Nitride protonation and NH3 binding versus N-H bond cleavage in uranium nitrides

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Diazo compounds of the type R1R2CN2 are widely used in organometallic catalysis and synthetic chemistry. Stable diazoolefins, R1R2C=CN2, have only been isolated recently. Diazoolefins undergo cycloaddition reactions and tend to be carbon donors when used a ...

A catalyst possessing a broad substrate scope, in terms of both turnover and enantioselectivity, is sometimes called "general". Despite their great utility in asymmetric synthesis, truly general catalysts are difficult or expensive to discover via traditio ...

Scrutinizing the metal nitride/oxide interface reveals the chemical origin of the enhanced oxygen reduction activity of metal nitrides. ...

End-on binding of dinitrogen to low valent metal centres is common in transition metal chemistry but remains extremely rare in f-elements chemistry. In particular, heterobimetallic end-on N2 bridged complexes of lanthanides are unprecedented despite their ...

Supported Co-based catalysts exhibit promising catalytic activities in the oxygen evolution reaction (OER) during alkaline water electrolysis. Surface functionalization of the support modulates the dispersion of the catalysts and their interaction with the ...

Nitrate is formed through the chemical production of gas-phase nitric acid and subsequent partitioning to the aerosol phase during the daytime. Many studies in the past separated these two aspects, even though they occur simultaneously in the atmosphere. T ...

The inward diffusion of metal electrodes is one of the main reasons for the deterioration of the long-term device stability of perovskite solar cells (PSCs). Thus, herein, we adopt a simple additive engineering strategy to modify the barrier material batho ...

Complexes of uranium in low oxidation state have shown the ability to activate non-reactive small molecules such as N-2. However, the multi-electron transfer required for such activation remains limited in uranium chemistry. Here, we review our recent rese ...

The automated construction of datasets has become increasingly relevant in computational chemistry. While transition-metal catalysis has greatly benefitted from bottom-up or top-down strategies for the curation of organometallic complexes libraries, the fi ...

Solid state nanopores are single-molecular devices governed by nanoscale physics with a broad potential for technological applications. However, the control of translocation speed in these systems is still limited. Ionic liquids are molten salts which are ...

Cuprous oxide (Cu2O) is a promising photocathode material for photoelectrochemical (PEC) water splitting. Recently, the PEC performances of Cu2O-based devices have been considerably improved by introducing nanostructures, semiconductor overlayers, and hydr ...

Diamines are essential building blocks for the synthesis of agrochemicals, drugs, and organic materials, yet their synthesis remains challenging, as both nitrogens need to be differentiated and diverse substitution patterns (1,2, 1,3, or 1,4) are required. ...

InSb has the smallest bandgap and highest electron mobility among III-V semiconductors and is widely used for photodetectors and high-frequency electronic applications. Integration of InSb directly on Si would drastically reduce the fabrication cost and en ...

Clathrochelate complexes have been widely investigated with different size and shape and used as building blocks for the obtainment of discrete supramolecular architectures. These clathrochelate complexes are very stable and kinetically inert complexes. A ...

Nitride protonation and NH3 binding versus N-H bond cleavage in uranium nitrides

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Exploring the reactivity of N-heterocyclic diazoolefins

A genetic optimization strategy with generality in asymmetric organocatalysis as a primary target

Strain by metal nitrides accelerates oxygen reduction

Iron promoted end-on dinitrogen-bridging in heterobimetallic complexes of uranium and lanthanides

Understanding the role of surface oxygen-containing functional groups on carbon-supported cobalt catalysts for the oxygen evolution reaction

Abundant nitrogen oxide and weakly acidic environment synergistically promote daytime particulate nitrate pollution

Inhibiting metal-inward diffusion-induced degradation through strong chemical coordination toward stable and efficient inverted perovskite solar cells

Multi-electron Transfer by U(II) and Masked U(II) Complexes

OSCAR: an extensive repository of chemically and functionally diverse organocatalysts

From Water Solutions to Ionic Liquids with Solid State Nanopores as a Perspective to Study Transport and Translocation Phenomena

Structural and Compositional Investigations on the Stability of Cuprous Oxide Nanowire Photocathodes for Photoelectrochemical Water Splitting

Diamine Synthesis via the Nitrogen-Directed Azidation of sigma- and pi-C-C Bonds

Fabrication of Single-Crystalline InSb-on-Insulator by Rapid Melt Growth

Half-clathrochelate Complexes as Versatile Links in Supramolecular Chemistry