Publications associées à Reaction of β-Ketoester and 1,3-Diol to Access Chemically Recyclable and Mechanically Robust Poly(vinyl alcohol) Thermosets through Incorporation of β-(1,3-dioxane)ester

Publications associées (18)

Development of a Sustainable Thermoplastic Composite Material Using Manicaria saccifera Fabric and Elium® Resin

The massive production of nonrenewable materials has exacerbated global environmental challenges, necessitating the development of sustainable alternatives. This study explores the potential of the Manicaria saccifera fabric, an indigenous Colombian natura ...

2025

Near-Room-Temperature Detection of Aromatic Compounds with Inkjet-Printed Plasticized Polymer Composites

Jürgen Brugger, Thomas Maeder, Mohammadmahdi Kiaee

Chemiresistive gas sensors composed of a thermoplastic polymer matrix and conductive fillers offer various advantages for detecting volatile organic compounds (VOCs), including low power consumption due to near-room-temperature operation, high sensitivity, ...

Amer Chemical Soc2024

Biobased Composites from Eugenol- and Coumarin-Derived Methacrylic Latex and Hemp Nanocellulose: Cross-Linking via [2+2] Photocycloaddition and Barrier Properties

Yves Leterrier, Sara Dalle Vacche

A novel-biobased latex was synthesized by redox-initiated emulsion copolymerization of ethoxy dihydroeugenyl methacrylate with 5 wt % of a photosensitive methacrylate containing a coumarin group. A stable copolymer latex having 16 wt % solids content and a ...

Amer Chemical Soc2024

3D Printing of Double Network Granular Elastomers with Locally Varying Mechanical Properties

Benjamin François Régis Tiberghien, Esther Amstad, Eva Jeanne Baur

Fast advances in the design of soft actuators and robots demand for new soft materials whose mechanical properties can be changed over short length scales. Elastomers can be formulated as highly stretchable or rather stiff materials and hence, are attracti ...

Wiley-V C H Verlag Gmbh2024

Supramolecular Modifications of Semicrystalline Polymers

Michael Alan Giffin

Supramolecular interactions play an important role in defining the structure and the resulting mechanical properties of materials. For instance, interchain hydrogen-bonding in PAs gives them superior strength and stiffness in engineering materials, while t ...

EPFL2023

Ductile, High-Lignin-Content Thermoset Films and Coatings

Thanh Thi Hà Lê, Harm-Anton Klok, Alice Boarino, Nicola Carrara

In the context of transitioning toward a more sustainable use of natural resources, the application of lignin to substitute commonly utilized petroleum-based plastics can play a key role. Although lignin is highly available at low cost and presents interes ...

Amer Chemical Soc2023

Bottlebrush Dielectric Elastomers with Improved Properties for Actuation

Yeerlan Adeli

Dielectric elastomer actuators (DEA) are elastic capacitors composed of a pair of compliant electrodes and a soft dielectric elastomer film sandwiched in between. This kind of stretchable capacitors can be actuated when charged, can generate electricity fr ...

EPFL2023

A HAPPI solution: Photothermal additive manufacturing of unmodified thermoset resins

Daryl Yee Wei Liang

The direct additive manufacturing (AM) of thermally cured thermosets is a long-standing challenge in the AM community. To address this, Boydston and coworkers developed a novel vat-based AM technology, termed HAPPI, that can be used with unmodified Sylgard ...

2023

MEWron: An open-source melt electrowriting platform

Jürgen Brugger, Christophe Moser, Taavet Kangur, Sönke Menke

Melt electrowriting (MEW) is a distinct class of additive manufacturing technologies that generates fibrous and porous macrostructures with microscale resolution from an electrically charged molten polymer. The high -resolution scaffolds produced by MEW ha ...

2023

Tailoring the performance of nanocellulose-based multilayer-barrier paperboard using biodegradable-thermoplastics, pigments, and plasticizers

Tiffany Abitbol

In this work a multilayer barrier paperboard was produced in a roll-to-roll process by slot-die coating of nanocellulose (microfibrillated cellulose or carboxymethylated cellulose nanofibrils) followed by extrusion coating of biodegradable thermoplastics ( ...

SPRINGER2023

A new high-pressure high-temperature deformation apparatus to study the brittle to ductile transition in rocks

Michel Teuscher, Laurent Fabrice Morier, Henri Joseph François Gilles Leclère, Marie Estelle Solange Violay, Mateo Alejandro Acosta, Gabriel Gérard Dominique Meyer

Understanding the micro-mechanisms underlying the localized-ductile transition (LDT) as well as the brittle-plastic transition (BPT) has become crucial for our wider understanding of crustal processes and seismicity. Given how difficult in situ observation ...

2023

Slot-Die Coating of an On-the-Shelf Polymer with Increased Dielectric Permittivity for Stack Actuators

Yauhen Sheima

Nitrile-butadiene rubbers (NBR) have been extensively used as dielectric materials due to their commercial availability, excellent mechanical properties, glass transition temperature below 0 degrees C, and increased dielectric permittivity owing to the pre ...

AMER CHEMICAL SOC2022

Synthesis of polar polynorbornenes with high dielectric relaxation strength as candidate materials for dielectric applications

Frank Nüesch

Materials with high dielectric permittivity and dielectric relaxation strength are sought for thermal and pressure sensors and electrical energy generators. However, most polymers have either too low dielectric permittivity or are so polar that their glass ...

ROYAL SOC CHEMISTRY2022

Enhancement of Pressure-Sensitive Adhesive by CO2 Laser Treatment

Dario Floreano, Jun Shintake, Yegor Piskarev, Vivek Ramachandran

Pressure-sensitive adhesives (PSAs) are polymeric films that can be adhered to and detached from surfaces without leaving residue. Researchers are looking to enhance the bond strength between PSAs and different substrates. It can be achieved by tuning PSA' ...

2022

Modulating the Electron Transporting Properties of Subphthalocyanines for Inverted Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Hiroyuki Kanda, Maria Cristina Momblona Rincón

The lack of organic non-fullerene ETMs with good electron transport and device stability is an important problem for the further development and commercialization of perovskite solar cells. Herein, the use of SubPcs as ETMs in PSCs is explored. To this end ...

FRONTIERS MEDIA SA2022

Hyper-Cross-Linked Polystyrene as a Stabilizing Medium for Small Metal Clusters

Lioubov Kiwi

Among different polymers nanostructured cross-linked aromatics have the greatest potential as catalytic supports due to their exceptional thermal and chemical stability and preservation of the active phase morphology. This work studies the ability of hyper ...

2021

In situ photopolymerizable hydrogels for intracranial aneurysms treatment

Oriane Poupart

Intracranial aneurysm is a cerebrovascular disease characterized by an artery dilation in the brain. An aneurysm is prone to rupture, which causes a life-threatening subarachnoid hemorrhage. The major drawbacks of the current treatments, open surgical clip ...

EPFL2021

Polysiloxanes Modified with Different Types and Contents of Polar Groups: Synthesis, Structure, and Thermal and Dielectric Properties

Holger Frauenrath, Yauhen Sheima

Polymers with high dielectric permittivity are promising for the construction of next-generation transducers and energy storage devices with improved energy density. Here, we report the synthesis, glass-transition temperature (T-g), and dielectric properti ...

American Chemical Society2021