classical pathways of nucleation and growth, where numerous intermediates exist between free ions in solution and the final crystalline phase. ...

ROYAL SOC CHEMISTRY2025

Performance of energy piles foundation in hot-dominated climate: A case study in Dubai

Lyesse Laloui, Elena Ravera, Sofie Elaine ten Bosch

Energy piles represent an innovative technology that can help provide sustainable geothermal heating or cooling energy for thermal conditioning purposes. In hot-dominated climates, the interest is to inject heat in the ground and extract energy for space-c ...

Pergamon-Elsevier Science Ltd2024

Ion Spectroscopy Reveals Structural Difference for Proteins Microhydrated by Retention and Condensation of Water

Oleg Boyarkine, Andrei Zviagin

Protein ubiquitin in its +7 charge state microhydrated by 5 and 10 water molecules has been interrogated in the gas phase by cold ion UV/IR spectroscopy. The complexes were formed either by condensing water onto the unfolded bare proteins in a temperature- ...

Amer Chemical Soc2024

Interpretative 3D MHD modelling of deuterium SPI into a JET H-mode plasma

Umar Sheikh, Haomin Sun, Mengdi Kong, Cristian Sommariva

The pre-thermal quench (pre-TQ) dynamics of a pure deuterium ( D 2 ) shattered pellet injection (SPI) into a 3 MA / 7 MJ JET H-mode plasma is studied via 3D non-linear MHD modelling with the JOREK code. The interpretative modelling captures the overall evo ...

IOP Publishing Ltd2024

Demonstration of a sparse sensor placement technique to the limited diagnostic set in a fusion power plant

Artur Perek, Lorenzo Martinelli

DEMO will have a limited diagnostic set for optimization of reactor performance, and limited diagnostic coverage due to challenging reactor conditions. This poses challenges for control, especially for detachment control which is planned to be performed wi ...

Elsevier Science Sa2024

Flash Melting Amorphous Ice

Marcel Drabbels, Ulrich Lorenz, Gabriele Bongiovanni, Constantin Richard Krüger, Nathan Junior Mowry

Water can be vitrified if it is cooled at high rates, which makes it possible to outrun crystallization in so-called no man’s land, a range of deeply supercooled temperatures where water crystallizes rapidly. Here, we study the reverse process in pure wate ...

2024

Design and assessment of an evaporating water-cooled methanation reactor for a SOE-based power-to-methane system

Philippe Aubin

The transition towards clean renewable energy sources, where wind and solar are prone to variation, requires adequate energy storage. Power-to-methane (PtM) systems can be part of the solution. Specifically, solid-oxide-electrolyser (SOE) based PtM systems ...

EPFL2024

Decomposition method to evaluate district heating/cooling network potential at urban scale

Ana Catarina Gouveia Braz, François Maréchal, Luc Girardin, Bingqian Liu

In this work, a tool to design district heating networks (DHN) is presented and applied to the city of Lausanne as a case study. The evaluation of the buildings’ heat/cooling demand is performed using a Geographic Information System (GIS) database, built f ...

Associazione Italiana Di Ingegneria Chimica2024

DTT toroidal field conductor samples test in Sultan: DC and AC characterization

Kamil Sedlák, Mattia Ortino, Hugues Marie Alain Bajas

The superconducting magnet system of the Divertor Tokamak Test (DTT) facility, composed of 18 toroidal field (TF) coils, 6 poloidal field coils and a central solenoid, has been designed and many procurements have been launched. Some manufacturing aspects a ...

Iop Publishing Ltd2024

Radiation-tolerant Multichannel Dew Point Temperature Monitoring System for High Energy Physics Applications

Amar Kapic

The next generation of high-energy physics (HEP) detectors will predominantly be silicon-based. As pixel sensor technology gains momentum and the number of channels surpasses one billion (for a volume of approximately 20 m3) to achieve the high resolution ...

