Publications associées à Stabilization of the Perovskite Phase of Formamidinium Lead Triiodide by Methylammonium, Cs, and/or Rb Doping

Dynamic Nuclear Polarization of Inorganic Halide Perovskites

Dominik Józef Kubicki, David Lyndon Emsley, Gabriele Stevanato, Aditya Mishra, Michael Allan Hope

The intrinsic low sensitivity of nuclear magnetic resonance (NMR) experiments limits their utility for structure determination of materials. Dynamic nuclear polarization (DNP) under magic angle spinning (MAS) has shown tremendous potential to overcome this ...

2023

Interface connection of functionalized carbon nanotubes for efficient and stable perovskite solar cells

Mohammad Khaja Nazeeruddin, Ruiyuan Hu, Jianxing Xia

The ionic defects of hetero-junction interfaces always attract and trap carriers via surface electrostatic forces, which are crucial for the efficiency and intrinsic stability of perovskite solar cells (PSCs). Herein, functionalized carbon nanotubes (CNTs) ...

Royal Society of Chemistry2023

Formation and stabilization of all-inorganic perovskites for photovoltaics

Zaiwei Wang

All-inorganic perovskite films hold promise for improving stability of perovskite solar cells. However, the desirable narrow-bandgap inorganic perovskites (such as CsPbI3 and CsPbI2Br) are suffering from the thermodynamic phase instability, as the photoact ...

EPFL2020

Elucidating the Doping Mechanism in Fluorene-Dithiophene-Based Hole Selective Layer Employing Ultrahydrophobic Ionic Liquid Dopant

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Sanghyun Paek, Laura Calio

Perovskite solar cells have set a new milestone in terms of efficiencies in the thin film photovoltaics category. Long-term stability of perovskite solar cells is of paramount importance but remains a challenging task. The lack of perovskite solar cells st ...

2020

Ba-induced phase segregation and band gap reduction in mixed-halide inorganic perovskite solar cells

Michael Graetzel, Ulf Anders Hagfeldt, Dominik Józef Kubicki, Wolfgang Richard Tress, Jingshan Luo, David Lyndon Emsley, Albert Hofstetter, Xiaoyan Wang, Zaiwei Wang, Wanchun Xiang, Jiahuan Zhang, Xiaoyu Wang

All-inorganic metal halide perovskites are showing promising development towards efficient long-term stable materials and solar cells. Element doping, especially on the lead site, has been proved to be a useful strategy to obtain the desired film quality a ...

Nature Research2019

Novel p-dopant toward highly efficient and stable perovskite solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Marko Stojanovic, Jiyoun Seo, Hui-Seon Kim, Seckin Akin

Li-TFSI is the most common p-dopant for the hole conductor spiro-MeOTAD in the normal structure (n-i-p) of perovskite solar cells (PSCs), which consistently yield the highest power conversion efficiency (PCE) albeit at the risk of lower long-term operation ...

ROYAL SOC CHEMISTRY2018

Molecular Engineering Towards High Efficiency Perovskite Solar Cells

Jiyoun Seo

High energy demands of our society stimulate the development of sustainable tech-nologies, such as those based on solar energy conversion or photovoltaics. Perovskite solar cells (PSCs) are an emerging photovoltaic technology that consist of the perov-skit ...

EPFL2018

Inorganic hole conductor based perovskite photoelectric conversion device with high operational stability at long term

Michael Graetzel, Shaik Mohammed Zakeeruddin, Mohammad Ibrahim Dar, Neha Arora

The invention relates to an optoelectronic and/or photoelectrochemical device comprising a conductive support layer, n-type semiconductor, a sensitizer or light-absorber layer, a hole transporting layer, a spacer layer and a back contact, wherein the n-typ ...

2018

High-Temperature Ferrimagnetism with Large Coercivity and Exchange Bias in the Partially Ordered 3d/5d Hexagonal Perovskite Ba2Fe1.12Os0.88O6

Philip Pattison

Double perovskite oxides A(2)BB'O-6 combining 3d and 4d or 5d transition metal ions at the B and B' sites feature a variety of magnetic and magneto-electric properties. Targeting Ba2FeOsO6, we synthesized powder samples of nonstoichiometric Ba2Fe1.12Os0.88 ...

American Chemical Society2017

Monovalent Cation Doping of CH3NH3PbI3 for Efficient Perovskite Solar Cells

Michael Graetzel, Mojtaba Abdi Jalebi, Mohammad Ibrahim Dar

Here, we demonstrate the incorporation of monovalent cation additives into CH3NH3PbI3 perovskite in order to adjust the optical, excitonic, and electrical properties. The possibility of doping was investigated by adding monovalent cation halides with simil ...

Journal Of Visualized Experiments2017