EPFL2023

Salt Bridge Structure of Microhydrated Arginine Kinetically Trapped in the Gas Phase by Evaporative Cooling

Oleg Boyarkine, Andrei Zviagin

Aminoacids and peptides generally exhibit zwitterionic forms withsalt bridge (SB) structures in solution but charge-solvated (CS) motifsin the gas phase. Here, we report a study of non-covalent complexesof the protonated amino acid arginine, ArgH(+)(H2O)( ...

2023

Bridging Native and Intrinsic Structures of Microhydrated Biomolecules by Cold Ion Spectroscopy

Andrei Zviagin

Solving native structures of such large molecules, like biomolecules, is often challenging, particularly due to the potentially infinite number of non-covalent interactions with water. In this thesis, we report the use of cold ion gas-phase action spectros ...

EPFL2023

Influence of outdoor air pollution on European residential ventilative cooling potential

Dusan Licina, Evangelos Belias

Residential ventilative cooling via natural ventilation is influenced by outdoor air pollution. However, relative to climate, outdoor air pollution is not comprehensively considered in determining the ventilative cooling potential of buildings. To assess t ...

ELSEVIER SCIENCE SA2023

Origin of the enhanced pseudo-elasticity of additively manufactured Fe-17Mn-5Si-4Ni-10Cr-(V, C) shape memory alloy fabricated by laser powder bed fusion

Christian Leinenbach, Irene Ferretto

This study investigated the origin of the enhanced pseudo-elasticity of additively manufactured vanadium carbide-containing Fe-based shape memory alloys. The aged samples with two different starting microstructures, as-built and solution-treated, showed co ...

Elsevier Science Sa2023

Efficacy of temporal and spatial abstraction for training accurate machine learning models: A case study in smart thermostats

Rachid Guerraoui, Alexandre David Olivier Maurer

Smart thermostats are increasingly popular in homes and buildings as they improve occupant comfort, lower energy use in heating and cooling systems, and reduce utility bills by automatically adjusting room temperature according to measurements of their bui ...

ELSEVIER SCIENCE SA2023

Advancing efficiency and reliability in thermal analysis of laser powder-bed fusion

Christian Leinenbach

In laser based powder-bed fusion of metals (PBF-LB/M), parts are fabricated by melting layers of powder using a high-intensity laser beam. During this process, the material is exposed to rapid cooling rates and intense thermal gradients, which are the unde ...

2023

Gas/Surface reactions probed by reflection absorption infrared spectroscopy

Harmina Vejayan

In my thesis, I present an investigation of the dissociation reactions of gas phase molecules on single crystal metal surfaces studied by a molecular beam in combination with Reflection Absorption Infrared Spectroscopy (RAIRS). Two gas/surface systems were ...

EPFL2023

Seasonality of density currents induced by differential cooling

Alfred Johny Wüest, Damien Bouffard, Hugo Nicolás Ulloa Sánchez, Tomy Doda

When lakes experience surface cooling, the shallow littoral region cools faster than the deep pelagic waters. The lateral density gradient resulting from this differential cooling can trigger a cold downslope density current that intrudes at the base of th ...

2022

First steps towards interlocking modular microfluidic cooling substrates (i-MμCS) for future silicon tracking detectors in High Energy Physics (HEP)

Philippe Renaud, Massimo Angeletti

In future High Energy Physics detectors, the coverage of large surfaces with silicon pixel chip sensors poses a challenge for the sensors positioning, for their cooling, assembly, and interconnection. The use of a cooling substrate on which the sensors are ...

2022

Conductive Heat Transfer in Partially Saturated Gas Diffusion Layers with Evaporative Cooling

Sophia Haussener, Mirco Magnini

Heat transport is an important, though often neglected function of gas diffusion layers (GDLs) of polymer electrolyte membrane fuel cells. Thermal conductivity is a key property, especially in partially water saturated GDLs and when the phase change of wat ...

2022